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Question about shellac solvent
"RKG" wrote in message ... Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Rick Hi Rick - don't know the real answer to your question because being the chemistry genius that I am, I have no idea what methyl hydrate is. Though... you really shouldn't have any trouble finding denatured alcohol just about anywhere. Ace Hardware carries it, as do just about all of the chain hardware and home centers. It's really not that expensive to buy a gallon of the stuff and keep it around. You might want to also try automotive refinishing supply houses. Those guys often sell chemicals like that a lot cheaper than the home centers. -- -Mike- |
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Mike Marlow wrote:
"RKG" wrote in message .. . Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Rick Hi Rick - don't know the real answer to your question because being the chemistry genius that I am, I have no idea what methyl hydrate is. Though... you really shouldn't have any trouble finding denatured alcohol just about anywhere. Ace Hardware carries it, as do just about all of the chain hardware and home centers. It's really not that expensive to buy a gallon of the stuff and keep it around. You might want to also try automotive refinishing supply houses. Those guys often sell chemicals like that a lot cheaper than the home centers. Around here (Southern Ontario) all the places I have checked carry methyl hydrate (basically methyl alcohol) instead of denatured alcohol (ethyl alcohol with a poison added so you can't drink it). I'ts labelled as a shellac thinner. Rick |
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Mon, Dec 13, 2004, 10:42am (RKG) wants
to know: Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Comparing, I think I'd prefer to go with denatured alcohol. http://www.syndel.com/msds/denatured_ethanol_msds.html http://physchem.ox.ac.uk/MSDS/ME/methyl_hydrate.html If, and when, I switch to using shellac tho, I'm going to do some experimenting using ever-clear, instead. JOAT We cannot direct the wind, but we can adjust the sails. - unknown |
#4
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Ammonia can be used to clean after using shellac, not as pricey as
alcohol. On Mon, 13 Dec 2004 12:40:37 -0600, Robert Galloway wrote: Methanol. I used to use Solox brand MetOH to thin and clean shellac brushes and it worked great. Never started with the flakes so can't say how that would work but as a thinner, no problem. |
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I too am in Souther Ontario and don't know what to use. When your
certain either way, please speak up and let us know what you think. I can't find denatured alcohol anywhere. But I seem to recall that LV sells something called shellac thinner? John RKG wrote: Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Rick |
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Methanol. I used to use Solox brand MetOH to thin and clean shellac
brushes and it worked great. Never started with the flakes so can't say how that would work but as a thinner, no problem. Mike Marlow wrote: "RKG" wrote in message ... Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Rick Hi Rick - don't know the real answer to your question because being the chemistry genius that I am, I have no idea what methyl hydrate is. Though... you really shouldn't have any trouble finding denatured alcohol just about anywhere. Ace Hardware carries it, as do just about all of the chain hardware and home centers. It's really not that expensive to buy a gallon of the stuff and keep it around. You might want to also try automotive refinishing supply houses. Those guys often sell chemicals like that a lot cheaper than the home centers. |
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Eddie Munster wrote:
I too am in Souther Ontario and don't know what to use. When your certain either way, please speak up and let us know what you think. I can't find denatured alcohol anywhere. But I seem to recall that LV sells something called shellac thinner? John RKG wrote: Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Rick I'm trying both right now, as far as dissolving the flakes I see no difference and both dry equally fast. The methyl hydrate appears to be a little more toxic but compared to some of the other finishes we use it's not bad. The LV website lists their shellac thinner as a mixture of ethenol methenol - basically denatured alcohol. A 32 oz can -slightly less than 1 L is 10.95 a 4 L jug of methyl hydrate at my local home hardware is 7. less then 1/4 the price. Rick |
#8
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Shellac thinner will be some sort of alcohol or mixture of
alcohols. I should think that you can ask LV what's in theirs and they'd tell you. Ethanol is the least toxic of the alcohols. Methylated Spirits, methyl alcohol, methanol, and wood alcohol, are all the same thing. They will all disolve shellac, so will propyl and isopropyl alcohol but that usually has too much water in it to be a good shellac thinner. -- FF |
#9
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In article , Eddie Munster
