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Metalworking (rec.crafts.metalworking) Discuss various aspects of working with metal, such as machining, welding, metal joining, screwing, casting, hardening/tempering, blacksmithing/forging, spinning and hammer work, sheet metal work. |
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#41
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chemistry question
On Sun, 02 Nov 2003 22:29:58 +0800, Old Nick
wrote: On Sat, 1 Nov 2003 18:17:53 -0800, "Harold & Susan Vordos" wrote something ......and in reply I say!: I keep hearing that same response, but how much salt would be in question? One would have rinsed the parts in clear water, then in a solution of sodium hydroxide. When the items in question are introduced to the lye solution the amount of HCL remaining on the parts should be down to next to nothing, and would most likely already have been neutralized by the iron itself. But if you have removed the HCl to the point where the salt will not matter, what is the point of "neutralising" it with the lye? Smart-sounding question, but genuine. I have always used simple rinsing and then oil (WD40 or whatever) if needed rather than NaCl, because of the salt argument. I used Brownell's water displacing oil after rinsing when hot bluing firearms, which I haven't done in decades. The bluing solution was a hellish mix of caustic, sodium nitrite, and sodium nitrate, kept at 295 deg F by back-adding water (very carefully). Very nasty. The hot rinse was to remove the caustic (lye), etc. In theory, the oil displaced the water to prevent rusting. Bluing is a form of oxide which is relatively stable. Without a good rinse and oil, it'll still rust. Pete Keillor _Does_ the lye protect the steel in any way? If you've not put any steel in HCL, perhaps you should do so to understand the speed at which it reacts, especially if heated. I have done it. Yes it rusts anyway if left. Please read the post by Koz, which is in keeping with my personal experiences as well. I have no argument with the theory of salt being a by-product, but one might consider the reality of the situation at hand. Actually burying the steel in lye, as those conveyors apparently are, is quite different from having dipped them for a short while and then left them out to air. In this instance, the part(s) would be protected by the residual lye. It would be highly unlikely that any salt would have been formed. ************************************************* ***************************************** Until I do the other one,this one means nothing Nick White --- HEAD:Hertz Music remove ns from my header address to reply via email !! ") _/ ) ( ) _//- \__/ |
#42
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chemistry question
I have difficulty with it too, but it happens. You used to be able to
buy pure Calgon at the super market, but all the boxes I have looked at for some years say Sodium Carbonate and Calgon. As you say Sodium Carbonate is washing soda, and as such it is milder than TSP but used for many of the same things. Dan "George E. Cawthon" wrote in message I have difficulty believing anything else is in a box labeled as Trisodium Phosphate! If it does, then it violates laws related to labeling products. I have two boxes, one old one fairly new that are labeled TSP and both do not mention any other compound, nor would I expect them too. Now if you have a product that is labeled as a cleaner, or a cleaner with TSP, who knows what would be in it. Recheck the label on the box. If it is labeled as TSP, it better be TSP. Anyway sodium carbonate is known commonly as washing soda. There is no more relationship between sodium carbonate and trisodium phosphate than there is between TSP and sodium chloride. |
#43
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Rust was chemistry question
Hey Ted,
OK. I'll do that. My concern for some time now has been that they may already have gotten condensate "dampened". I'll give it a shot though! Thanks. Taker care. Brian Lawson, Bothwell, Ontario. XXXXXXXXXXXXXXXXXXXXXXOn Sun, 02 Nov 2003 17:20:16 GMT, Ted Edwards wrote: Brian Lawson wrote: here. Drizzly rain this morning, and light fog for a few hours early everyday now. Oh goodie! Wish me luck! Get a spray can of CRC 3-36 NOT WD-40 and give the machines a light spray before taking them out of the truck. Good luck. Ted |
#44
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chemistry question
Tom Quackenbush wrote: On Sat, 01 Nov 2003 22:44:48 GMT, "George E. Cawthon" wrote: SNIP I have difficulty believing anything else is in a box labeled as Trisodium Phosphate! If it does, then it violates laws related to labeling products. I have two boxes, one old one fairly new that are labeled TSP and both do not mention any other compound, nor would I expect them too. Now if you have a product that is labeled as a cleaner, or a cleaner with TSP, who knows what would be in it. Recheck the label on the box. If it is labeled as TSP, it better be TSP. Anyway sodium carbonate is known commonly as washing soda. There is no more relationship between sodium carbonate and trisodium phosphate than there is between TSP and sodium chloride. I have a tub of Red Devil brand cleaner labeled TSP/90. The "TSP/90" is printed in a bold font about 3/4" tall. Above that, in a much smaller and lighter font, it says "phosphate free". The ingredients are "sodium metasilicate". The instructions for use say it is "a trisodium phosphate substitute". Any that spends 30 seconds reading the label would know that this is not real TSP, but I could see where someone in a hurry could mistake it for the real thing. R, Tom Q. True. But TSP/90 sounds like 90% TSP, so I would think this is a near case of labeling fraud. |
#45
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Rust was chemistry question
In that case - way oil will raise water up and out - and stick on also.
Has kept oxygen from steel in my shop. Fog every day around the house now. Raining now. Martin -- Martin Eastburn, Barbara Eastburn @ home at Lion's Lair with our computer NRA LOH, NRA Life NRA Second Amendment Task Force Charter Founder |
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