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Electronics Repair (sci.electronics.repair) Discussion of repairing electronic equipment. Topics include requests for assistance, where to obtain servicing information and parts, techniques for diagnosis and repair, and annecdotes about success, failures and problems. |
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#41
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Alkaline Battery Leak Cleanup
"josephkk" wrote in message ...
On Sun, 23 Sep 2012 16:24:08 -0700, "William Sommerwerck" wrote: I prefer household ammonia, followed by an isopropyl alcohol flush. Ammonia is a base, as is the electrolyte -- like dissolves like. If you care to get more chemically correct ammonia is a weak acid. ?-) I think he meant household, which is a base... http://en.wikipedia.org/wiki/Ammonia#Properties |
#42
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Alkaline Battery Leak Cleanup
On Mon, 1 Oct 2012 17:30:30 -0700, "Guv Bob"
wrote: "josephkk" wrote in message ... On Sun, 23 Sep 2012 16:24:08 -0700, "William Sommerwerck" wrote: I prefer household ammonia, followed by an isopropyl alcohol flush. Ammonia is a base, as is the electrolyte -- like dissolves like. If you care to get more chemically correct ammonia is a weak acid. ?-) I think he meant household, which is a base... http://en.wikipedia.org/wiki/Ammonia#Properties I am not talking about household ideas. I am talking technical chemistry. Ammonia, including household varieties, have the same chemistry, an acid with a KA of about -10 so it looks basic compared to other acids (even distilled water), including carbonic acid (H2CO3 (soda pop) which fizzes in the presence of strong acids. ?-) |
#43
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Alkaline Battery Leak Cleanup
"josephkk" wrote in message
... On Mon, 1 Oct 2012 17:30:30 -0700, "Guv Bob" wrote: "josephkk" wrote in message ... On Sun, 23 Sep 2012 16:24:08 -0700, "William Sommerwerck" wrote: I prefer household ammonia, followed by an isopropyl alcohol flush. Ammonia is a base, as is the electrolyte -- like dissolves like. If you care to get more chemically correct ammonia is a weak acid. I think he meant household, which is a base... http://en.wikipedia.org/wiki/Ammonia#Properties I am not talking about household ideas. I am talking technical chemistry. Ammonia, including household varieties, have the same chemistry, an acid with a KA of about -10 so it looks basic compared to other acids (even distilled water), including carbonic acid (H2CO3 (soda pop) which fizzes in the presence of strong acids. I think it's time for a chemist to step in and explain this. The argument that an acid "looks basic" compared to stronger acids makes little sense to me. http://en.wikipedia.org/wiki/Acid_dissociation_constant |
#44
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Alkaline Battery Leak Cleanup
josephkk wrote:
On Mon, 1 Oct 2012 17:30:30 -0700, "Guv Bob" wrote: "josephkk" wrote in message ... On Sun, 23 Sep 2012 16:24:08 -0700, "William Sommerwerck" wrote: I prefer household ammonia, followed by an isopropyl alcohol flush. Ammonia is a base, as is the electrolyte -- like dissolves like. If you care to get more chemically correct ammonia is a weak acid. ?-) I think he meant household, which is a base... http://en.wikipedia.org/wiki/Ammonia#Properties I am not talking about household ideas. I am talking technical chemistry. Ammonia, including household varieties, have the same chemistry, an acid with a KA of about -10 so it looks basic compared to other acids (even distilled water), including carbonic acid (H2CO3 (soda pop) which fizzes in the presence of strong acids. ?-) every MSDS I've ever seen for ammonium hydroxide says it's a base. |
#45
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Alkaline Battery Leak Cleanup
On Sunday, September 30, 2012 3:44:40 PM UTC-7, Jeff Liebermann wrote:
On Sun, 30 Sep 2012 14:37:40 -0700 (PDT), whit3rd wrote: On Tuesday, September 25, 2012 12:29:02 PM UTC-7, Jeff Liebermann wrote: The current version is DeOxit from Caig Labs. It comes in an amazing variety of forms, and is allegedly non-corrosive. Those 'forms' are mainly volatile solvents, the residue is the same old stuff. The MSDS data shows the active ingredients as a "trade secret". Oh well. It isn't much of a secret; the patent dates back to late sixties; it's a liquid semiconductor that makes a tenacious film/coating. I couldn't find a German patent. What's a liquid semiconductor? I'm looking at US patent 4696832; there are probably others, the patent refers to prior use of these materials. It's a long-chain molecule with decorations, so the 'formula' is complex (mainly lots of different chain lengths). Semiconductors have few free charge carriers, but low electric fields cause breakdown (really, charge injection at metal contacts). So, that's the kind of behavior this liquid is engineered for. In thin sections (one micron) it's just about like a conductor, but in long tracks (one millimeter) it insulates. The nonlinearity of its conduction makes it suitable for sloshing onto insulating surfaces. |
