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Metalworking (rec.crafts.metalworking) Discuss various aspects of working with metal, such as machining, welding, metal joining, screwing, casting, hardening/tempering, blacksmithing/forging, spinning and hammer work, sheet metal work. |
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#41
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Ronnie Ray-gun, was 1977 22' Catalina Capri Sailboat - $700 (MarinaDel Rey)
On 10/31/2014 4:52 PM, Ed Huntress wrote:
On Fri, 31 Oct 2014 15:56:52 -0500, Richard wrote: But that's boats. This project was a lot more fun - and less sweat. And there was even a little metal-working involved here! This all came about because I wanted a ray gun. A real honest to gosh ray gun! I guess the Buck Rogers weapons were okay - for their day. But the Bugs Bunny / Marvin the Martian type was the one. And it really really works! (echoes of Ron Propeil!?!) The basic design. Kinda spiffy, huh? http://www.home.earthlink.net/~cave-.../Raygun-01.jpg The shell is hand laid fiberglass over a foam core using 8 ounce woven cloth and west 105 epoxy. Both were selected after a detailed study of what was in the scrap box. Most of the glass was laid on in small patches because of the curvature, but every lay-up was closed out with a full sized wrap to help keep loose strings under control and give a smoother surface. In all three separate lay-ups were done to get the final shell. Using West 105 with 205 (fast) hardener the resin kicks and can be handled in half an hour. So it didn't take long to make the shell. The core was dissolved out with a little lacquer thinner leaving a the body hollow, but the insides sharp as 40 grit sandpaper. The shell was then filed and sanded inside and out to a smooth surface and finally gelcoated. This first one has a 15 mw laser pointer installed - because it was cheap and easy. And it's fun to use as a "kitty prod" to herd cats. The basic shell with the laser retainer hardware installed. http://www.home.earthlink.net/~cave-.../Raygun-02.jpg Laser goes in right about here... http://www.home.earthlink.net/~cave-.../Raygun-04.jpg The metal-working part... It took a few iterations to get the trigger shape right, but I'm happy with the results. I haven't measured the pull, but it's not heavy. The trigger was bandsawed from 1/4" aluminum plate and smoothed nicely. http://www.home.earthlink.net/~cave-.../Raygun-06.jpg The other part - call it the "loop"(?) - was blacksmithed from .063 steel strap by bending it around the correctly sized deep well socket and pounding it into submission with a hammer. The business end. http://www.home.earthlink.net/~cave-.../Raygun-07.jpg The pencil laser pointer is held in place with a sort piece of brass tube bonded in the front end, and a larger diameter piece in the aft end. The pencil fits over (ie outside) the front one and inside the aft one. Then a small plastic cap (from a sting-ez insect-sting stick - hey, it fit perfectly!!) holds the laser firmly in place. Up and running: http://www.home.earthlink.net/~cave-.../Raygun-08.jpg The second one (in the works now) will open up in the middle to allow for a 450 mw laser to be installed. Same shape and style, but a seriously more dangerous weapon. Fiberglass is fun stuff. All it takes is some imagination. http://www.instructables.com/id/Maki...erglass-parts/ Very cool, Richard! You should name it "Ronnie." g I like it. Ronny it is! Even if that crosses genre - from Bugs Bunny to star wars? Oops - wrong star wars? |
#42
Posted to rec.crafts.metalworking
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Fri, 31 Oct 2014 08:45:50 -0400, Ed Huntress
wrote: On Fri, 31 Oct 2014 08:38:44 +0700, John B. Slocomb wrote: On Thu, 30 Oct 2014 09:05:21 -0400, Ed Huntress wrote: On Thu, 30 Oct 2014 17:46:39 +0700, John B. Slocomb wrote: On Wed, 29 Oct 2014 10:10:39 -0400, Ed Huntress wrote: On Wed, 29 Oct 2014 18:46:24 +0700, John B. Slocomb wrote: On Wed, 29 Oct 2014 06:37:26 -0400, Ed Huntress wrote: snip Anyway, your sarcasm was misplaced, as was Richard's. I don't know what the hell he was talking about regarding boat paints. And when you popped off about PFDs, it was clear that you don't sail where we sail. I think Richard was probably referring to the fact that most, if not all, small production fiberglass boats have the hull finished with gel coat and a boat requiring paint would be one on which the gel coat had deteriorated to a considerable degree. Enjoy your sailing in S.E.A., John. Cheers, John B. It's true that failing gel coats on lightly-built fiberglass boats may reflect fatigue in the hull layup, but I don't see that as a reason to make a blanket statement about it. Strongly-built boats, like a Boston Whaler, Black Watch, Cape Dory or Stone Horse, will FAR outlast their gel coats, and it has nothing to do with fatigue -- because those boats generally don't fatigue. In tropical countries it is quite common to see old fiberglass boats with "chalky" finishes due to UV deterioration. It's the same here on the mid-Atlantic coast. While this may or may not be a serious problem depends on the individual case but the turning up of the nose at fiberglass boats that need paint is certainly not a frivolous notion. It depends. But it's not accurate to make a blanket statement about it. Eventually, even well-built boats need a new coating of some kind. Richard's "blanket statement" as I remember it was something like "I wouldn't buy a boat that had to be painted" or something similar... It seems like a perfectly legitimate statement. There's an entire industry dedicated to re-covering those boats. It satarted with a spray-on replacement gel coat around 1960; progressed a few years later to sprayed-on two-part epoxy; and, finally, developed into re-coating with two-part polyurethanes, a lot