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Metalworking (rec.crafts.metalworking) Discuss various aspects of working with metal, such as machining, welding, metal joining, screwing, casting, hardening/tempering, blacksmithing/forging, spinning and hammer work, sheet metal work. |
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#1
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Using a Sacrificial anode on a car to suppress or at least helpprevent rusting
On Tuesday, 27 February 2007 07:22:46 UTC, Brent wrote:
I have had a thought occur to me and i could use confirmation that I am or i'm not nuts. First off i live up in snow country and salt country, Ottawa Ontario Canada we put enough salt on our roads up here to make the ocean seem fit to drink. And well Ottawa has one of the most aggressive snow removal and salt plans going in in the first place. So heres my question. has anyone or is there any reason not to deliberately set up a galvanic cell by bolting an amount of magnesium or zinc to the car body in a place where the elements can hit it? IF i'm not "nucking futs" then the anode (Magnesium or zinc) getting wet touching bare steel will set up a galvanic cell with the Mg being sacrificed and "rusting/oxidizing" away to protect the steel of the cars bodywork. Am i nuts? is this doable? does anyone do this? Just curious? If it matters drive a unibody car with an aluminum block (diesel jetta) Hi, I have just removed the front stone guard and chassis end covers from my 1933 Rolls Royce for the first time since it was made and in the chassis cavity I find 3 magnesium sacrificial anodes each side. The chassis is steel and it's immaculate and the covers are aluminium and they are immaculate with no corrosion, the anodes however are almost completely corroded away. Interestingly this car was first delivered to Ontario in 1933 for it's new owner Fredric William Cowan chairman of the Ontario Malleable Iron Company and it remained in the family's ownership until 1974 so the car knows about your environment and road conditions. Seems the anode Idea is neither mad or new |
#2
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
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#3
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
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#4
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Using a Sacrificial anode on a car to suppress or at least helpprevent rusting
On 4/12/2016 9:18 AM, Ed Huntress wrote:
.... The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. ... Right! And where is the electrolyte in a car? Bob |
#5
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Tue, 12 Apr 2016 09:50:23 -0400, Bob Engelhardt
wrote: On 4/12/2016 9:18 AM, Ed Huntress wrote: ... The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. ... Right! And where is the electrolyte in a car? Bob I assume it's an intermittant thing: when the area is wet, you have an electrolyte. When it's dry, you don't have to worry about corrosion, anyway. Again, I haven't seen it used on a car. I'm guessing about how it would work in practice. -- Ed Huntress |
#6
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Using a Sacrificial anode on a car to suppress or at least helpprevent rusting
On 4/12/2016 10:26 AM, Ed Huntress wrote:
wrote: On 4/12/2016 9:18 AM, Ed Huntress wrote: ... The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. ... Right! And where is the electrolyte in a car? I assume it's an intermittant thing: when the area is wet, you have an electrolyte. When it's dry, you don't have to worry about corrosion, anyway. Kinda' - when the _anode_ is wet you get protection, when it's dry and anywhere else is wet, that anywhere else is not protected. Again, I haven't seen it used on a car. I'm guessing about how it would work in practice. Me too - and my BS detector gave a low-level hum on the OP. The OP had more details than the usual BS, but there is still the fundamental chemistry issue. Maybe the Rolls in the OP had some kind of permanent electrolyte that didn't need to be wetted. But then the anodes wouldn't last 80+ years. I dunno. Bob |
#7
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Tue, 12 Apr 2016 10:56:59 -0400, Bob Engelhardt
wrote: On 4/12/2016 10:26 AM, Ed Huntress wrote: wrote: On 4/12/2016 9:18 AM, Ed Huntress wrote: ... The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. ... Right! And where is the electrolyte in a car? I assume it's an intermittant thing: when the area is wet, you have an electrolyte. When it's dry, you don't have to worry about corrosion, anyway. Kinda' - when the _anode_ is wet you get protection, when it's dry and anywhere else is wet, that anywhere else is not protected. Again, I haven't seen it used on a car. I'm guessing about how it would work in practice. Me too - and my BS detector gave a low-level hum on the OP. The OP had more details than the usual BS, but there is still the fundamental chemistry issue. Maybe the Rolls in the OP had some kind of permanent electrolyte that didn't need to be wetted. But then the anodes wouldn't last 80+ years. I dunno. Bob I think I'd have to see it. I can't picture it being very effective, but then, Rolls Royce would go to extremes in the old days, to make everything as perfect as they knew how. Maybe... I wonder, too, about stray currents. Those are the really big problems with boats, which are docked around electrical currents. The ground rods for shore power -- often just an EMT shield -- tend to eat the submerged metal parts of boats, even when they're protected with sacrificial anodes. You probably have such stray currents in an old car, which tend to have a lot of high-resistance paths to the battery ground. I'm skeptical but it's not something I've heard about before. -- Ed Huntress |