#46
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Alkaline Battery Leak Cleanup
On Sat, 6 Oct 2012 12:24:19 -0700 (PDT), whit3rd
wrote: I couldn't find a German patent. What's a liquid semiconductor? I'm looking at US patent 4696832; there are probably others, the patent refers to prior use of these materials. It's a long-chain molecule with decorations, so the 'formula' is complex (mainly lots of different chain lengths). http://www.google.com/patents/US4696832 Semiconductors have few free charge carriers, but low electric fields cause breakdown (really, charge injection at metal contacts). So, that's the kind of behavior this liquid is engineered for. In thin sections (one micron) it's just about like a conductor, but in long tracks (one millimeter) it insulates. The nonlinearity of its conduction makes it suitable for sloshing onto insulating surfaces. Thanks. That makes sense. I was assuming it was some kind of directional semiconductor, such as in a liquid diode. http://ilyam.org/CR-ROM_IYPT_1999/16_Liquid_diode_Austria_I_61-73_IYPT_1999.pdf Looks like the contact coating is still a liquid even at the molecular plating thickness. My guess is that the liquid displaces a higher resistance oxide layer with a more conductive "liquid" layer thereby enhancing conductivity. Nice. -- Jeff Liebermann 150 Felker St #D http://www.LearnByDestroying.com Santa Cruz CA 95060 http://802.11junk.com Skype: JeffLiebermann AE6KS 831-336-2558 |
#47
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Alkaline Battery Leak Cleanup
Thanks for the info about Tweak.
I have a tiny bottle, which I only used on my pickup lugs. I've wondered of what use it is, when you (presumably) get quantum tunneling, whether or not Tweak is a "conductor". |
#48
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Alkaline Battery Leak Cleanup
whit3rd wrote:
On Sunday, September 30, 2012 3:44:40 PM UTC-7, Jeff Liebermann wrote: On Sun, 30 Sep 2012 14:37:40 -0700 (PDT), whit3rd wrote: On Tuesday, September 25, 2012 12:29:02 PM UTC-7, Jeff Liebermann wrote: The current version is DeOxit from Caig Labs. It comes in an amazing variety of forms, and is allegedly non-corrosive. Those 'forms' are mainly volatile solvents, the residue is the same old stuff. The MSDS data shows the active ingredients as a "trade secret". Oh well. It isn't much of a secret; the patent dates back to late sixties; it's a liquid semiconductor that makes a tenacious film/coating. I couldn't find a German patent. What's a liquid semiconductor? I'm looking at US patent 4696832; there are probably others, the patent refers to prior use of these materials. It's a long-chain molecule with decorations, so the 'formula' is complex (mainly lots of different chain lengths). Semiconductors have few free charge carriers, but low electric fields cause breakdown (really, charge injection at metal contacts). So, that's the kind of behavior this liquid is engineered for. In thin sections (one micron) it's just about like a conductor, but in long tracks (one millimeter) it insulates. The nonlinearity of its conduction makes it suitable for sloshing onto insulating surfaces. over 20 years ago in the US, they sold some amazingly expensive liquid to slosh on your DIP, SIPP and ZIP memory chips to make them not error out in their sockets. The stuff was sold as being super magical and ultra engineered magic. Just pressing stuff back into their sockets always worked just fine for me. |
#49
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Alkaline Battery Leak Cleanup
Cydrome Leader wrote: over 20 years ago in the US, they sold some amazingly expensive liquid to slosh on your DIP, SIPP and ZIP memory chips to make them not error out in their sockets. The stuff was sold as being super magical and ultra engineered magic. Just pressing stuff back into their sockets always worked just fine for me. Of course it did, if you didn't want a real fix. All that did was wipe off enough oxidation for temporary operation, like wiggling the knob on a dirty TV tuner when they were mechanical. |
#50
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Alkaline Battery Leak Cleanup
On 10/08/2012 02:40 PM, Cydrome Leader wrote:
