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Metalworking (rec.crafts.metalworking) Discuss various aspects of working with metal, such as machining, welding, metal joining, screwing, casting, hardening/tempering, blacksmithing/forging, spinning and hammer work, sheet metal work. |
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#1
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Does anyone have experience with cyanide-free silver plating? How does it
compare? Second question, does anyone know how to go about getting potassium cyanide in the UK? You used to be able to get it from a chemist's shop by signing a poisons register, but I don't know if that still holds - and chemists don't seem to sell that kind of thing any more. -- Peter Fairbrother |
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"Peter Fairbrother" wrote in message
... Does anyone have experience with cyanide-free silver plating? How does it compare? Second question, does anyone know how to go about getting potassium cyanide in the UK? You used to be able to get it from a chemist's shop by signing a poisons register, but I don't know if that still holds - and chemists don't seem to sell that kind of thing any more. You will probably need to get it from a chemical supply company. When I was about 12 years old I worked out a way to make it from potassium ferrocyanide, which was easy to get hold of as it wasn't very toxic and often used in photography. Leon |
#3
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If there are jewellers/goldsmith supply houses and you are a customer
with a buisiness presence they might sell to you, they will not deliver to a residence as far as I know. Nasty stuff in a world filled with fools. |
#4
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![]() "Peter Fairbrother" wrote in message ... Does anyone have experience with cyanide-free silver plating? How does it compare? Second question, does anyone know how to go about getting potassium cyanide in the UK? You used to be able to get it from a chemist's shop by signing a poisons register, but I don't know if that still holds - and chemists don't seem to sell that kind of thing any more. -- Peter Fairbrother Can't answer your question about cyanide free plating, but here in the States the jewelry supply houses generally sell plating solutions. It's not exactly an economical way to get where you're trying to go, but better than never getting there. It's getting almost impossible to buy chemicals of any kind here in the States. You might consider talking to a plating house to see if they'd be willing to sell you what little you may need, assuming it's not against regs in your country. Dunno. Harold |
#5
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It's getting almost impossible to buy chemicals of
any kind here in the States. Bought a gallon of nitric acid ~12 years ago, waltzed right in an paid for it and waltzed right on out. Had I dropped the [glass] bottle in the parking lot it would have evaced the block. Meebee its a good thing them regs is tough now. still have 3/4 of that bottle and sweat bullets every time I have to move it. |
#6
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Harold and Susan Vordos wrote:
"Peter Fairbrother" wrote in message ... Does anyone have experience with cyanide-free silver plating? How does it compare? Second question, does anyone know how to go about getting potassium cyanide in the UK? You used to be able to get it from a chemist's shop by signing a poisons register, but I don't know if that still holds - and chemists don't seem to sell that kind of thing any more. -- Peter Fairbrother Can't answer your question about cyanide free plating, but here in the States the jewelry supply houses generally sell plating solutions. It's not exactly an economical way to get where you're trying to go, but better than never getting there. It's getting almost impossible to buy chemicals of any kind here in the States. You might consider talking to a plating house to see if they'd be willing to sell you what little you may need, assuming it's not against regs in your country. Dunno. Harold Along with Harold's idea - if it is small - how about a Silver Smith - Kitchen / Dinner Silver repair places. Martin -- Martin Eastburn, Barbara Eastburn @ home at Lion's Lair with our computer NRA LOH, NRA Life NRA Second Amendment Task Force Charter Founder |
#7
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Without going into the gory detail, I can tell you from personal
experience that it's difficult or impossible to get an acceptible silver plated surface without the use of cyanide based chemicals. The same is true for gold and other precious metals like rhodium. You should be able to purchase the materials that you need from any electroplating supply firm, even in the UK, although as here in the US they may be unwilling to sell to individuals due to liability considerations. Harry C. |
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#9
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![]() wrote in message oups.com... Without going into the gory detail, I can tell you from personal experience that it's difficult or impossible to get an acceptible silver plated surface without the use of cyanide based chemicals. The same is true for gold and other precious metals like rhodium. The plating shop I used to use ran a phosphoric gold process, but I have no clue about how it was applied, nor if it was necessary to do a strike with cyanide first. They plated to Mil specs, and were highly respected and well known for their quality. Sadly, I no longer live in that state, so it would be difficult for me to inquire. Having refined precious metals, I understand that the introduction of certain metals to cyanide solution can be trouble. One of the procedures I used to use to recover gold or silver from solution was to introduce zinc flower. The reaction was almost instantaneous, with an almost perfect recovery. That can interfere with plating, just as iron interferes with copper plating from an acid electrolyte. There's a place for each process, and often they must be used in conjunction. You should be able to purchase the materials that you need from any electroplating supply firm, even in the UK, although as here in the US they may be unwilling to sell to individuals due to liability considerations. That would certainly be my thoughts, too. Still, if you can get someone to warm up to your project and share with them what you're trying to do, you never know-----every now and then you encounter someone that takes a personal interest and can't help enough. And then there's the other times---------------sigh. Harold Harry C. |
#10
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Peter Fairbrother wrote:
Does anyone have experience with cyanide-free silver plating? How does it compare? Many years ago I used some produced by an outfit called, IIRC, "Dalic". It was _very_ good but expensive and I never could find a formula to make my own. Ted |
#11
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On Mon, 28 Feb 2005 15:19:08 +0000, Peter Fairbrother
wrote: Does anyone have experience with cyanide-free silver plating? How does it compare? http://www.caswellplating.com/kits/silver.htm I have no experience with this silver, but I've had excellent results from Caswell zinc, nickel and copper. Mike Caswell is a former Brit, may know of someone in the UK that could help you. |
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