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UK diy (uk.d-i-y) For the discussion of all topics related to diy (do-it-yourself) in the UK. All levels of experience and proficency are welcome to join in to ask questions or offer solutions. |
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#1
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Drain blocked with caustic soda
I poured caustic soda down my shower hole and it has harderned any leads ?
Im panicking -- for full context, visit https://www.homeownershub.com/uk-diy...a-1391099-.htm |
#2
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Drain blocked with caustic soda
On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote:
I poured caustic soda down my shower hole and it has harderned any leads ? Im panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. NT |
#3
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Drain blocked with caustic soda
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#4
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Drain blocked with caustic soda
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#6
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Drain blocked with caustic soda
On 30/10/2019 08:07, Ian Jackson wrote:
In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, JakeÂ* wrote: I poured caustic soda down my shower hole and it has harderned any leads ? Im panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? The same bottle has IME done both depending in the concentration of added water. .. -- Its easier to fool people than to convince them that they have been fooled. Mark Twain |
#7
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Drain blocked with caustic soda
On 30/10/19 08:07, Ian Jackson wrote:
In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote: I poured caustic soda down my shower hole and it has harderned any leads ? Im panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." -- Jeff |
#8
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Drain blocked with caustic soda
Yes, seriously, I know of a drain that was blown apart by the reaction,
which was not nice for anyone in splatter range. Brian -- ----- -- This newsgroup posting comes to you directly from... The Sofa of Brian Gaff... Blind user, so no pictures please Note this Signature is meaningless.! "Jeff Layman" wrote in message ... On 30/10/19 02:54, wrote: On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote: I poured caustic soda down my shower hole and it has harderned any leads ? I'm panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Whatever you do, do it slowly and do not use boiling water to try to speed things up. Caustic soda solidified in a drain might have a layer of sodium carbonate covering it (it is very efficient at removing carbon dioxide from the air). That carbonate layer dissolves a lot more slowly than caustic soda itself. Once the caustic soda is exposed, it can react unpredictably and sometimes almost explosively with boiling water. As NT says, it can blind you if it shoots out of from the drain hole as a hot, concentrated, highly corrosive solution. At the very least, good eye protection is essential, and a full-face mask makes sense if you already have one. -- Jeff |
#9
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Drain blocked with caustic soda
In message , Jeff Layman
writes On 30/10/19 08:07, Ian Jackson wrote: In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote: I poured caustic soda down my shower hole and it has harderned any leads ? Im panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." Thanks. I'll study that. One thing I didn't mention was that my water is extremely hard, and it may be the calcium that does it. However, it does seem that some brands of caustic soda are worse than others. -- Ian |
#10
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Drain blocked with caustic soda
Ian Jackson wrote:
In message , Jeff Layman writes On 30/10/19 08:07, Ian Jackson wrote: In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote: I poured caustic soda down my shower hole and it has harderned any leads ? I'm panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." Thanks. I'll study that. One thing I didn't mention was that my water is extremely hard, and it may be the calcium that does it. However, it does seem that some brands of caustic soda are worse than others. My guess would be the size and shape of the pellets and the rate of adding water would be important factors. Aren't you supposed to gradually add the NaOH to the water and use the solution? -- Roger Hayter |
#11
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Drain blocked with caustic soda
"Roger Hayter" wrote in message
... My guess would be the size and shape of the pellets and the rate of adding water would be important factors. Aren't you supposed to gradually add the NaOH to the water and use the solution? And, as with any dangerous solid or liquid (eg exothermic in contact with water), always add solid/liquid to an excess of water rather than water to an excess of solid/liquid. Had that drummed into me in chemistry lessons! |
#12
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Drain blocked with caustic soda
NY wrote:
"Roger Hayter" wrote in message ... My guess would be the size and shape of the pellets and the rate of adding water would be important factors. Aren't you supposed to gradually add the NaOH to the water and use the solution? And, as with any dangerous solid or liquid (eg exothermic in contact with water), always add solid/liquid to an excess of water rather than water to an excess of solid/liquid. Had that drummed into me in chemistry lessons! Agreed. That's what I meant by 'gradually' - but I could have stated it more clearly. -- Roger Hayter |
