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Metalworking (rec.crafts.metalworking) Discuss various aspects of working with metal, such as machining, welding, metal joining, screwing, casting, hardening/tempering, blacksmithing/forging, spinning and hammer work, sheet metal work. |
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#1
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Dispensing Toluene, anybody?........
I have a project that I need to use toluene to bond some rubber. I don't
want to use any kind of rubber cement, as the bond is in mid-process--after the rubber is dried but before it is vulcanized--and anything added may disrupt the final vulcanization of the rubber. -Plus, the only cements that would work would be 'industrial' ones that have a lot of toluene or xylene anyway (so they'd still be flammable/noxious) and still might not work as well. I can buy the toluene in a gallon can, but what I want is a smaller container for use, and a way to apply it easily a few drops at a time. For the smaller bottle, US plastics sells glass bottles with teflon lid liners. Toluene seems to dissolve damn near every kind of plastic there is eventually, but Teflon is one plastic that is resistant to damn near everything. So far I have not found any info that Toluene will harm teflon.... ? The can it comes in has a plastic liner made of,,,, something? The toluene comes in a metal can, FWIW. I know places to buy smaller metal cans but they all have plastic linings, and I dunno which to get for this. There are also one-piece stainless-steel cans around too I guess, which might work too. I'd just have to find one that had a screw-on stainless lid,,,, and a liner made of ,,, what? teflon? For the applicator, I am thinking of just using a piece of glass lab tubing as a manual dropper. This would allow avoiding contaminating the jar. I'd like to find a plastic/rubber-bulb dropper that would hold maybe 2cc's at a time, but so far all I have found has not been suitable for this use. Any ideas? Also note: being just a Regular Guy, I can't buy anything from anywhere that requires a corporate account. |
#2
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Dispensing Toluene, anybody?........
DougC fired this volley in news:uG8Gq.14192
: This would allow avoiding contaminating the jar. I'd like to find a plastic/rubber-bulb dropper that would hold maybe 2cc's at a time, but so far all I have found has not been suitable for this use. Any ideas? To my knowlege, toluene will not attack virgin polyethylene. There are numerous "disposable" laboratory eye droppers made from blow- molded PE. LLoyd |
#3
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Dispensing Toluene, anybody?........
On Dec 14, 2:37*pm, DougC wrote:
I have a project that I need to use toluene to bond some rubber. I don't want to use any kind of rubber cement, as the bond is in mid-process--after the rubber is dried but before it is vulcanized--and anything added may disrupt the final vulcanization of the rubber. -Plus, the only cements that would work would be 'industrial' ones that have a lot of toluene or xylene anyway (so they'd still be flammable/noxious) and still might not work as well. I can buy the toluene in a gallon can, but what I want is a smaller container for use, and a way to apply it easily a few drops at a time. For the smaller bottle, US plastics sells glass bottles with teflon lid liners. Toluene seems to dissolve damn near every kind of plastic there is eventually, but Teflon is one plastic that is resistant to damn near everything. So far I have not found any info that Toluene will harm teflon.... ? The can it comes in has a plastic liner made of,,,, something? The toluene comes in a metal can, FWIW. I know places to buy smaller metal cans but they all have plastic linings, and I dunno which to get for this. There are also one-piece stainless-steel cans around too I guess, which might work too. I'd just have to find one that had a screw-on stainless lid,,,, and a liner made of ,,, what? teflon? For the applicator, I am thinking of just using a piece of glass lab tubing as a manual dropper. This would allow avoiding contaminating the jar. I'd like to find a plastic/rubber-bulb dropper that would hold maybe 2cc's at a time, but so far all I have found has not been suitable for this use. Any ideas? Also note: being just a Regular Guy, I can't buy anything from anywhere that requires a corporate account. Polyethylene is pretty inert, look for a wash bottle or dropper bottle, one trade name is Nalgene. If you're going to have toluene around regularly, you need a safety can and a flammables locker. I just store all those kinds of solvents outside in a hut well away from the house. You DO know the stuff will do a number on your liver, if you're regularly exposed, right? See what www.sciencecompany.com has, they're local and retail. Have dropper bottles, glass and plastic as well as other lab gear. I've gotten labware from them to mix up small quantities of two-part paint for airbrushing gun stuff. That stuff's a lot more aggressive than just toluene. Stan |
#4
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Dispensing Toluene, anybody?........