wrote: On Sunday, September 30, 2012 3:44:40 PM UTC-7, Jeff Liebermann wrote: On Sun, 30 Sep 2012 14:37:40 -0700 (PDT), wrote: On Tuesday, September 25, 2012 12:29:02 PM UTC-7, Jeff Liebermann wrote: The current version is DeOxit from Caig Labs. It comes in an amazing variety of forms, and is allegedly non-corrosive. Those 'forms' are mainly volatile solvents, the residue is the same old stuff. The MSDS data shows the active ingredients as a "trade secret". Oh well. It isn't much of a secret; the patent dates back to late sixties; it's a liquid semiconductor that makes a tenacious film/coating. I couldn't find a German patent. What's a liquid semiconductor? I'm looking at US patent 4696832; there are probably others, the patent refers to prior use of these materials. It's a long-chain molecule with decorations, so the 'formula' is complex (mainly lots of different chain lengths). Semiconductors have few free charge carriers, but low electric fields cause breakdown (really, charge injection at metal contacts). So, that's the kind of behavior this liquid is engineered for. In thin sections (one micron) it's just about like a conductor, but in long tracks (one millimeter) it insulates. The nonlinearity of its conduction makes it suitable for sloshing onto insulating surfaces. over 20 years ago in the US, they sold some amazingly expensive liquid to slosh on your DIP, SIPP and ZIP memory chips to make them not error out in their sockets. The stuff was sold as being super magical and ultra engineered magic. Just pressing stuff back into their sockets always worked just fine for me. Stabilant-22? Cheers Phil Hobbs -- Dr Philip C D Hobbs Principal Consultant ElectroOptical Innovations LLC Optics, Electro-optics, Photonics, Analog Electronics 160 North State Road #203 Briarcliff Manor NY 10510 hobbs at electrooptical dot net http://electrooptical.net |
#51
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Alkaline Battery Leak Cleanup
Phil Hobbs wrote:
On 10/08/2012 02:40 PM, Cydrome Leader wrote: wrote: On Sunday, September 30, 2012 3:44:40 PM UTC-7, Jeff Liebermann wrote: On Sun, 30 Sep 2012 14:37:40 -0700 (PDT), wrote: On Tuesday, September 25, 2012 12:29:02 PM UTC-7, Jeff Liebermann wrote: The current version is DeOxit from Caig Labs. It comes in an amazing variety of forms, and is allegedly non-corrosive. Those 'forms' are mainly volatile solvents, the residue is the same old stuff. The MSDS data shows the active ingredients as a "trade secret". Oh well. It isn't much of a secret; the patent dates back to late sixties; it's a liquid semiconductor that makes a tenacious film/coating. I couldn't find a German patent. What's a liquid semiconductor? I'm looking at US patent 4696832; there are probably others, the patent refers to prior use of these materials. It's a long-chain molecule with decorations, so the 'formula' is complex (mainly lots of different chain lengths). Semiconductors have few free charge carriers, but low electric fields cause breakdown (really, charge injection at metal contacts). So, that's the kind of behavior this liquid is engineered for. In thin sections (one micron) it's just about like a conductor, but in long tracks (one millimeter) it insulates. The nonlinearity of its conduction makes it suitable for sloshing onto insulating surfaces. over 20 years ago in the US, they sold some amazingly expensive liquid to slosh on your DIP, SIPP and ZIP memory chips to make them not error out in their sockets. The stuff was sold as being super magical and ultra engineered magic. Just pressing stuff back into their sockets always worked just fine for me. Stabilant-22? It might have been. I'd have to drag out the old magazine to see. It's too bad they never made junky IC sockets that when vibrated and temperature cycled would worked the leads in into the socket and not away from it. |
#52
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Alkaline Battery Leak Cleanup
Michael A. Terrell wrote:
Cydrome Leader wrote: over 20 years ago in the US, they sold some amazingly expensive liquid to slosh on your DIP, SIPP and ZIP memory chips to make them not error out in their sockets. The stuff was sold as being super magical and ultra engineered magic. Just pressing stuff back into their sockets always worked just fine for me. Of course it did, if you didn't want a real fix. All that did was wipe off enough oxidation for temporary operation, like wiggling the knob on a dirty TV tuner when they were mechanical. the real fix is not having dozens of chips in cheap sockets. Luckily those days are over. we've moved onto exploding capacitors instead. |
#53
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Alkaline Battery Leak Cleanup
"josephkk" wrote in message ...
