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UK diy (uk.d-i-y) For the discussion of all topics related to diy (do-it-yourself) in the UK. All levels of experience and proficency are welcome to join in to ask questions or offer solutions. |
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#1
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OT but I bet we have someone with the answer - Lead Chamber Process
When I was a mere lad there was a chemical fertiliser plant next to
the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? |
#2
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OT but I bet we have someone with the answer - Lead Chamber Process
In message
, cynic writes When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Ammonium sulphate? regards -- Tim Lamb |
#3
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OT but I bet we have someone with the answer - Lead Chamber Process
cynic wrote:
When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Ass a chemist and chemistry teacher, I could not recall the lead chmber process as it was obsolete on the industrial scale and therefore not taught in detail Google provided this link http://www.sulphuric-acid.com/techma...ad_Chamber.htm which suggests that your memry may be flawed. there are other references on google which may help malcolm |
#4
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OT but I bet we have someone with the answer - Lead Chamber Process
"cynic" wrote in message ... When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? If there was copper pyrites, I would imagine you had a copper smelters, who used the waste sulphur for making acid via the scrubber (which from your description of the chimney didn't work very well: bet all people's washing used to fall to bits!), rather than an acid plant per se. They would not waste copper ore just to make sulphuric acid. Just about the only UK source would have been in Cornwall: is that where your village was? http://en.wikipedia.org/wiki/Chalcopyrite S |
#5
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OT but I bet we have someone with the answer - Lead Chamber Process
When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower You wouldn't want more than one of those in the village ;-) -- Graham. %Profound_observation% |
#6
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OT but I bet we have someone with the answer - Lead Chamber Process
"Malcolm" wrote in message newscLZn.114493$m87.35376@hurricane... cynic wrote: When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Ass a chemist and chemistry teacher, I could not recall the lead chmber process as it was obsolete on the industrial scale and therefore not taught in detail Google provided this link http://www.sulphuric-acid.com/techma...ad_Chamber.htm which suggests that your memry may be flawed. there are other references on google which may help just read "nitrous vitriol (sulfuric acid with nitric oxide, NO, and nitrogen dioxide, NO2, dissolved in it)" now that sounds like a real mans drink ! |
#7
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OT but I bet we have someone with the answer - Lead ChamberProcess
On 9 July, 19:34, cynic wrote:
When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Not a chemist but had just been reading about hydrochloric and sulphuric acid, in Vol 2 of Harmsworth's popular science (1911). The sulphur source would have been a by-product from the LeBlanc process or direct from roasted Iron Pyrites. The sulphur free pyrites clinker then mixed with salt and re-roasted, giving copper chloride. The copper along with silver and gold residues then extracted leaving a pure iron oxide for supply to the steel makers. It was the copper content that regulated the pyrites price. Seems the sulphur was just a means to an end. |
#8
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OT but I bet we have someone with the answer - Lead Chamber Process
wrote in message ... On 9 July, 19:34, cynic wrote: When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Not a chemist but had just been reading about hydrochloric and sulphuric acid, in Vol 2 of Harmsworth's popular science (1911). The sulphur source would have been a by-product from the LeBlanc process or direct from roasted Iron Pyrites. The sulphur free pyrites clinker then mixed with salt and re-roasted, giving copper chloride. The copper along with silver and gold residues then extracted leaving a pure iron oxide for supply to the steel makers. It was the copper content that regulated the pyrites price. Seems the sulphur was just a means to an end. They are good those old Harmsworth's books. Shame about all the eugenics though! S |
#9
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OT but I bet we have someone with the answer - Lead ChamberProcess
On 9 July, 19:34, cynic wrote:
When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Pretty common this sort of thing in the good old days. During WW1 there was an explosives manufacturer in the town where Ilived. Seventy years later there still was a huge area of ground down wind of the plant where nothing grew. I think they were making amatol. Even more deadly the old gas works was demolished, the ground was laced with arsenic, cost a fortune to clear up. |