wrote: I too am in Souther Ontario and don't know what to use. When your certain either way, please speak up and let us know what you think. I can't find denatured alcohol anywhere. But I seem to recall that LV sells something called shellac thinner? The LV stuff is denatured ethyl. I buy it when I can combine the shipping costs with other stuff, but by itself it's too expensive. As I posted earlier: Rubbing Alcohol Compound, United Pharmacists brand, packaged by RW Packaging (in Manitoba... No address but postal code is R2R 1V7). 95% ethyl. |
#10
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No problem with using methanol. Depending on your needs you might find it a
better solvent than ethanol due to it's lower boiling point (evaporates faster). I'm not 100 % sure, but the solubility of the shellac flakes in methanol might be better than in ethanol. "RKG" wrote in message ... Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Rick |
#11
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Might want to first find out why denatured isn't sold regularly. Here the
denaturing is to avoid excise tax on booze. Might come up against your "revenuers" if you tried. Given the deadl(ier) nature of methanol, I have to believe that there's some legal reason why it's what's available rather than ethanol. "JGS" wrote in message ... Hi Doug, If you know of anyone who might be interested in distributing denatured ethanol in the GTA or other parts of southern Ontario have them email me at woodpdg at sympaticodotca. JG |
#12
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Hi George,
Thanks for the heads-up but I have asked many, many clerks and managers in paint/finishing stores why they do not carry it. For the most part they do not know or care what they are selling. For those that do know, they tell me it is consumer resistance to spending more for ethanol over methanol. When I bring up the health concern they get that deer in the headlights look and then slink away. All it will take is a few stores to start carrying it and the rest will follow. Cheers, JG George wrote: Might want to first find out why denatured isn't sold regularly. Here the denaturing is to avoid excise tax on booze. Might come up against your "revenuers" if you tried. Given the deadl(ier) nature of methanol, I have to believe that there's some legal reason why it's what's available rather than ethanol. "JGS" wrote in message ... Hi Doug, If you know of anyone who might be interested in distributing denatured ethanol in the GTA or other parts of southern Ontario have them email me at woodpdg at sympaticodotca. JG |
#13
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It's a little amusing the responses contained in this thread regarding the
toxicity of methanol. I am willing to bet that if the op was about using mineral spirits or lacquer thinner, toxicity would nerver be mentioned. Just dont drink your solvents or bath in them and you will be ok. "RKG" wrote in message ... Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Rick |
#14
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Relative toxicity, and there are a lot of other things he's _not_ using, I'm
sure, which of course is not worthy of comment. http://www.bazellracefuels.com/Methanol.htm Check that bit about the odor threshold, and the ability to get a lethal dose from mucosa and through the skin. This is some truly bad sh*t, which does the same job as its less toxic cousin(s), one of which is even available in "food grade." "stoutman" wrote in message m... It's a little amusing the responses contained in this thread regarding the toxicity of methanol. I am willing to bet that if the op was about using mineral spirits or lacquer thinner, toxicity would nerver be mentioned. Just dont drink your solvents or bath in them and you will be ok. "RKG" wrote in message ... Most of the directions I have seen for shellac flakes call to dissolve them in denatured alcohol. Is there a problem with using methyl hydrate. It is certainly cheaper and easier to find around here. I've tried it on some small stuff and don't see any difference immediately. Rick |
#16
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Thanks for all the comments. Comments in general seemed to think it
would work fine so I used it with shellac flakes on a small cabinet I built for my grandson, it works fine. I don't spray and as with any of the solvents we use you take precautions. Having worked in nuclear plants for 27 years and continually taking safety courses, when I started woodworking after retiring my first purchases included an air cleaner that hangs from the ceiling and gets turned on whenever I am working in the shop, a dust collector and a dust respirator. Once I started doing finishing I got a chemical respirator and the cartridges get changed regularly. Since my 25' x 25' shop is in the basement I'll spend the extra and use the denatured alcohol LV sells in the winter when I can't really vent the shop outside like I do in the warmer weather. Rick |
#17
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Charlie Self wrote:
it, I could drive a few miles--Franklin, one county over is supposed to be one of the centers of the bootleg booze production in the South. Pick up some second run distilled stuff at nearly 200 proof. That should do 'er. My distant relations have NO idea what you're talking about. -- Michael McIntyre ---- Silvan Linux fanatic, and certified Geek; registered Linux user #243621 http://www.geocities.com/Paris/Rue/5407/ http://rosegarden.sourceforge.net/tutorial/ |
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#19