#13
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Drain blocked with caustic soda
On 30/10/2019 13:37, Roger Hayter wrote:
Ian Jackson wrote: In message , Jeff Layman writes On 30/10/19 08:07, Ian Jackson wrote: In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote: I poured caustic soda down my shower hole and it has harderned any leads ? I'm panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." Thanks. I'll study that. One thing I didn't mention was that my water is extremely hard, and it may be the calcium that does it. However, it does seem that some brands of caustic soda are worse than others. My guess would be the size and shape of the pellets and the rate of adding water would be important factors. Aren't you supposed to gradually add the NaOH to the water and use the solution? That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. -- €œIdeas are inherently conservative. They yield not to the attack of other ideas but to the massive onslaught of circumstance" - John K Galbraith |
#14
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Drain blocked with caustic soda
On 30/10/2019 14:19, NY wrote:
"Roger Hayter" wrote in message ... MyÂ*Â* guess would be the size and shape of the pellets and the rate of adding water would be important factors.Â* Aren't you supposed to gradually add the NaOH to the water and use the solution? And, as with any dangerous solid or liquid (eg exothermic in contact with water), always add solid/liquid to an excess of water rather than water to an excess of solid/liquid. Had that drummed into me in chemistry lessons! It's the safe and less useful way, yes. As I said, try it the other way after making sure you have old clothes and eye protection. -- €œIdeas are inherently conservative. They yield not to the attack of other ideas but to the massive onslaught of circumstance" - John K Galbraith |
#15
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Drain blocked with caustic soda
"The Natural Philosopher" wrote in message ... On 30/10/2019 13:37, Roger Hayter wrote: Ian Jackson wrote: In message , Jeff Layman writes On 30/10/19 08:07, Ian Jackson wrote: In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote: I poured caustic soda down my shower hole and it has harderned any leads ? I'm panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." Thanks. I'll study that. One thing I didn't mention was that my water is extremely hard, and it may be the calcium that does it. However, it does seem that some brands of caustic soda are worse than others. My guess would be the size and shape of the pellets and the rate of adding water would be important factors. Aren't you supposed to gradually add the NaOH to the water and use the solution? That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. |
#16
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More Heavy Trolling by Senile Nym-Shifting Rodent Speed!
On Thu, 31 Oct 2019 07:20:17 +1100, Chang, better known as cantankerous
trolling senile geezer Rodent Speed, wrote: Which might be a problem with modern plastic drain pipes. Can't be as much of a problem as you are, you abnormal trolling senile pest! -- Website (from 2007) dedicated to the 85-year-old trolling senile cretin from Oz: https://www.pcreview.co.uk/threads/r...d-faq.2973853/ |
#17
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Drain blocked with caustic soda
On 30/10/2019 20:20, Chang wrote:
"The Natural Philosopher" wrote in message ... On 30/10/2019 13:37, Roger Hayter wrote: Ian Jackson wrote: In message , Jeff Layman writes On 30/10/19 08:07, Ian Jackson wrote: In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, JakeÂ* wrote: I poured caustic soda down my shower hole and it has harderned any leads ? I'm panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." Thanks. I'll study that. One thing I didn't mention was that my water is extremely hard, and it may be the calcium that does it. However, it does seem that some brands of caustic soda are worse than others. MyÂ*Â* guess would be the size and shape of the pellets and the rate of adding water would be important factors.Â* Aren't you supposed to gradually add the NaOH to the water and use the solution? That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free -- The New Left are the people they warned you about. |
#18
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Drain blocked with caustic soda
"The Natural Philosopher" wrote in message
... That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It's the heat that would be the problem, not the pressure. Solid NaOH (crystals) gives out a lot of heat when it dissolves in water. Added to the fact that the water is already boiling, you could cause the pipe to soften or even melt. |
#19
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Drain blocked with caustic soda
On Thursday, 31 October 2019 13:14:15 UTC, NY wrote:
"The Natural Philosopher" wrote in message ... That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It's the heat that would be the problem, not the pressure. Solid NaOH (crystals) gives out a lot of heat when it dissolves in water. Added to the fact that the water is already boiling, you could cause the pipe to soften or even melt. The water can't get above 100C, it just forms steam to carry the excess heat away. Harmless to any drain pipe. As for pressure, you can't make any when there's only one blockage, there's nowhere closed. If you artifically made 2 blockages, even then the materials blocking drain pipes won't contain any significant pressure. IOW the alarmism is bs. NT |
#20
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More Heavy Trolling by Senile Nym-Shifting Rodent Speed!