On Mon, 1 Oct 2012 17:30:30 -0700, "Guv Bob" wrote: "josephkk" wrote in message ... On Sun, 23 Sep 2012 16:24:08 -0700, "William Sommerwerck" wrote: I prefer household ammonia, followed by an isopropyl alcohol flush. Ammonia is a base, as is the electrolyte -- like dissolves like. If you care to get more chemically correct ammonia is a weak acid. ?-) I think he meant household, which is a base... http://en.wikipedia.org/wiki/Ammonia#Properties I am not talking about household ideas. I am talking technical chemistry. Ammonia, including household varieties, have the same chemistry, an acid with a KA of about -10 so it looks basic compared to other acids (even distilled water), including carbonic acid (H2CO3 (soda pop) which fizzes in the presence of strong acids. ?-) I probably missed the conversation by now.... This is a good discussion. You are correct if you are talking about relative acidity - any compound with a hydrogen bond can be considered either acidic or basic: http://chemed.chem.purdue.edu/genche.../bronsted.html One example is the Degussa process reacts NH3 and CH4, where ammonia acts as an acid.... http://jack.ecosse.org/design/98-9/d.../BMA-prog.html Likewise, compared with most other acidic gases and liquids, ammonia acts as a base. Like this experiment shows when you mix gaseous HCl and NH3.... http://www.youtube.com/watch?v=U0M-Q65VQHs And so, there you have it! Everybody wins! Bob PS -- Whut dew I win? |
#54
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Alkaline Battery Leak Cleanup
"Guv Bob" wrote in message m...
"josephkk" wrote in message ... On Mon, 1 Oct 2012 17:30:30 -0700, "Guv Bob" wrote: "josephkk" wrote in message ... On Sun, 23 Sep 2012 16:24:08 -0700, "William Sommerwerck" wrote: I prefer household ammonia, followed by an isopropyl alcohol flush. Ammonia is a base, as is the electrolyte -- like dissolves like. If you care to get more chemically correct ammonia is a weak acid. ?-) I think he meant household, which is a base... http://en.wikipedia.org/wiki/Ammonia#Properties I am not talking about household ideas. I am talking technical chemistry. Ammonia, including household varieties, have the same chemistry, an acid with a KA of about -10 so it looks basic compared to other acids (even distilled water), including carbonic acid (H2CO3 (soda pop) which fizzes in the presence of strong acids. ?-) I probably missed the conversation by now.... This is a good discussion. You are correct if you are talking about relative acidity - any compound with a hydrogen bond can be considered either acidic or basic: http://chemed.chem.purdue.edu/genche.../bronsted.html One example is the Degussa process reacts NH3 and CH4, where ammonia acts as an acid.... http://jack.ecosse.org/design/98-9/d.../BMA-prog.html Likewise, compared with most other acidic gases and liquids, ammonia acts as a base. Like this experiment shows when you mix gaseous HCl and NH3.... http://www.youtube.com/watch?v=U0M-Q65VQHs And so, there you have it! Everybody wins! Bob PS -- Whut dew I win? === Now I wish I hadn't posted this...... so here's the warning... DANGER: DO NOT DO THIS HCl - NH3 experiment -- or mix ammonia with anything. The white 'smoke' in that video is actually super fine ammonium chloride powder. All 3 of these chemicals can burn your skin or cause permanent damage to lungs, etc. And if you spill any of these, your mama (or the lovely wife) will kill you -- if you live through it. |
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