#10
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OT but I bet we have someone with the answer - Lead ChamberProcess
On 10 July, 00:26, "Spamlet" wrote:
wrote in message ... On 9 July, 19:34, cynic wrote: When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Not a chemist but *had just been reading about hydrochloric and sulphuric acid, in Vol 2 of Harmsworth's popular science (1911). The sulphur source would have been *a *by-product from the LeBlanc process or direct from roasted Iron Pyrites. The sulphur free pyrites clinker then mixed with salt and re-roasted, giving copper chloride. The copper along with *silver and gold residues then extracted leaving a pure iron oxide for supply to the steel makers. It was the copper content that regulated the pyrites price. Seems the sulphur was just a means to an end. They are good those old Harmsworth's books. *Shame about all the eugenics though! S Indeed!. It's quite clear we were the world's leading eugenicists at the time. Amazing how our eugenics history could be so easily edited/ revised/deleted after WW2. Love reading the books though. So utterly non-PC they would cause a greenie to look for urgent counselling. White superiority, the Empire, the British as world leaders in virtually everything, industry/ machinery/engineering as the means to any end, jingoism by the bucketful. But also offering masses of basic 'truths' and analysis that apply moreso today and an almost tactile national pride in our achievements and history. The books are the intellectual equivalent of eating a mucky fat sandwich, followed by a couple of Capstan full strength |
#11
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OT but I bet we have someone with the answer - Lead Chamber Process
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#12
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OT but I bet we have someone with the answer - Lead Chamber Process
"harry" wrote in message ... On 9 July, 19:34, cynic wrote: When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Pretty common this sort of thing in the good old days. During WW1 there was an explosives manufacturer in the town where Ilived. Seventy years later there still was a huge area of ground down wind of the plant where nothing grew. I think they were making amatol. Even more deadly the old gas works was demolished, the ground was laced with arsenic, cost a fortune to clear up. Round our way thy just tarmacked over the gasworks and called it Lidl & Sainsburys; and Laporte's waste they tarmacked over and called it Aldi & B&Q. The latter being not such a bad idea as for half a century they were dumping right over an adit to one of the town's main wells... S |
#13
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OT but I bet we have someone with the answer - Lead ChamberProcess
On 10 July, 21:35, wrote:
On 10 July, 00:26, "Spamlet" wrote: wrote in message ... On 9 July, 19:34, cynic wrote: When I was a mere lad there was a chemical fertiliser plant next to the village I lived in. Part of the works was a lead chamber sulphuric acid plant with a Glover and a Gay-Lussac tower which emitted a stinking yellow stream of fumes. All this has gone now but during a good old days discussion the other day someone came up with the remark that the input to the plant was copper pyrites being burnt and the flue gas used to make the acid. I don't recall anything about copper bearing ash being shipped out but I suppose it could have been. Does this sound right to our chemists? Not a chemist but had just been reading about hydrochloric and sulphuric acid, in Vol 2 of Harmsworth's popular science (1911). The sulphur source would have been a by-product from the LeBlanc process or direct from roasted Iron Pyrites. The sulphur free pyrites clinker then mixed with salt and re-roasted, giving copper chloride. The copper along with silver and gold residues then extracted leaving a pure iron oxide for supply to the steel makers. It was the copper content that regulated the pyrites price. Seems the sulphur was just a means to an end. They are good those old Harmsworth's books. Shame about all the eugenics though! S Indeed!. It's quite clear we were the world's leading eugenicists at the time. Amazing how our eugenics history could be so easily edited/ revised/deleted after WW2. Love reading the books though. So utterly non-PC they would cause a greenie to look for urgent counselling. White superiority, the Empire, the British as world leaders in virtually everything, industry/ machinery/engineering as the means to any end, jingoism by the bucketful. But also offering masses of basic 'truths' and analysis that apply moreso today and an almost tactile national pride in our achievements and history. The books are the intellectual equivalent of eating a mucky fat sandwich, followed by a couple of Capstan full strength tangibly put ;)))))) Jim K |
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