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"Andy Dingley" wrote in message ... On 13 Dec 2004 11:31:38 -0800, wrote: Methylated Spirits, methyl alcohol, methanol, and wood alcohol, are all the same thing. I thought you didn't have methylated spirits in the USA ? Anyway, UK (and AFAIK, everywhere) methylated spirits is a mixture of four things - ethanol, methanol (about 1/3rd), purple dye and pyridine (a stenching agent). The Canadian use of "methyl hydrate" was the original source of discussion. By name it would seem it really is wood alcohol, http://physchem.ox.ac.uk/MSDS/ME/methyl_hydrate.html which as we know is not the same a methylated (denatured) spirits http://www.birdbrand.co.uk/msds/Meth...%20Spirits.pdf. US doesn't add the dye to our mix, but the residue of some of the dehydrating agents can be tough on you, even in relatively small quantities. |
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Andy Dingley wrote: On 13 Dec 2004 11:31:38 -0800, wrote: Methylated Spirits, methyl alcohol, methanol, and wood alcohol, are all the same thing. I thought you didn't have methylated spirits in the USA ? Anyway, UK (and AFAIK, everywhere) methylated spirits is a mixture of four things - ethanol, methanol (about 1/3rd), purple dye and pyridine (a stenching agent). My mistake, I thought methylated spritis was a synomym for methanol. It may no longer be available but from your description I daresay methylated spritis may be very similar to what we used to use for mimeograph copies. Though from what I remember of the odor it did not have pyridine in it. -- FF .... When I can get hold of it (friends in the lab trade) I use pure lab-grade ethanol. This is safer because of not having the methanol in it, and it's much more pleasant to use as there's no pyridine. However the paperwork to get it is frightening, and the suppliers don't regard wood finishing as a suitable cause for supplying it. In many states pure ethanol, well, almost pure it has some water in it as does all ethanol once it is exposed to the air, is available in liquor stores. It is pure enough for use as shellac thinner and a number of folks prefer it for French Polishing. No paperwork, it simply has state taxes accessed on it that non-consumable alcohol mixtures do not. -- FF |
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I think the wood alcohol is poisonous and the grain alcohol is the
drinky kind. I think I have seen it for sale in booze stores? Where does ethanol fit in? |
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#23
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On Wed, 15 Dec 2004 12:30:03 -0500, Eddie Munster
wrote: I think the wood alcohol is poisonous and the grain alcohol is the drinky kind. Ethanol, good stuff, sometimes called "grain alcohol". Methanol, bad stuff, sometimes called "wood alcohol". |
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Eddie Munster writes:
I think the wood alcohol is poisonous and the grain alcohol is the drinky kind. I think I have seen it for sale in booze stores? Wood alcohol is methanol. Where does ethanol fit in? Thats the stuff in beer and wine. It would be the best solvent, because it's not so very poisonous (after all it you drink...), but because you can drink it it's loaded with a very heavy tax that makes it very expensive if bought without any nasty stuff mixed in. BTW: glycerine is also an alcohol.. -- Dr. Juergen Hannappel http://lisa2.physik.uni-bonn.de/~hannappe Phone: +49 228 73 2447 FAX ... 7869 Physikalisches Institut der Uni Bonn Nussallee 12, D-53115 Bonn, Germany CERN: Phone: +412276 76461 Fax: ..77930 Bat. 892-R-A13 CH-1211 Geneve 23 |
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Andy Dingley writes:
On 15 Dec 2004 14:25:02 GMT, otforme (Charlie Self) wrote: Jeez. I just buy whatever the paint store has in stock We have _huge_ taxes on retail drinkable alcohol. As a result, "non-drinking" alcohol is very difficult to get hold of. We also have practically no moonshine distilling. If you're so inclined, you're more likely to be making strong cider or beer. Well, nuts to that. I don't drink these days, but back in my boozing days, I can recall hitting some white lightning that really lived up to its name. By the 4th ounce or so, you thought you'd been hit by lightning. If you took another ounce, you woke up wishing you would BE hit by lightning. Charlie Self "He has all the virtues I dislike and none of the vices I admire." Sir Winston Churchill |
#26
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Eddie Munster wrote:
I think the wood alcohol is poisonous and the grain alcohol is the drinky kind. I think I have seen it for sale in booze stores? Where does ethanol fit in? There are many kinds of alcohol. From a chemical point of view, the word "alcohol" describes a large class of chemical compounds containing an OH group connected to a carbon atom. The three most common alcohols most lay people hear about are methanol, ethanol, and isopropanol. What is commonly called "wood alchol" is methanol, and yes it is poisonous, even in very small amounts. Grain alcohol is ethanol. In large quantities, it too is poisonous, as a few unfortunate college kids find out every year; chug a quart of whisky and you'll probably be dead before the night is out. Absolute ethanol (not to be confused with the Absolut brand of vodka) is just very pure