like the paint used on high-class custom cars. Ed, I think in this case you really don't have all the facts. I've got a good friend in the business and certainly he will re gel-coat your boat for you, but it costs far more money than a two part polyurethane paint job Spray-on polyester get coat is a lot cheaper than two-part polyurethane -- somewhere around 1/3 the cost. There are quality yards throughout the Northeast that will replace a gel coat with a new sprayed-on polyester gel coat. But then it's a matter of how good you want your finish to be. As-spraryed, polyurethane is done. You can't rub it out without ruining its durability, but, if it was done right, you don't have to. (The one-part acrylic polyurethanes can be rubbed out, but that's a different material.) Gel coat, on the other hand, generally looks lousy, as-sprayed. It has to be levelled and rubbed out. It can require a lot of labor, which will raise the cost above the cost of a polyurethane finish. Which, without going into details was pretty much what I said about my mate "the fiberglass guy". Who is quite willing to do you a re-coating with gel-coat. If you are willing to pay for it. All that sanding, rubbing and polishing costs money. Even in a developing country :-) , which is not necessarily "similar to paint on high class cars" as in many cases it is the same stuff. Dupont Imron comes to mind. Yeah, it often is the same stuff. Others are similar. I haven't seen a car painted with Interlux, but then, I've never asked. d8-) And polyester gel coats are porous; they can get stained, or marked up badly because of the way they were tied up at a dock. If "Polyester gel coats" are porous then so is the whole hull as "gel-coat" is commonly just polyester resin with an added pigment. It is porous; water enters through diffusion and by capillary action: http://tinyurl.com/nmxdnlk And the more styrene there is in the resin, the more porous it becomes over time. Cheaper boats generally have more styrene in the resin. Polyester resin is permeable, even without styrene. Epoxy is much less so. Likewise, polyurethane. It's not widely appreciated how much this degrades the interlaminar strength of polyester-resin composites. I think that statement applies more to people that buy boats rather then the boating industry as a whole. Certainly blistering, Osmosis it is usually called, a common fault with polyester boats, seems to be pretty well known. It's not just osmosis. It's also diffusion and outright capillary absorption. The weight gain of a boat that sits in water for a year can be significant, particularly if the boat is a few years old. " Osmosis it is usually called" ??? With polyester resin, the capillary action is accelerated by the breakdown of the resin-to-fiber bonds, which are substantial to begin with and get worse over time. Polyester resin is a lousy adhesive and it shrinks quite a bit during curing, which shears the bonds. Then water makes it worse. You may have noted in that article that the shear strength of a thin (as in most small boats) laminate typically falls off by 35% after a year of sitting in water. But! It is the cheapest resin around :-) Gel coat is not much protection. But better then plain old polyester. Your reference (above) spells out the problem of polyester versus epoxy - cost. I believe that the better quality boats now incorporate a layer of vinyl ester (vinylester?) as a water proofing means. (Not as effective as epoxy but much, much, cheaper :-) There are more additives in polyester gel coat than just pigment, for scratch resistance, UV protection, and so on. That is not necessarily true. I've watched shops building 25 ft. power boats here and seen how they mix the gel-coat. Just plain polyester resin and a pigment. I worked as a bonder at Ranger Yachts in the early '70s. We did not mix our own gel coat. But, as I wrote above, some shops do, and the ones I saw simply mixed the pigment with the polyester and slathered it into the molds. In fact the pigment is commonly available at shops selling fiberglass supplies here and you can get it here in various colors. Gunner is more likely talking about rolling on a coat of house paint g, but I don't get why Richard was so dismissive about painting a boat. There are a lot of boats around here right now that are dry docked or up on stilts, having their topsides painted at the same time they're getting a new coat of bottom paint, before the weather gets too cold. Most of them are fiberglass boats. I suspect that it is because properly painting a deteriorated gel-coated hull is an expensive proposition as to do a good job you first need to remove the old gel-coat down to a smooth solid surface and removing gel-coat is a pain in the butt and pains in the butt tend to be expensive. Additionally, I suspect, it may well be extra costly in the U.S. due to your environmental laws. I read somewhere that a U.S. yard had refused to allow removing old copper bottom paint as they said it would get them in trouble with the environmental people. We don't use much copper bottom paint anymore, largely for that reason. Bottom paints now are usually *very* specific to the regional waters one will sail in. I got away without bottom paint for a whole year by sailing my little Cape Dory Typhoon up a freshwater creek once a week. It killed everything growing on the bottom. Yes, I know. I once bought a quart of real copper paint - powdered copper and some sort of binder - local made paint and much cheaper then the foreign made "bottom paint". I used it on a dinghy and even there it wasn't really a very good anti-fouling paint. I asked, sometime later, about "what is this stuff used for" and the shop told me that most of their sales were to "fishing boats". Which given their location probably meant the big Thai wooden fishing boats, say 50 - 70 ft. and they are hauled every year and are under way probably 75 - 80 percent of the time. Which does make a difference. But you are correct, bottom paint is like the old English saying, "Horses for courses". Practical Boat Owner, a British magazine, tried to do a definitive test of bottom paints and made test panels that were exposed in all the larger harbors in England (and I think Scotland) and they determined that "there's no telling" as a paint that worked well in one location failed in others. They couldn't even get results that were general - "this paint works well in southern harbors" - as there seemed to be no correlation between any specifics that they could discover. The local yards find out what works from local experience, and stick with it. It's really amazing how much difference there is from one location to another. -- Cheers, John B. |