On Wed, 14 Dec 2011 15:37:29 -0600, DougC
wrote: I have a project that I need to use toluene to bond some rubber. I don't want to use any kind of rubber cement, as the bond is in mid-process--after the rubber is dried but before it is vulcanized--and anything added may disrupt the final vulcanization of the rubber. -Plus, the only cements that would work would be 'industrial' ones that have a lot of toluene or xylene anyway (so they'd still be flammable/noxious) and still might not work as well. I can buy the toluene in a gallon can, but what I want is a smaller container for use, and a way to apply it easily a few drops at a time. For the smaller bottle, US plastics sells glass bottles with teflon lid liners. Toluene seems to dissolve damn near every kind of plastic there is eventually, but Teflon is one plastic that is resistant to damn near everything. So far I have not found any info that Toluene will harm teflon.... ? The can it comes in has a plastic liner made of,,,, something? The toluene comes in a metal can, FWIW. I know places to buy smaller metal cans but they all have plastic linings, and I dunno which to get for this. There are also one-piece stainless-steel cans around too I guess, which might work too. I'd just have to find one that had a screw-on stainless lid,,,, and a liner made of ,,, what? teflon? For the applicator, I am thinking of just using a piece of glass lab tubing as a manual dropper. This would allow avoiding contaminating the jar. I'd like to find a plastic/rubber-bulb dropper that would hold maybe 2cc's at a time, but so far all I have found has not been suitable for this use. Any ideas? Try he http://www.nalgenunc.com/techdata/chemical/ Looks like teflon is okay (30 days at 50°C), but it attacks many other kinds of plastics. Also note: being just a Regular Guy, I can't buy anything from anywhere that requires a corporate account. How did you get ahold of gallons of toluene then? ;-) Reagent grade is sold in glass bottles, dunno what they use for the caps, maybe thermoset plastic of some kind with a teflon seal. |
#5
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Dispensing Toluene, anybody?........
On 12/14/2011 4:12 PM, Stanley Schaefer wrote:
... You DO know the stuff will do a number on your liver, if you're regularly exposed, right?.... Stan Yea, I am aware of that. I don't need to use much at once (literally only 5-6 drops probably) and I won't need it often. |
#6
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Dispensing Toluene, anybody?........
"DougC" wrote in message ... ... For the applicator, I am thinking of just using a piece of glass lab tubing as a manual dropper. This would allow avoiding contaminating the jar. I'd like to find a plastic/rubber-bulb dropper that would hold maybe 2cc's at a time, but so far all I have found has not been suitable for this use. Any ideas?... This reads like a salesman wrote it: http://en.wikipedia.org/wiki/Pipette From the chemist's perspective, draw down a glass tube like the end of an eyedropper, break it off and flame-smooth the end. Dip the tube in the liquid to fill it and put your finger over the end to hold it in. Tilt your finger slightly to let air in and drops out. It isn't difficult but does take practice for fine control. Volatile liquids like toluene will dribble out from the hand-warmed expansion of their vapor. In 1965 I had a factory job stirring urethane resin into an open drum of toluene and running nylon webbing through the solution and onto a drying reel over it. I learned to hold a deep breath for about two minutes of work, then stick my head outside and hyperventilate. I also learned that I don't get high. Toluene is a component of enamel paint thinner/reducer, and not much different from gasoline on plastics. I've bought high-test gas that smelled like toluene. http://www.eng-tips.com/viewthread.cfm?qid=41617 jsw |
#7
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Dispensing Toluene, anybody?........