ethanol. This has no water in it (unlike vodka, which is more or less half water, depending on the proof). It is generally only available by special license to industrial customers. There are also other extremely pure grades of ethanol (reagent grade, spectroscopic grade, etc) which are increasingly more pure, and increasingly more expensive. Denatured Alcohol is absolute ethanol with a little methanol added to it, to intentionally make it unfit to drink. Since you can't drink it, the government isn't interested in taxing or controlling it, and it's much more widely available than absolute. For most uses as an industrial solvent (such as for disolving shelac), the little bit of methanol doesn't really matter. If memory serves, the addition of the methanol also aids in the removal of the last bits of water during the distilation process. What's sold in most drugstores as "rubbing alcohol" is isopropanol (typically 70%, the rest is water). To the best of my knowlege, it's not toxic, at least in small quantities. The reason it's sold in drug stores is because it evaporates fast, so it makes a great cooling rubdown. |
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#28
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"Andy Dingley" wrote in message ... On Wed, 15 Dec 2004 12:30:03 -0500, Eddie Munster wrote: I think the wood alcohol is poisonous and the grain alcohol is the drinky kind. Ethanol, good stuff, sometimes called "grain alcohol". Or Vodka.... Check the LD50, and it's not so benign either, though I have booked 0.36 that was still more or less upright. 95% is as good as it gets with ethanol, because the 95/5 azeotrope prevents further distillation. Anything beyond has to be dried another way, some of which are nastier than the methanol. |
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#31
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Charlie Self wrote:
My distant relations have NO idea what you're talking about. Just don't buy that bridge they keep trying to sell you. Sell? That would be illegal. They GIVE the stuff away. -- Michael McIntyre ---- Silvan Linux fanatic, and certified Geek; registered Linux user #243621 http://www.geocities.com/Paris/Rue/5407/ http://rosegarden.sourceforge.net/tutorial/ |
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Charlie Self wrote:
If I could find Everclear locally I'd be using it, just for the convenience - even with the taxes on it. Next time you hit Richmond or some other semi-Southern city, check out the local ABC store. They'll have Everclear, though possibly not by that name. Not anymore, I don't think. Could just be local, but I'm fairly sure it has been banned statewide. After too many dumbass college students accidentally committed suicide. Nasty stuff to drink by itself, though, unless you're already ripped. IIRC, most of it goes into punch bowls for the unwary, often at church picnics. None for me, thanks. I get pretty well hammered from three **** water American beers. I think if I ever had a shot of Everclear, I'd go straight for the coma. -- Michael McIntyre ---- Silvan Linux fanatic, and certified Geek; registered Linux user #243621 http://www.geocities.com/Paris/Rue/5407/ http://rosegarden.sourceforge.net/tutorial/ |
#33
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Xane T. wrote:
It's not always methanol. The bottle of Ace brand denatured alcohol is denatured with both methanol and MEK, it's more poisonous than it needs to be. I think the Kleen Strip brand is the one that has only methanol to denature it. Urk! What does MEK do to shellac? Nothing good, I would imagine. That's vile stuff, but it sure is great for bonding styrene. -- Michael McIntyre ---- Silvan Linux fanatic, and certified Geek; registered Linux user #243621 http://www.geocities.com/Paris/Rue/5407/ http://rosegarden.sourceforge.net/tutorial/ |
#34
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Charlie Self wrote:
name. By the 4th ounce or so, you thought you'd been hit by lightning. If you took another ounce, you woke up wishing you would BE hit by lightning. And the people who took the 5th ounce ended up in the mortuary. Good ol' corn squeezin's. -- Michael McIntyre ---- Silvan Linux fanatic, and certified Geek; registered Linux user #243621 http://www.geocities.com/Paris/Rue/5407/ http://rosegarden.sourceforge.net/tutorial/ |
#35
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rcook5 notes:
Jeez. I just buy whatever the paint store has in stock. If it came down to it, I could drive a few miles--Franklin, one county over is supposed to be one of the centers of the bootleg booze production in the South. Pick up some second run distilled stuff at nearly 200 proof. That should do 'er. Charlie Self "He has all the virtues I dislike and none of the vices I admire." Sir Winston Churchill Here in the US you can just pick up some Everclear at the liquor store. Expensive as a solvent for shellac, but it gives great results. Yes, well when you do that, you're paying the Feds the current $44 or whatever per gallon in booze tax. Charlie Self "He has all the virtues I dislike and none of the vices I admire." Sir Winston Churchill |
#36
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The college students can steal the 95% from Organic lab, like we did. They