On Fri, 1 Nov 2019 05:48:51 +1100, Chang, better known as cantankerous
trolling senile geezer Rodent Speed, wrote: One end is always free It clearly isnt LOL in auto-contradicting mode again, sociopathic troll from Oz? -- Kerr-Mudd,John addressing senile Rot: "Auto-contradictor Rod is back! (in the KF)" MID: |
#21
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Drain blocked with caustic soda
"The Natural Philosopher" wrote in message ... On 30/10/2019 20:20, Chang wrote: "The Natural Philosopher" wrote in message ... On 30/10/2019 13:37, Roger Hayter wrote: Ian Jackson wrote: In message , Jeff Layman writes On 30/10/19 08:07, Ian Jackson wrote: In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote: I poured caustic soda down my shower hole and it has harderned any leads ? I'm panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." Thanks. I'll study that. One thing I didn't mention was that my water is extremely hard, and it may be the calcium that does it. However, it does seem that some brands of caustic soda are worse than others. My guess would be the size and shape of the pellets and the rate of adding water would be important factors. Aren't you supposed to gradually add the NaOH to the water and use the solution? That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It clearly isnt if there is lots of pressure. |
#22
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Drain blocked with caustic soda
On 31/10/2019 13:13, NY wrote:
"The Natural Philosopher" wrote in message ... That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It's the heat that would be the problem, not the pressure. Solid NaOH (crystals) gives out a lot of heat when it dissolves in water. Added to the fact that the water is already boiling, you could cause the pipe to soften or even melt. It never has yet As you probably do not understand, plastic waste pipes can take boiling water, and boiling solutions of caustic sodoaq boilss at approximately the same temperature. -- How fortunate for governments that the people they administer don't think. Adolf Hitler |
#23
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Drain blocked with caustic soda
On 31/10/2019 18:48, Chang wrote:
"The Natural Philosopher" wrote in message ... On 30/10/2019 20:20, Chang wrote: "The Natural Philosopher" wrote in message ... On 30/10/2019 13:37, Roger Hayter wrote: Ian Jackson wrote: In message , Jeff Layman writes On 30/10/19 08:07, Ian Jackson wrote: In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, JakeÂ* wrote: I poured caustic soda down my shower hole and it has harderned any leads ? I'm panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." Thanks. I'll study that. One thing I didn't mention was that my water is extremely hard, and it may be the calcium that does it. However, it does seem that some brands of caustic soda are worse than others. MyÂ*Â* guess would be the size and shape of the pellets and the rate of adding water would be important factors.Â* Aren't you supposed to gradually add the NaOH to the water and use the solution? That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It clearly isnt if there is lots of pressure. 'lots of pressure' is relative to 'none at all' The vigorous boiling: - heats the fat berg - adds pressure at the base of the accessible water column in terms of short duration pulses. It's a bit like a hammer drill. It is not like a shotgun cartridge. Or pumping up a car tyre Experience suggests that it is highly effective at dislodging congealed fat and represents no danger to pipework and only a small danger to stupid people who lean over to see whats going on without glasses on. But then, I have tried it many times and you obviously have not. -- Its easier to fool people than to convince them that they have been fooled. Mark Twain |
#24
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Drain blocked with caustic soda
"The Natural Philosopher" wrote in message ... On 31/10/2019 18:48, Chang wrote: "The Natural Philosopher" wrote in message ... On 30/10/2019 20:20, Chang wrote: "The Natural Philosopher" wrote in message ... On 30/10/2019 13:37, Roger Hayter wrote: Ian Jackson wrote: In message , Jeff Layman writes On 30/10/19 08:07, Ian Jackson wrote: In message , writes On Wednesday, 30 October 2019 02:44:07 UTC, Jake wrote: I poured caustic soda down my shower hole and it has harderned any leads ? I'm panicking water dissolves it. Vinegar dissolves it faster, but beware of splash from caustic, a chemical that can blind you. Some brands of caustic soda 'harden'. With others, there's a rapid, heat-producing reaction with the water, and dissolve totally without a trace. Why is this? Have the former been 'cut' - ie something has added to bulk it out (such as washing soda)? It's probably due to the amount of water added and the complex hydrates sodium hydroxide forms with water, particularly the eutectic mixtures of varying solubility: https://en.wikipedia.org/wiki/Sodium_hydroxide#Hydrates "A hot water solution containing 73.1% (mass) of NaOH is an eutectic that solidifies at about 62.63 °C as an intimate mix of anhydrous and monohydrate crystals." Thanks. I'll study that. One thing I didn't mention was that my water is extremely hard, and it may be the calcium that does it. However, it does seem that some brands of caustic soda are worse than others. My guess would be the size and shape of the pellets and the rate of adding water would be important factors. Aren't you supposed to gradually add the NaOH to the water and use the solution? That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It clearly isnt if there is lots of pressure. 'lots of pressure' is relative to 'none at all' The vigorous boiling: - heats the fat berg - adds pressure at the base of the accessible water column in terms of short duration pulses. It's a bit like a hammer drill. It is not like a shotgun cartridge. Or pumping up a car tyre Experience suggests that it is highly effective at dislodging congealed fat and represents no danger to pipework and only a small danger to stupid people who lean over to see whats going on without glasses on. But then, I have tried it many times and you obviously have not. I have actually, but I have earthenware pipes. And a mate of mine, a plumber, used to be keen on pouring a Winchester of conc nitric acid into blocked drains and did find that worked very well. That as in the days before plastic drain pipes too. |
#25
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More Heavy Trolling by Senile Nym-Shifting Rodent Speed!