#43
Posted to rec.crafts.metalworking
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Fri, 31 Oct 2014 09:55:37 -0500, Richard
wrote: On 10/30/2014 8:38 PM, John B. Slocomb wrote: Richard's "blanket statement" as I remember it was something like "I wouldn't buy a boat that had to be painted" or something similar... It seems like a perfectly legitimate statement. snippage Thanks, Capt'n. I think he may have been a bit more adamant about it. Maybe to the point of a Never Ever! but yeah, that was about the gist of it. Which, without going into details was pretty much what I said about my mate "the fiberglass guy". Who is quite willing to do you a re-coating with gel-coat. If you are willing to pay for it. All that sanding, rubbing and polishing costs money. Even in a developing country :-) It all depends on your personal standards, of course. Some people think a chalky boat is the epitome of success - because it takes no effort to maintain. And they are perfectly right - for them. Way back in the days of wooden boats I read an article in one of the U.S. magazines extolling topside paints that chalked easily. The writer said that they really hade the boot look good, longer, as when you scrubbed the topsides mid season the chalkiness scrubbed off taking the dirt and crud with it. The Maine lobster fishermen usually hauled once during the season and one chap came up with an ingenious scheme. They, of course, beached the boats, propped up with sticks and this guy, as soon as the tide started going out and the sticks started taking some weight started spraying the hull with Clorox from one of those back mounted spray tanks. Just walked round and round spraying. When the tide was pretty well all the way out he'd scrub the hull with a "straw Broom" and all the weeds and shell fish would fall off. He clamed that as he didn't have to scrape, the bottom paint wasn't damaged so he didn't have top re-paint half way through the season :-) I take a different tack - (or maybe "they" do?) but I adore a nice shiny hull. I picked up my technique from a fellow who goes by the handle Maine Sail. He has written an awful lot about repairing and maintaining boats, and I have joined the choir there. The best collection is he http://forums.hunter.sailboatowners....play.php?f=135 I bought the Ryoby variable speed buffer he recommended - and learned to use it. I's amazing what you can bring back from the dead that way. (For various values of dead, of course!) I started gelcoat craziness with our Capri 18, "Spirit". The surfaces needed wet sanding first, then polishing. That took a week in all. Sanding, buffing and waxing. But the finish lasted for years afterwards, with only an occasional wash and wax. "Temptress", our Capri 26, was the national fleet flagship for several years. I didn't need much more incentive to go overboard on her. But that's a lot more boat. I hired out the buffing part. Happily! Here is a link to Maine Sail's article about bringing gelcoat back to life: http://forums.hunter.sailboatowners....d.php?t=117266 Another phobia picked up from the same source is silicone. It's perhaps the most misused substance on the planet - or maybe runs a close second to 3M 4200. My deck hardware is bedded with high quality Butyl rubber tape. Now, note: I said High-Quality and Tape (not cheap putty mashed out to look like tape). The putty-tape is commonly used in RV construction where it often contributes to hard-to-find leaks. It has no place on a boat. I've used Bed-It butyl tape on several boats and guarantee the results. http://forums.hunter.sailboatowners....d.php?t=117172 And help for cored deck and hull penetrations: How to keep water out of a balsa or plywood deck core. http://www.pbase.com/mainecruising/sealing_the_deck The forty footer I owned, for some reason, had additional jib tracks added inboard of the original tracks on the gunnels. Apparently done by the previous owner who simply drilled holes through the deck and bolted them down. Needless to say, the holes leaked and the plywood core rutted in two six foot strips down the side decks, toward the forward end of the cockpit. I finally used a 4" hand grinder and sliced the fiberglass deck surface and removed two six foot long by about 18 inch wide sections. The plywood had turned into a black mush. I cleaned it out back to solid ply thinking that I could simply get some more plywood of the same thickness to "inlay". It turned out that the original plywood was some strange dimension that couldn't be duplicated and I ended up with a horrible job of gluing down a layer of ply, then building it up with epoxy filler and gluing the original deck sections back on top. A horrible mess trying to get the whole job smooth and fair with the old deck. A lot of work? Maybe. But a job that doesn't have to be reworked all the time is worth the extra expense and effort. At least that's how I feel. It all depends on your personal standards... -- Cheers, John B. |
#44
Posted to rec.crafts.metalworking