#9
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
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#10
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Tue, 12 Apr 2016 10:26:56 -0400, Ed Huntress
wrote: On Tue, 12 Apr 2016 09:50:23 -0400, Bob Engelhardt wrote: On 4/12/2016 9:18 AM, Ed Huntress wrote: ... The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. ... Right! And where is the electrolyte in a car? Bob I assume it's an intermittant thing: when the area is wet, you have an electrolyte. When it's dry, you don't have to worry about corrosion, anyway. Again, I haven't seen it used on a car. I'm guessing about how it would work in practice. The part that is going to rust can be wet and salty while the anode location is clean and dry. It's been tried - the results are not encouraging - not worth the cost and effort of installing, generally speeking. |
#11
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Tue, 12 Apr 2016 12:02:38 -0400, wrote:
On Tue, 12 Apr 2016 09:18:09 -0400, Ed Huntress wrote: On Tue, 12 Apr 2016 03:59:43 -0700 (PDT), wrote: On Tuesday, 27 February 2007 07:22:46 UTC, Brent wrote: I have had a thought occur to me and i could use confirmation that I am or i'm not nuts. First off i live up in snow country and salt country, Ottawa Ontario Canada we put enough salt on our roads up here to make the ocean seem fit to drink. And well Ottawa has one of the most aggressive snow removal and salt plans going in in the first place. So heres my question. has anyone or is there any reason not to deliberately set up a galvanic cell by bolting an amount of magnesium or zinc to the car body in a place where the elements can hit it? IF i'm not "nucking futs" then the anode (Magnesium or zinc) getting wet touching bare steel will set up a galvanic cell with the Mg being sacrificed and "rusting/oxidizing" away to protect the steel of the cars bodywork. Am i nuts? is this doable? does anyone do this? Just curious? If it matters drive a unibody car with an aluminum block (diesel jetta) Hi, I have just removed the front stone guard and chassis end covers from my 1933 Rolls Royce for the first time since it was made and in the chassis cavity I find 3 magnesium sacrificial anodes each side. The chassis is steel and it's immaculate and the covers are aluminium and they are immaculate with no corrosion, the anodes however are almost completely corroded away. Interestingly this car was first delivered to Ontario in 1933 for it's new owner Fredric William Cowan chairman of the Ontario Malleable Iron Company and it remained in the family's ownership until 1974 so the car knows about your environment and road conditions. Seems the anode Idea is neither mad or new Sacrificial anodes are widely used on boats -- magnesium for fresh water and zinc for salt water. Aluminum (pure) is becoming more common in salt water, and it's also more effective in brackish water. Some things to keep in mind: It only works if you have a good electrical connection between the anode and the metal being protected. The water is not enough. You need either a good, clean contact, or an electrical wire connecting the two. Any of the steel that is not electrically connected will not be protected. The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. I have a couple of 10-pound anodes ("zincs") left over from when I maintained my uncle's 42-foot boat. Two of them would last a year, protecting the bronze prop shaft and the propeller, as well as the stainless and bronze through-hull fittings. If the prop shaft was stainless and if there was any aluminum down there, like an aluminum propeller, they would have been eaten up in a few months without anode protection. I've never seen them installed on a car, but I suppose it would work. You might look into the "pencil" zincs and magnesium rods that are used in fresh-water cooling systems for salt-water boats. It'll work fine on your car if you park it in a full drainage ditch. Doesn't (apparently) work too well dry. Yeah, well, cars do get wet sometimes. And when I lived in Michigan, the wet was salt water all winter long. 'Dunno. It's an interesting idea. But having worked on some large boats, and having placed as many as six anodes on a hull to keep the current paths through the water within protected range, I have a hard time imagining how it would work on a car. But then, I haven't seen it or done it. -- Ed Huntress |
#12
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Tue, 12 Apr 2016 10:56:59 -0400, Bob Engelhardt