don't need to pay the money. Gallon of it, can each of whatever Hi-C juices were on the shelf to make up a 5-gallon Jerrycan worth, and off to the dunes.... "Silvan" wrote in message ... Charlie Self wrote: If I could find Everclear locally I'd be using it, just for the convenience - even with the taxes on it. Next time you hit Richmond or some other semi-Southern city, check out the local ABC store. They'll have Everclear, though possibly not by that name. Not anymore, I don't think. Could just be local, but I'm fairly sure it has been banned statewide. After too many dumbass college students accidentally committed suicide. |
#37
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Charlie Self wrote:
rcook5 notes: Jeez. I just buy whatever the paint store has in stock. If it came down to it, I could drive a few miles--Franklin, one county over is supposed to be one of the centers of the bootleg booze production in the South. Pick up some second run distilled stuff at nearly 200 proof. That should do 'er. Charlie Self "He has all the virtues I dislike and none of the vices I admire." Sir Winston Churchill Here in the US you can just pick up some Everclear at the liquor store. Expensive as a solvent for shellac, but it gives great results. Yes, well when you do that, you're paying the Feds the current $44 or whatever per gallon in booze tax. I'm curious--anybody have any experiences to relate with Behlen's "Behkol", which they sell as purpose-made for dissolving shellac flakes and which appears to be ethanol denatured with isobutanol instead of methanol. They charge a good deal more for it than one pays for regular denatured alcohol. Charlie Self "He has all the virtues I dislike and none of the vices I admire." Sir Winston Churchill -- --John Reply to jclarke at ae tee tee global dot net (was jclarke at eye bee em dot net) |
#38
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George wrote: The college students can steal the 95% from Organic lab, like we did. Unless it was spectrophotometric grade, which would be very expensive, the other 5% might have included benzene. For that matter, there are denatured alcohols sold for rubbing alcohol and shellac thinner that are 95% ethanol. -- FF |
#39
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Xane T. wrote:
On 15 Dec 2004 13:12:17 -0500, (Roy Smith) wrote: Denatured Alcohol is absolute ethanol with a little methanol added to it, to intentionally make it unfit to drink. Since you can't drink it, the government isn't interested in taxing or controlling it, and it's much more widely available than absolute. For most uses as an industrial solvent (such as for disolving shelac), the little bit of methanol doesn't really matter. If memory serves, the addition of the methanol also aids in the removal of the last bits of water during the distilation process. It's not always methanol. The bottle of Ace brand denatured alcohol is denatured with both methanol and MEK, it's more poisonous than it needs to be. I think the Kleen Strip brand is the one that has only methanol to denature it. ISTR that the brand with "SLX" on the label was denatured with methanol only. I avoid anything with ketones because they are quite toxic as well as more noisome. At one time sulphuric acid was used as a denaturant. I remember an episode of "Untouchables" with Robert Stack as Eliot Ness in which the villian was a chemist who had found a way to 'renature' denatured alcohol. Assuming there was _some_ historical basis for that episode this may have been a referance to using sulphuric acid as a denaturant. What's sold in most drugstores as "rubbing alcohol" is isopropanol (typically 70%, the rest is water). To the best of my knowlege, it's not toxic, at least in small quantities. The reason it's sold in drug stores is because it evaporates fast, so it makes a great cooling rubdown. All alcohols are toxic. Ethanol is just the least toxic, well maybe some of the fancy alcohols used in mouthwash might be less toxic than ethanol but I doubt it. Isopropynol is plenty toxic, you just do not absorb enough through occaisional exposure to unbroken skin to be a concern. I _think_ methanol is better absorbed through the skin, but is less toxic when ethanol is also present, oddly enough. In fact I'm pretty sure that all organic solvents and almost all organic liquids, excepting some oils, are toxic. Certainly all the common ones are *quite* toxic. ... Ethyl alcohol is also sold as 'rubbing alcohol', which I believe is also a form of denatured ethanol. The label I read at CVS last night had all sorts of odd ingredients in it other than ethyl alcohol, in fact it looked /more/ poisonous than woodworking denatured stuff. Quite often the ethyl alcohol (aka ethanol, aka grain alcohol) sold for rubbing alcohol is denatured with methanol just like the denatured alcohol sold for shellac thinner. The other stuff on the label may well have been added to enhance it's effect when used for, well, rubbing, or whatever you're supposed to do with it. -- FF |
#40
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On Wed, 15 Dec 2004 13:59:33 +0000, Andy Dingley
wrote: On 13 Dec 2004 11:31:38 -0800, wrote: Methylated Spirits, methyl alcohol, methanol, and wood alcohol, are all the same thing. snip Filter the meths through a hollowed out half loaf of bread. Colour gone, pyride gone. Drinkable. Ask any seasoned hobo. A bottle of meths is a lot cheaper than anything in the bottle store. |
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