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Fri, 31 Oct 2014 15:56:52 -0500, Richard
wrote: But that's boats. This project was a lot more fun - and less sweat. And there was even a little metal-working involved here! This all came about because I wanted a ray gun. A real honest to gosh ray gun! I guess the Buck Rogers weapons were okay - for their day. But the Bugs Bunny / Marvin the Martian type was the one. And it really really works! (echoes of Ron Propeil!?!) The basic design. Kinda spiffy, huh? http://www.home.earthlink.net/~cave-.../Raygun-01.jpg The shell is hand laid fiberglass over a foam core using 8 ounce woven cloth and west 105 epoxy. Both were selected after a detailed study of what was in the scrap box. Most of the glass was laid on in small patches because of the curvature, but every lay-up was closed out with a full sized wrap to help keep loose strings under control and give a smoother surface. In all three separate lay-ups were done to get the final shell. Using West 105 with 205 (fast) hardener the resin kicks and can be handled in half an hour. So it didn't take long to make the shell. The core was dissolved out with a little lacquer thinner leaving a the body hollow, but the insides sharp as 40 grit sandpaper. The shell was then filed and sanded inside and out to a smooth surface and finally gelcoated. This first one has a 15 mw laser pointer installed - because it was cheap and easy. And it's fun to use as a "kitty prod" to herd cats. Never mind all that fiberglass stuff. If you can actually "herd cats" you can probably manage a small tribe of wives too :-) -- Cheers, John B. |
#45
Posted to rec.crafts.metalworking
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Sat, 01 Nov 2014 07:41:12 +0700, John B. Slocomb
wrote: On Fri, 31 Oct 2014 08:45:50 -0400, Ed Huntress wrote: On Fri, 31 Oct 2014 08:38:44 +0700, John B. Slocomb wrote: On Thu, 30 Oct 2014 09:05:21 -0400, Ed Huntress wrote: On Thu, 30 Oct 2014 17:46:39 +0700, John B. Slocomb wrote: On Wed, 29 Oct 2014 10:10:39 -0400, Ed Huntress wrote: On Wed, 29 Oct 2014 18:46:24 +0700, John B. Slocomb wrote: On Wed, 29 Oct 2014 06:37:26 -0400, Ed Huntress wrote: snip Anyway, your sarcasm was misplaced, as was Richard's. I don't know what the hell he was talking about regarding boat paints. And when you popped off about PFDs, it was clear that you don't sail where we sail. I think Richard was probably referring to the fact that most, if not all, small production fiberglass boats have the hull finished with gel coat and a boat requiring paint would be one on which the gel coat had deteriorated to a considerable degree. Enjoy your sailing in S.E.A., John. Cheers, John B. It's true that failing gel coats on lightly-built fiberglass boats may reflect fatigue in the hull layup, but I don't see that as a reason to make a blanket statement about it. Strongly-built boats, like a Boston Whaler, Black Watch, Cape Dory or Stone Horse, will FAR outlast their gel coats, and it has nothing to do with fatigue -- because those boats generally don't fatigue. In tropical countries it is quite common to see old fiberglass boats with "chalky" finishes due to UV deterioration. It's the same here on the mid-Atlantic coast. While this may or may not be a serious problem depends on the individual case but the turning up of the nose at fiberglass boats that need paint is certainly not a frivolous notion. It depends. But it's not accurate to make a blanket statement about it. Eventually, even well-built boats need a new coating of some kind. Richard's "blanket statement" as I remember it was something like "I wouldn't buy a boat that had to be painted" or something similar... It seems like a perfectly legitimate statement. There's an entire industry dedicated to re-covering those boats. It satarted with a spray-on replacement gel coat around 1960; progressed a few years later to sprayed-on two-part epoxy; and, finally, developed into re-coating with two-part polyurethanes, a lot like the paint used on high-class custom cars. Ed, I think in this case you really don't have all the facts. I've got a good friend in the business and certainly he will re gel-coat your boat for you, but it costs far more money than a two part polyurethane paint job Spray-on polyester get coat is a lot cheaper than two-part polyurethane -- somewhere around 1/3 the cost. There are quality yards throughout the Northeast that will replace a gel coat with a new sprayed-on polyester gel coat. But then it's a matter of how good you want your finish to be. As-spraryed, polyurethane is done. You can't rub it out without ruining its durability, but, if it was done right, you don't have to. (The one-part acrylic polyurethanes can be rubbed out, but that's a different material.) Gel coat, on the other hand, generally looks lousy, as-sprayed. It has to be levelled and rubbed out. It can require a lot of labor, which will raise the cost above the cost of a polyurethane finish. Which, without going into details was pretty much what I said about my mate "the fiberglass guy". Who is quite willing to do you a re-coating with gel-coat. If you are willing to pay for it. All that sanding, rubbing and polishing costs money. Even in a developing country :-) , which is not necessarily "similar to paint on high class cars" as in many cases it is the same stuff. Dupont Imron comes to mind. Yeah, it often is the same stuff. Others are similar. I haven't seen a car painted with Interlux, but then, I've never asked. d8-) And polyester gel coats are porous; they can get stained, or marked up badly because of the way they were tied up at a dock. If "Polyester gel coats" are porous then so is the whole hull as "gel-coat" is commonly just polyester resin with an added pigment. It is porous; water enters through diffusion and by capillary action: http://tinyurl.com/nmxdnlk And the more styrene there is in the resin, the more porous it becomes over time. Cheaper boats generally have more styrene in the resin. Polyester resin is permeable, even without styrene. Epoxy is much less so. Likewise, polyurethane. It's not widely appreciated how much this degrades the interlaminar strength of polyester-resin composites. I think that statement applies more to people that buy boats rather then the boating industry as a whole. Certainly blistering, Osmosis it is usually called, a common fault with polyester boats, seems to be pretty well known. It's not just osmosis. It's also diffusion and outright capillary absorption. The weight gain of a boat that sits in water for a year can be significant, particularly if the boat is a few years old. " Osmosis it is usually called" ??? With polyester resin, the capillary action is accelerated by the breakdown of the resin-to-fiber bonds, which are substantial to begin with and get worse over time. Polyester resin is a lousy adhesive and it shrinks quite a bit during curing, which shears the bonds. Then water makes it worse. You may have noted in that article that the shear strength of a thin (as in most small boats) laminate typically falls off by 35% after a year of sitting in water. But! It is the cheapest resin around :-) Gel coat is not much protection. But better then plain old polyester. Your reference (above) spells out the problem of polyester versus epoxy - cost. I believe that the better quality boats now incorporate a layer of vinyl ester (vinylester?) as a water proofing means. (Not as effective as epoxy but much, much, cheaper :-) There are more additives in polyester gel coat than just pigment, for scratch resistance, UV protection, and so on. That is not necessarily true. I've watched shops building 25 ft. power boats here and seen how they mix the gel-coat. Just plain polyester resin and a pigment. I worked as a bonder at Ranger Yachts in the early '70s. We did not mix our own gel coat. But, as I wrote above, some shops do, and the ones I saw simply mixed the pigment with the polyester and slathered it into the molds. In fact the pigment is commonly available at shops selling fiberglass supplies here and you can get it here in various colors. Well, commercial gel coat is made with a water-clear base, like casting resin, rather than the purplish or brownish tint that's common to laminating resin, and it contains plasticizers to reduce brittleness. If it's to be used in a mold, to build a boat, it doesn't contain the wax that's in ordinary laminating resin, and it gets a better bond to the first layup as a result. Of course, it it's a repair job, and sprayed on the outside, it needs the wax or it won't cure on the surface. At Ranger, as with most molders, gel coat would sometimes peel off of the hull, onto the mold, in small chunks, when the hull was pulled from the mold. Then a specialist would fill the spot and repair if after the hull had fully cured. They'd use the regular gel coat for that, with some wax mixed in. It looked like a colloidal slush and it only took an ounce or so of it per quart of resin to do the job. The pigments were used in Ranger boats, and many others, to mix with the laminating resin used for the initial layer of the layup, as a color backup for the gel coat. Our gel coats came pre-colored to the company's color standards. Gunner is more likely talking about rolling on a coat of house paint g, but I don't get why Richard was so dismissive about painting a boat. There are a lot of boats around here right now that are dry docked or up on stilts, having their topsides painted at the same time they're getting a new coat of bottom paint, before the weather gets too cold. Most of them are fiberglass boats. I suspect that it is because properly painting a deteriorated gel-coated hull is an expensive proposition as to do a good job you first need to remove the old gel-coat down to a smooth solid surface and removing gel-coat is a pain in the butt and pains in the butt tend to be expensive. Additionally, I suspect, it may well be extra costly in the U.S. due to your environmental laws. I read somewhere that a U.S. yard had refused to allow removing old copper bottom paint as they said it would get them in trouble with the environmental people. We don't use much copper bottom paint anymore, largely for that reason. Bottom paints now are usually *very* specific to the regional waters one will sail in. I got away without bottom paint for a whole year by sailing my little Cape Dory Typhoon up a freshwater creek once a week. It killed everything growing on the bottom. Yes, I know. I once bought a quart of real copper paint - powdered copper and some sort of binder - local made paint and much cheaper then the foreign made "bottom paint". I used it on a dinghy and even there it wasn't really a very good anti-fouling paint. I asked, sometime later, about "what is this stuff used for" and the shop told me that most of their sales were to "fishing boats". Which given their location probably meant the big Thai wooden fishing boats, say 50 - 70 ft. and they are hauled every year and are under way probably 75 - 80 percent of the time. Which does make a difference. But you are correct, bottom paint is like the old English saying, "Horses for courses". Practical Boat Owner, a British magazine, tried to do a definitive test of bottom paints and made test panels that were exposed in all the larger harbors in England (and I think Scotland) and they determined that "there's no telling" as a paint that worked well in one location failed in others. They couldn't even get results that were general - "this paint works well in southern harbors" - as there seemed to be no correlation between any specifics that they could discover. The local yards find out what works from local experience, and stick with it. It's really amazing how much difference there is from one location to another. |