wrote: On 4/12/2016 10:26 AM, Ed Huntress wrote: wrote: On 4/12/2016 9:18 AM, Ed Huntress wrote: ... The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. ... Right! And where is the electrolyte in a car? I assume it's an intermittant thing: when the area is wet, you have an electrolyte. When it's dry, you don't have to worry about corrosion, anyway. Kinda' - when the _anode_ is wet you get protection, when it's dry and anywhere else is wet, that anywhere else is not protected. Again, I haven't seen it used on a car. I'm guessing about how it would work in practice. Me too - and my BS detector gave a low-level hum on the OP. The OP had more details than the usual BS, but there is still the fundamental chemistry issue. Maybe the Rolls in the OP had some kind of permanent electrolyte that didn't need to be wetted. But then the anodes wouldn't last 80+ years. I dunno. Bob If you place different metals in contact with no electrolyte there is no corrosion. If you place different metals in contact with an electrolyte there is corrosion and if you add an anode the corrosion takes place at the anode. As has been mentioned they are commonly used on boats and outboard engines and in sal****er cooled marine engines and even large stationary power plants engines usually have anodes. -- Cheers, John B. |
#13
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Tue, 12 Apr 2016 12:00:39 -0400, wrote:
On Tue, 12 Apr 2016 19:13:43 +0700, John B. wrote: On Tue, 12 Apr 2016 03:59:43 -0700 (PDT), wrote: On Tuesday, 27 February 2007 07:22:46 UTC, Brent wrote: I have had a thought occur to me and i could use confirmation that I am or i'm not nuts. First off i live up in snow country and salt country, Ottawa Ontario Canada we put enough salt on our roads up here to make the ocean seem fit to drink. And well Ottawa has one of the most aggressive snow removal and salt plans going in in the first place. So heres my question. has anyone or is there any reason not to deliberately set up a galvanic cell by bolting an amount of magnesium or zinc to the car body in a place where the elements can hit it? IF i'm not "nucking futs" then the anode (Magnesium or zinc) getting wet touching bare steel will set up a galvanic cell with the Mg being sacrificed and "rusting/oxidizing" away to protect the steel of the cars bodywork. Am i nuts? is this doable? does anyone do this? Just curious? If it matters drive a unibody car with an aluminum block (diesel jetta) Hi, I have just removed the front stone guard and chassis end covers from my 1933 Rolls Royce for the first time since it was made and in the chassis cavity I find 3 magnesium sacrificial anodes each side. The chassis is steel and it's immaculate and the covers are aluminium and they are immaculate with no corrosion, the anodes however are almost completely corroded away. Interestingly this car was first delivered to Ontario in 1933 for it's new owner Fredric William Cowan chairman of the Ontario Malleable Iron Company and it remained in the family's ownership until 1974 so the car knows about your environment and road conditions. Seems the anode Idea is neither mad or new Both metal hull boats/ships and buried pipelines use anodes so the idea is certainly feasible although if one mixes various metals it might be a bit complex to figure exactly what you wanted to do to [protect all of them. Another system that might be of interest is an electronic system, I believe called a "Cathodic System" where sensors determine the difference in potential and feed an electrical current to oppose existing current flows. The electronic units are totally useless except for the insurance policy that comes with them. Friends have 5 and 6 year old vehicles that have had in excess of $5000 worth of rust repair done under warranty. (make sure you keep up with the inspections or the policy is null and void). My daughter's Neon rusted very badly with the unit installed - no warranty because one inspection had been missed. I have 20 year old vehicle with no rust - used RustCheck. I'm in tha salt and slush belt of Central Ontario - every bit as bad for rust as Ottawa. I have no idea of how effective the units for automobiles but I can assure you that the similar systems used on buried pipelines are very effective, certainly far more than anodes. I also understand, although I've not seen it my self, that all very large shipping use the system. -- Cheers, John B. |
#14
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Using a Sacrificial anode on a car to suppress or at least helpprevent rusting
On Tuesday, April 12, 2016 at 7:27:06 AM UTC-7, Ed Huntress wrote:
On Tue, 12 Apr 2016 09:50:23 -0400, Bob Engelhardt wrote: On 4/12/2016 9:18 AM, Ed Huntress wrote: ... The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. Right! And where is the electrolyte in a car? Again, I haven't seen it used on a car. I'm guessing about how it would work in practice. It works fine; galvanized body was a feature of Americn Motors cars, at least the 1964 Rambler I used to own. It's not as cheap as good paint, though. |
#15
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Wed, 13 Apr 2016 00:28:02 -0700 (PDT), whit3rd
wrote: On Tuesday, April 12, 2016 at 7:27:06 AM UTC-7, Ed Huntress wrote: On Tue, 12 Apr 2016 09:50:23 -0400, Bob Engelhardt wrote: On 4/12/2016 9:18 AM, Ed Huntress wrote: ... The way it works is that the anode/cathode (the cathode is the steel, iron, aluminum alloy, brass or bronze) combination forms a battery, and the anode material is "eaten" away as the "battery" conducts electricity. The water is the electrolyte. Right! And where is the electrolyte in a car? Again, I haven't seen it used on a car. I'm guessing about how it would work in practice. It works fine; galvanized body was a feature of Americn Motors cars, at least the 1964 Rambler I used to own. It's not as cheap as good paint, though. Well, galvanizing is a different story. Any spot that has to be protected is immediately adjacent to zinc in that case. -- Ed Huntress |
#16
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Wed, 13 Apr 2016 10:37:48 +0700, John B.