I have had a couple of these for years (Hunter branded) and the pumps (and
top sections) are all metal. If a glass jar could be found with the correct thread, these are very convenient for liquids that don't thicken. As the top is pushed down, a small amount of liquid is pumped up to the shallow dish-shaped top. The convenience is not needing to open a capped container for each use, while keeping the solvent capped. http://www.labsafety.com/menda-autom...sers_24532129/ I dunno if HDPE is toluene-proof. -- WB .......... "DougC" wrote in message ... I have a project that I need to use toluene to bond some rubber. I don't want to use any kind of rubber cement, as the bond is in mid-process--after the rubber is dried but before it is vulcanized--and anything added may disrupt the final vulcanization of the rubber. -Plus, the only cements that would work would be 'industrial' ones that have a lot of toluene or xylene anyway (so they'd still be flammable/noxious) and still might not work as well. I can buy the toluene in a gallon can, but what I want is a smaller container for use, and a way to apply it easily a few drops at a time. For the smaller bottle, US plastics sells glass bottles with teflon lid liners. Toluene seems to dissolve damn near every kind of plastic there is eventually, but Teflon is one plastic that is resistant to damn near everything. So far I have not found any info that Toluene will harm teflon.... ? The can it comes in has a plastic liner made of,,,, something? The toluene comes in a metal can, FWIW. I know places to buy smaller metal cans but they all have plastic linings, and I dunno which to get for this. There are also one-piece stainless-steel cans around too I guess, which might work too. I'd just have to find one that had a screw-on stainless lid,,,, and a liner made of ,,, what? teflon? For the applicator, I am thinking of just using a piece of glass lab tubing as a manual dropper. This would allow avoiding contaminating the jar. I'd like to find a plastic/rubber-bulb dropper that would hold maybe 2cc's at a time, but so far all I have found has not been suitable for this use. Any ideas? Also note: being just a Regular Guy, I can't buy anything from anywhere that requires a corporate account. |
#8
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Dispensing Toluene, anybody?........
On 12/14/2011 4:45 PM, Spehro Pefhany wrote:
Try he http://www.nalgenunc.com/techdata/chemical/ Looks like teflon is okay (30 days at 50°C), but it attacks many other kinds of plastics. I am aware of nalgene bottles and lab equipment, but places with info on its applications mainly talk about autoclave and chemical resistance used in medical/biological processes and toluene doesn't seem to be real common in them. Also note: being just a Regular Guy, I can't buy anything from anywhere that requires a corporate account. How did you get ahold of gallons of toluene then? ;-) .... Some paint stores still sell it in the US. Sherwin-Williams and Ace Hardware are two sources mentioned online. I got it at S-W because they were closest. I did not check at Ace. I asked for the smallest quantity they could get, and a gallon was about $27. They kinda looked at me funny but when I mentioned latex rubber casting, but I suppose that made some sense. I would have much rather just bought a quart, but oh well. I'm just happy I could still get any at all. Most chemical retailers in the USA normally won't sell to individuals at all now, due to liability--they only sell to schools and corporate accounts. |
#9
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Dispensing Toluene, anybody?........
technomaNge wrote: On 12/14/2011 03:37 PM, DougC wrote: I have a project that I need to use toluene to bond some rubber. I don't want to use any kind of rubber cement, as the bond is in... For the applicator, I am thinking of just using a piece of glass lab tubing as a manual dropper. This would allow avoiding contaminating the jar. I'd like to find a plastic/rubber-bulb dropper that would hold maybe 2cc's at a time, but so far all I have found has not been suitable for this use. Any ideas? Know anyone that injects (legal) medicines at home? Grab a used hyperdermic syringe, clean it, test it for toluene tolerance. Does he know anyone who uses Insulin? If it don't melt/dissolve, you are home free. technomaNge -- -- You can't have a sense of humor, if you have no sense. |
#10
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Dispensing Toluene, anybody?........
On 2011-12-15, Wild_Bill wrote:
Forgot to mench.. glass eye droppers (which was a fairly common term, but fading) are rapidly becoming replaced with plastics. I was on a quest to find some recently, and got a number of dumb looks, or shown plastic versions even though I asked about glass droppers. Finally spotted some of Rite Aid brand, 2-pack with a straight and an angled tip.. and made in the USA. The removable bulb part isn't rubber, some rubbery vinyl instead, but not melted by lacquer thinner, at least. I prefer glass, which is easy to clean, and indicates when it's not. Common ear swabs are a decent bore brush. If that source dries up -- do you remember chem lab in high school or college? Get some glass tubing, a small triangular file, and set up a propane torch (since you are not likely to have a Bunsen burner, and you can flare one end to fit the bulb, and draw down the diameter to make the small spout end -- to whatever size you really want. Enjoy, DoN. -- Remove oil spill source from e-mail Email: | Voice (all times): (703) 938-4564 (too) near Washington D.C. | http://www.d-and-d.com/dnichols/DoN.html --- Black Holes are where God is dividing by zero --- |
#11
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Dispensing Toluene, anybody?........