#46
Posted to rec.crafts.metalworking
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On 10/31/2014 8:13 PM, John B. Slocomb wrote:
On Fri, 31 Oct 2014 15:56:52 -0500, Richard wrote: But that's boats. This project was a lot more fun - and less sweat. And there was even a little metal-working involved here! This all came about because I wanted a ray gun. A real honest to gosh ray gun! I guess the Buck Rogers weapons were okay - for their day. But the Bugs Bunny / Marvin the Martian type was the one. And it really really works! (echoes of Ron Propeil!?!) The basic design. Kinda spiffy, huh? http://www.home.earthlink.net/~cave-.../Raygun-01.jpg The shell is hand laid fiberglass over a foam core using 8 ounce woven cloth and west 105 epoxy. Both were selected after a detailed study of what was in the scrap box. Most of the glass was laid on in small patches because of the curvature, but every lay-up was closed out with a full sized wrap to help keep loose strings under control and give a smoother surface. In all three separate lay-ups were done to get the final shell. Using West 105 with 205 (fast) hardener the resin kicks and can be handled in half an hour. So it didn't take long to make the shell. The core was dissolved out with a little lacquer thinner leaving a the body hollow, but the insides sharp as 40 grit sandpaper. The shell was then filed and sanded inside and out to a smooth surface and finally gelcoated. This first one has a 15 mw laser pointer installed - because it was cheap and easy. And it's fun to use as a "kitty prod" to herd cats. Never mind all that fiberglass stuff. If you can actually "herd cats" you can probably manage a small tribe of wives too :-) Cats are easy. Women are women. |
#47
Posted to rec.crafts.metalworking
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On 10/31/2014 8:08 PM, John B. Slocomb wrote:
This message has been snipped some - just to show that the technology still works! Some people think a chalky boat is the epitome of success - because it takes no effort to maintain. And they are perfectly right - for them. Way back in the days of wooden boats I read an article in one of the U.S. magazines extolling topside paints that chalked easily. The writer said that they really hade the boot look good, longer, as when you scrubbed the topsides mid season the chalkiness scrubbed off taking the dirt and crud with it. The Maine lobster fishermen usually hauled once during the season and one chap came up with an ingenious scheme. They, of course, beached the boats, propped up with sticks and this guy, as soon as the tide started going out and the sticks started taking some weight started spraying the hull with Clorox from one of those back mounted spray tanks. Just walked round and round spraying. When the tide was pretty well all the way out he'd scrub the hull with a "straw Broom" and all the weeds and shell fish would fall off. He clamed that as he didn't have to scrape, the bottom paint wasn't damaged so he didn't have top re-paint half way through the season :-) Now that's a sailor! Want to know the easiest way to do something? Put a smart lazy man on the job. The forty footer I owned, for some reason, had additional jib tracks added inboard of the original tracks on the gunnels. Apparently done by the previous owner who simply drilled holes through the deck and bolted them down. Needless to say, the holes leaked and the plywood core rutted in two six foot strips down the side decks, toward the forward end of the cockpit. I finally used a 4" hand grinder and sliced the fiberglass deck surface and removed two six foot long by about 18 inch wide sections. The plywood had turned into a black mush. I cleaned it out back to solid ply thinking that I could simply get some more plywood of the same thickness to "inlay". It turned out that the original plywood was some strange dimension that couldn't be duplicated and I ended up with a horrible job of gluing down a layer of ply, then building it up with epoxy filler and gluing the original deck sections back on top. A horrible mess trying to get the whole job smooth and fair with the old deck. Oh man. I feel your pain. A friend is involved with the Sea Scouts and sometimes get boats donated. One Catalina ancient 27 came in and the entire foredeck was spongy. He asked what it would cost to have it fixed. Well, traditional methods - more than the boat was worth - for sure. We tried something different. You know how that polyurethane Gorilla Glue foams up from moisture? We drilled some holes in the under side of the deck, poked plastic tubing down the length of the deck and squirted in 6 bottles of glue - one at a time. Squirt a bunch of glue and pull the hose out. Let it expand for a day or two(!). Then run another tube in as far as it will go and squirt in more glue. Didn't plug the holes or anything, just to let it relieve pressure. Put buckets under the drains and let it cook. A couple of weeks later the deck was solid as a rock again. The under side looked like hell. He didn't want to do anything but trim the foam off flush with a knife. He didn't want to mislead a buyer as to the condition of the boat. It sold soon after. Not much, but income for the Scouts. It's still sailing. A lot of work? Maybe. But a job that doesn't have to be reworked all the time is worth the extra expense and effort. At least that's how I feel. It all depends on your personal standards... |
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Sat, 01 Nov 2014 08:08:45 +0700, John B. Slocomb