On Fri, 1 Nov 2019 19:47:42 +1100, Chang, better known as cantankerous
trolling senile geezer Rodent Speed, wrote: I have actually, but I have earthenware pipes. Shut your stupid senile gob, you stupid nym-shifting senile cretin from Oz! -- addressing nym-shifting senile Rodent: "You on the other hand are a heavyweight bull****ter who demonstrates your particular prowess at it every day." MID: |
#26
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Drain blocked with caustic soda
On 01/11/2019 07:33, The Natural Philosopher wrote:
On 31/10/2019 13:13, NY wrote: "The Natural Philosopher" wrote in message ... That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It's the heat that would be the problem, not the pressure. Solid NaOH (crystals) gives out a lot of heat when it dissolves in water. Added to the fact that the water is already boiling, you could cause the pipe to soften or even melt. It never has yet As you probably do not understand, plastic waste pipes can take boiling water, and boiling solutions of caustic sodoaq boilss at approximately the same temperature. Unless the temperature gets to boiling point rapidly and the steam cannot escape, whereupon the temperature could well get over 100C. Steam burns cause skin a lot of damage very quickly. |
#27
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Drain blocked with caustic soda
On Friday, 1 November 2019 16:06:35 UTC, Andrew wrote:
On 01/11/2019 07:33, The Natural Philosopher wrote: On 31/10/2019 13:13, NY wrote: "The Natural Philosopher" wrote in message ... That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It's the heat that would be the problem, not the pressure. Solid NaOH (crystals) gives out a lot of heat when it dissolves in water. Added to the fact that the water is already boiling, you could cause the pipe to soften or even melt. It never has yet As you probably do not understand, plastic waste pipes can take boiling water, and boiling solutions of caustic sodoaq boilss at approximately the same temperature. Unless the temperature gets to boiling point rapidly and the steam cannot escape, whereupon the temperature could well get over 100C. Steam burns cause skin a lot of damage very quickly. Someone must have their head wedged firmly down the drain for all that to happen. |
#28
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Drain blocked with caustic soda
On 01/11/2019 16:06, Andrew wrote:
On 01/11/2019 07:33, The Natural Philosopher wrote: On 31/10/2019 13:13, NY wrote: "The Natural Philosopher" wrote in message ... That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It's the heat that would be the problem, not the pressure. Solid NaOH (crystals) gives out a lot of heat when it dissolves in water. Added to the fact that the water is already boiling, you could cause the pipe to soften or even melt. It never has yet As you probably do not understand, plastic waste pipes can take boiling water, and boiling solutions of caustic sodoaq boilss at approximately the same temperature. Unless the temperature gets to boiling point rapidly and the steam cannot escape, whereupon the temperature could well get over 100C. How -= if te water can get to it, can te steam NOT escape? Steam burns cause skin a lot of damage very quickly. Christ you are handwavery received wisdom WIMP Have you ever done ANYTHING in real life? -- Theres a mighty big difference between good, sound reasons and reasons that sound good. Burton Hillis (William Vaughn, American columnist) |
#29
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Drain blocked with caustic soda
On 01/11/19 07:33, The Natural Philosopher wrote:
On 31/10/2019 13:13, NY wrote: "The Natural Philosopher" wrote in message ... That's the namby way to do it, yes, but Real Men„¢ fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It's the heat that would be the problem, not the pressure. Solid NaOH (crystals) gives out a lot of heat when it dissolves in water. Added to the fact that the water is already boiling, you could cause the pipe to soften or even melt. It never has yet As you probably do not understand, plastic waste pipes can take boiling water, and boiling solutions of caustic sodoaq boilss at approximately the same temperature. Yes and no. Most certainly, PVC pipes can withstand boiling water. It's not easy to find a specific figure, but the melting point of PVC in the form it is used in pipes is probably