On Wed, 14 Dec 2011 17:08:44 -0600, DougC wrote:
On 12/14/2011 4:12 PM, Stanley Schaefer wrote: ... You DO know the stuff will do a number on your liver, if you're regularly exposed, right?.... .... Yea, I am aware of that. I don't need to use much at once (literally only 5-6 drops probably) and I won't need it often. As others have mentioned, pipettes are easy to make from glass or plastic tubing. However, they also are inexpensive on ebay: http://www.ebay.com/itm/100-Extended-Fine-Tip-Pippet-Pipet-1-0ml-50-drops-/170747397034?pt=LH_DefaultDomain_0&hash=item27c156 83aa Item number: 170747397034 The above are polyethylene, which is ok in toluene at room temperature but gets more soluble as temperature rises above 60C (140F). A lot of glass pipettes are available on ebay also. They cost several times more (eg 10 cents to a dollar each instead of 3 cents to 10 cents) http://www.ebay.com/sch/Disposables-/26414/i.html?_nkw=pipette*&_trkparms=65%253A12%257C66%25 3A2%257C39%253A1%257C72%253A5833&rt=nc&_trksid=p32 86.c0.m14.l1581&_pgn=2 -- jiw |
#12
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Dispensing Toluene, anybody?........
"DougC" wrote in message ... I have a project that I need to use toluene to bond some rubber. I don't want to use any kind of rubber cement, as the bond is in mid-process--after the rubber is dried but before it is vulcanized--and anything added may disrupt the final vulcanization of the rubber. -Plus, the only cements that would work would be 'industrial' ones that have a lot of toluene or xylene anyway (so they'd still be flammable/noxious) and still might not work as well. I can buy the toluene in a gallon can, but what I want is a smaller container for use, and a way to apply it easily a few drops at a time. For the smaller bottle, US plastics sells glass bottles with teflon lid liners. Toluene seems to dissolve damn near every kind of plastic there is eventually, but Teflon is one plastic that is resistant to damn near everything. So far I have not found any info that Toluene will harm teflon.... ? The can it comes in has a plastic liner made of,,,, something? The toluene comes in a metal can, FWIW. I know places to buy smaller metal cans but they all have plastic linings, and I dunno which to get for this. There are also one-piece stainless-steel cans around too I guess, which might work too. I'd just have to find one that had a screw-on stainless lid,,,, and a liner made of ,,, what? teflon? For the applicator, I am thinking of just using a piece of glass lab tubing as a manual dropper. This would allow avoiding contaminating the jar. I'd like to find a plastic/rubber-bulb dropper that would hold maybe 2cc's at a time, but so far all I have found has not been suitable for this use. Any ideas? Also note: being just a Regular Guy, I can't buy anything from anywhere that requires a corporate account. Without reading all the replies.... Get anything in nalgene, most scientific sellers would sell in 1s or 2s. http://www.scientificlabs.co.uk/product/BOT8856 |
#13
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Dispensing Toluene, anybody?........
On 12/15/2011 1:47 AM, Dennis wrote:
Without reading all the replies.... Get anything in nalgene, most scientific sellers would sell in 1s or 2s. http://www.scientificlabs.co.uk/product/BOT8856 Nope. It would have to be flourinated nalgene- http://www.usplastic.com/catalog/ite...3477&catid=651 and even then it is only good for temporary storage (shows damage after only seven days at 50C) nalgenecontainers.nuncbrand.com/PDF/Chemical%20Resistance%20Chart%20Detail.pdf Looks like only glass or metal here, with a teflon lid liner. |
#14
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Dispensing Toluene, anybody?........
On 15 Dec 2011 04:19:27 GMT, "DoN. Nichols"
wrote: On 2011-12-15, Wild_Bill wrote: Forgot to mench.. glass eye droppers (which was a fairly common term, but fading) are rapidly becoming replaced with plastics. I was on a quest to find some recently, and got a number of dumb looks, or shown plastic versions even though I asked about glass droppers. Finally spotted some of Rite Aid brand, 2-pack with a straight and an angled tip.. and made in the USA. The removable bulb part isn't rubber, some rubbery vinyl instead, but not melted by lacquer thinner, at least. I prefer glass, which is easy to clean, and indicates when it's not. Common ear swabs are a decent bore brush. If that source dries up -- do you remember chem lab in high school or college? Get some glass tubing, a small triangular file, and set up a propane torch (since you are not likely to have a Bunsen burner, and you can flare one end to fit the bulb, and draw down the diameter to make the small spout end -- to whatever size you really want. Or this? http://goo.gl/Sl0gB -- Silence is more musical than any song. -- Christina Rossetti |
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