wrote: I have no idea of how effective the units for automobiles but I can assure you that the similar systems used on buried pipelines are very effective, certainly far more than anodes. I also understand, although I've not seen it my self, that all very large shipping use the system. Well I have a real good idea how well they do NOT work from the 3 examples I provided. They were a pretty common "aftermarket upsell" at many dealerships when I was in the business - and the dealer was the only one who got any advantage out of the sale other than the rust warranty (if it was vallidated by paying the dealer an annual inspection fee) - and even then it seemed the vehicles with the units installed needed a lot more rust repair than those that didn't - particularly those that got an aftermarket oil / wax type rust spray. |
#17
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Using a Sacrificial anode on a car to suppress or at least helpprevent rusting
On Tuesday, April 12, 2016 at 12:07:05 PM UTC-4, Ed Huntress wrote:
'Dunno. It's an interesting idea. But having worked on some large boats, and having placed as many as six anodes on a hull to keep the current paths through the water within protected range, I have a hard time imagining how it would work on a car. But then, I haven't seen it or done it. -- Ed Huntress I imagine you could get a bunch of magnesium fire starters like Harbor Freight sells and cut each one into three pieces , put a hole thru each piece and attach with self tapping screws. Then you could have one mounted close to every part of the car. But it would be a lot less work to paint places that need protection. Dan |
#18
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Wed, 13 Apr 2016 11:56:49 -0700 (PDT), "
wrote: On Tuesday, April 12, 2016 at 12:07:05 PM UTC-4, Ed Huntress wrote: 'Dunno. It's an interesting idea. But having worked on some large boats, and having placed as many as six anodes on a hull to keep the current paths through the water within protected range, I have a hard time imagining how it would work on a car. But then, I haven't seen it or done it. -- Ed Huntress I imagine you could get a bunch of magnesium fire starters like Harbor Freight sells and cut each one into three pieces , put a hole thru each piece and attach with self tapping screws. Then you could have one mounted close to every part of the car. But it would be a lot less work to paint places that need protection. Dan Having restored and repaired a few boat trailers that were regularly dunked in salt water, the best thing I ever tried was a zinc-loaded epoxy coating. It was miserable to apply (very thick, and it drooled -- not thixotropic at all), and very expensive, but it worked great. I rotated the trailer 90 deg. after painting the top and bottom horizontal surfaces, and then coated tops and bottoms of *those* sides. You have to do that before the epoxy cures but after it starts to gel, or the amine will blush and the overlap won't seal it. Then wash off the amine with soap and water, rough it with steel wool, and coat with a good boat enamel. Second best was two coats of zinc chromate primer, and then two coats of brush-on Rust-Oleum. That was the fish-oil based stuff that took a week to dry hard. -- Ed |
#19
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Using a Sacrificial anode on a car to suppress or at least help prevent rusting
On Wed, 13 Apr 2016 11:56:49 -0700 (PDT), "
wrote: On Tuesday, April 12, 2016 at 12:07:05 PM UTC-4, Ed Huntress wrote: 'Dunno. It's an interesting idea. But having worked on some large boats, and having placed as many as six anodes on a hull to keep the current paths through the water within protected range, I have a hard time imagining how it would work on a car. But then, I haven't seen it or done it. -- Ed Huntress I imagine you could get a bunch of magnesium fire starters like Harbor Freight sells and cut each one into three pieces , put a hole thru each piece and attach with self tapping screws. Then you could have one mounted close to every part of the car. But it would be a lot less work to paint places that need protection. Dan Hear Hear!! |
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