around 200 deg C. What temperature it might start to soften at, and lose some physical strength is another matter, but it should still be fine for use as a waste pipe. With polyethylene, it's a different matter. Sources give the melting point as between 120 and 141 deg C, but, of course, it softens at a much lower temperature as anyone who has poured boiling water into a PE container will have found out. So anyone who tries to use PE pipe for waste could be in for a nasty surprise if they pour boiling water down it. How much of a surprise if caustic soda is used can be calculated - to some extent. A bit of Googling will show that when sodium hydroxide is dissolved in water it releases 44kJ of energy per mole - in other words about 250 calories per gram. One calorie will raise the temperature of one gram of water by 1 deg C. So, for example, adding one gram of sodium hydroxide to half a teaspoon (2.5 ml) of water at freezing point will raise its temperature to boiling point. And adding more will raise its temperature *above* boiling point. Well above boiling point, in fact, and not "...approximately the same temperature". If you look at Graph 1 on page 31 he https://www.oxy.com/OurBusinesses/Chemicals/Products/Documents/CausticSoda/caustic.pdf you will see that a 50% solution of sodium hydroxide boils at about 142 deg C at atmospheric pressure (and so even higher if under pressure in a blocked pipe). In other words, the temperature of the solution will be above the melting point of polyethylene. -- Jeff |
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Drain blocked with caustic soda
"Jeff Layman" wrote in message ... On 01/11/19 07:33, The Natural Philosopher wrote: On 31/10/2019 13:13, NY wrote: "The Natural Philosopher" wrote in message ... That's the namby way to do it, yes, but Real MenT fill the u-bend up and pour a boiling kettle down. That shifts any fatbergs you get superheated pure NaOH and lots of pressure. Which might be a problem with modern plastic drain pipes. It isn't One end is always free It's the heat that would be the problem, not the pressure. Solid NaOH (crystals) gives out a lot of heat when it dissolves in water. Added to the fact that the water is already boiling, you could cause the pipe to soften or even melt. It never has yet As you probably do not understand, plastic waste pipes can take boiling water, and boiling solutions of caustic sodoaq boilss at approximately the same temperature. Yes and no. Most certainly, PVC pipes can withstand boiling water. It's not easy to find a specific figure, but the melting point of PVC in the form it is used in pipes is probably around 200 deg C. What temperature it might start to soften at, and lose some physical strength is another matter, but it should still be fine for use as a waste pipe. With polyethylene, it's a different matter. Sources give the melting point as between 120 and 141 deg C, but, of course, it softens at a much lower temperature as anyone who has poured boiling water into a PE container will have found out. So anyone who tries to use PE pipe for waste could be in for a nasty surprise if they pour boiling water down it. How much of a surprise if caustic soda is used can be calculated - to some extent. A bit of Googling will show that when sodium hydroxide is dissolved in water it releases 44kJ of energy per mole - in other words about 250 calories per gram. One calorie will raise the temperature of one gram of water by 1 deg C. So, for example, adding one gram of sodium hydroxide to half a teaspoon (2.5 ml) of water at freezing point will raise its temperature to boiling point. And adding more will raise its temperature *above* boiling point. Well above boiling point, in fact, and not "...approximately the same temperature". If you look at Graph 1 on page 31 he https://www.oxy.com/OurBusinesses/Chemicals/Products/Documents/CausticSoda/caustic.pdf you will see that a 50% solution of sodium hydroxide boils at about 142 deg C at atmospheric pressure (and so even higher if under pressure in a blocked pipe). In other words, the temperature of the solution will be above the melting point of polyethylene. Regardless of its effect on the pipe itself, I'd imagine a bigger concern might be its effect on any joints. As basically the last thing anyone needs are leaking joints in inaccessible places. michael adams .... |
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