wrote: On Fri, 31 Oct 2014 09:55:37 -0500, Richard wrote: On 10/30/2014 8:38 PM, John B. Slocomb wrote: Richard's "blanket statement" as I remember it was something like "I wouldn't buy a boat that had to be painted" or something similar... It seems like a perfectly legitimate statement. snippage Thanks, Capt'n. I think he may have been a bit more adamant about it. Maybe to the point of a Never Ever! but yeah, that was about the gist of it. Which, without going into details was pretty much what I said about my mate "the fiberglass guy". Who is quite willing to do you a re-coating with gel-coat. If you are willing to pay for it. All that sanding, rubbing and polishing costs money. Even in a developing country :-) It all depends on your personal standards, of course. Some people think a chalky boat is the epitome of success - because it takes no effort to maintain. And they are perfectly right - for them. Way back in the days of wooden boats I read an article in one of the U.S. magazines extolling topside paints that chalked easily. The writer said that they really hade the boot look good, longer, as when you scrubbed the topsides mid season the chalkiness scrubbed off taking the dirt and crud with it. Here's one that went for really chalky paint: http://tinyurl.com/kh59byr Marty Haines hauled the Sea Pigeon every year, scraped and sanded her for about a month, and then painted her with regular topsides paint. He grew tired of that after 20 years and heard that house paint might be a solution. So in 1981 he did the usual scraping and sanding, and then painted her with regular latex house paint. She looked great; chalked off dirt all the next season; and, when he hauled her the next fall, all he had to do was sand her with an orbital sander and re-paint. There was no chipping or peeling, and the wood was in fine shape underneath. Sea Pigeon was carvel-planked with traditional cotton caulked seams, but with modern Thiokol caulking compound. Marty sold her five years later, so I never learned how long it worked. But it was a revelation to a lot of old-time owners of wooden working boats in this area. -- Ed Huntress |
#49
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On 10/31/2014 10:45 PM, Ed Huntress wrote:
On Sat, 01 Nov 2014 08:08:45 +0700, John B. Slocomb wrote: On Fri, 31 Oct 2014 09:55:37 -0500, Richard wrote: On 10/30/2014 8:38 PM, John B. Slocomb wrote: Richard's "blanket statement" as I remember it was something like "I wouldn't buy a boat that had to be painted" or something similar... It seems like a perfectly legitimate statement. snippage Thanks, Capt'n. I think he may have been a bit more adamant about it. Maybe to the point of a Never Ever! but yeah, that was about the gist of it. Which, without going into details was pretty much what I said about my mate "the fiberglass guy". Who is quite willing to do you a re-coating with gel-coat. If you are willing to pay for it. All that sanding, rubbing and polishing costs money. Even in a developing country :-) It all depends on your personal standards, of course. Some people think a chalky boat is the epitome of success - because it takes no effort to maintain. And they are perfectly right - for them. Way back in the days of wooden boats I read an article in one of the U.S. magazines extolling topside paints that chalked easily. The writer said that they really hade the boot look good, longer, as when you scrubbed the topsides mid season the chalkiness scrubbed off taking the dirt and crud with it. Here's one that went for really chalky paint: http://tinyurl.com/kh59byr Marty Haines hauled the Sea Pigeon every year, scraped and sanded her for about a month, and then painted her with regular topsides paint. He grew tired of that after 20 years and heard that house paint might be a solution. So in 1981 he did the usual scraping and sanding, and then painted her with regular latex house paint. She looked great; chalked off dirt all the next season; and, when he hauled her the next fall, all he had to do was sand her with an orbital sander and re-paint. There was no chipping or peeling, and the wood was in fine shape underneath. Sea Pigeon was carvel-planked with traditional cotton caulked seams, but with modern Thiokol caulking compound. Marty sold her five years later, so I never learned how long it worked. But it was a revelation to a lot of old-time owners of wooden working boats in this area. I was going to say that oakum was "traditional" and cotton would caul. But then you said Thiokol. You just KNOW that's gonna leak on a cold day! |
#50
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Fri, 31 Oct 2014 23:11:49 -0500, Richard
wrote: On 10/31/2014 10:45 PM, Ed Huntress wrote: On Sat, 01 Nov 2014 08:08:45 +0700, John B. Slocomb wrote: On Fri, 31 Oct 2014 09:55:37 -0500, Richard wrote: On 10/30/2014 8:38 PM, John B. Slocomb wrote: Richard's "blanket statement" as I remember it was something like "I wouldn't buy a boat that had to be painted" or something similar... It seems like a perfectly legitimate statement. snippage Thanks, Capt'n. I think he may have been a bit more adamant about it. Maybe to the point of a Never Ever! but yeah, that was about the gist of it. Which, without going into details was pretty much what I said about my mate "the fiberglass guy". Who is quite willing to do you a re-coating with gel-coat. If you are willing to pay for it. All that sanding, rubbing and polishing costs money. Even in a developing country :-) It all depends on your personal standards, of course. Some people think a chalky boat is the epitome of success - because it takes no effort to maintain. And they are perfectly right - for them. Way back in the days of wooden boats I read an article in one of the U.S. magazines extolling topside paints that chalked easily. The writer said that they really hade the boot look good, longer, as when you scrubbed the topsides mid season the chalkiness scrubbed off taking the dirt and crud with it. Here's one that went for really chalky paint: http://tinyurl.com/kh59byr Marty Haines hauled the Sea Pigeon every year, scraped and sanded her for about a month, and then painted her with regular topsides paint. He grew tired of that after 20 years and heard that house paint might be a solution. So in 1981 he did the usual scraping and sanding, and then painted her with regular latex house paint. She looked great; chalked off dirt all the next season; and, when he hauled her the next fall, all he had to do was sand her with an orbital sander and re-paint. There was no chipping or peeling, and the wood was in fine shape underneath. Sea Pigeon was carvel-planked with traditional cotton caulked seams, but with modern Thiokol caulking compound. Marty sold her five years later, so I never learned how long it worked. But it was a revelation to a lot of old-time owners of wooden working boats in this area. I was going to say that oakum was "traditional" and cotton would caul. But then you said Thiokol. You just KNOW that's gonna leak on a cold day! G I caulked my uncle's 42-footer for eight years -- every year after he turned 70 and couldn't do it himself -- and we used cotton, too. Actually, with Thiokol, the caulk would last for two or even three years, and only needed touch-up on an annual basis. I only re-caulked the whole boat once. There is some oakum used around here but a tightly-seamed boat typically is caulked with cotton. My uncle's boat was planked with African "mahogony," one of the non-mahoganies that have been used since around 1970, that look good and that have low rates of shrinkage and expansion. I would not use cotton and Thiokol on a booster rocket. Maybe they should have used oakum, white lead, and linseed oil... -- Ed Huntress |
#51
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Wed, 29 Oct 2014 12:53:34 -0500, Richard
wrote: On 10/29/2014 9:10 AM, Ed Huntress wrote: On Wed, 29 Oct 2014 18:46:24 +0700, John B. Slocomb wrote: On Wed, 29 Oct 2014 06:37:26 -0400, Ed Huntress wrote: snip Anyway, your sarcasm was misplaced, as was Richard's. I don't know what the hell he was talking about regarding boat paints. And when you popped off about PFDs, it was clear that you don't sail where we sail. I think Richard was probably referring to the fact that most, if not all, small production fiberglass boats have the hull finished with gel coat and a boat requiring paint would be one on which the gel coat had deteriorated to a considerable degree. Enjoy your sailing in S.E.A., John. Cheers, John B. It's true that failing gel coats on lightly-built fiberglass boats may reflect fatigue in the hull layup, but I don't see that as a reason to make a blanket statement about it. Strongly-built boats, like a Boston Whaler, Black Watch, Cape Dory or Stone Horse, will FAR outlast their gel coats, and it has nothing to do with fatigue -- because those boats generally don't fatigue. There's an entire industry dedicated to re-covering those boats. It satarted with a spray-on replacement gel coat around 1960; progressed a few years later to sprayed-on two-part epoxy; and, finally, developed into re-coating with two-part polyurethanes, a lot like the paint used on high-class custom cars. And polyester gel coats are porous; they can get stained, or marked up badly because of the way they were tied up at a dock. Gunner is more likely talking about rolling on a coat of house paint g, but I don't get why Richard was so dismissive about painting a boat. There are a lot of boats around here right now that are dry docked or up on stilts, having their topsides painted at the same time they're getting a new coat of bottom paint, before the weather gets too cold. Most of them are fiberglass boats. Because once you paint a hull - even with the very best paints - the maintenance truly begins. But that's not the real problem here. The REAL problem is that Gunner is a stalking troll. Really? Stalking Troll you say? So posting boat ads is..stalking? Is that like putting out bait during turkey season? Then you are saying you are as stupid as a turkey? Take the bait..take the bait..take the bait!! Snicker.... "At the core of liberalism is the spoiled child, miserable, as all spoiled children are, unsatisfied, demanding, ill-disciplined, despotic and useless. Liberalism is a philosophy of sniveling brats." PJ O'Rourke |
#52
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Fri, 31 Oct 2014 15:56:52 -0500, Richard
wrote: But that's boats. This project was a lot more fun - and less sweat. And there was even a little metal-working involved here! This all came about because I wanted a ray gun. A real honest to gosh ray gun! I guess the Buck Rogers weapons were okay - for their day. But the Bugs Bunny / Marvin the Martian type was the one. And it really really works! (echoes of Ron Propeil!?!) The basic design. Kinda spiffy, huh? http://www.home.earthlink.net/~cave-.../Raygun-01.jpg The shell is hand laid fiberglass over a foam core using 8 ounce woven cloth and west 105 epoxy. Both were selected after a detailed study of what was in the scrap box. Most of the glass was laid on in small patches because of the curvature, but every lay-up was closed out with a full sized wrap to help keep loose strings under control and give a smoother surface. In all three separate lay-ups were done to get the final shell. Using West 105 with 205 (fast) hardener the resin kicks and can be handled in half an hour. So it didn't take long to make the shell. The core was dissolved out with a little lacquer thinner leaving a the body hollow, but the insides sharp as 40 grit sandpaper. The shell was then filed and sanded inside and out to a smooth surface and finally gelcoated. This first one has a 15 mw laser pointer installed - because it was cheap and easy. And it's fun to use as a "kitty prod" to herd cats. The basic shell with the laser retainer hardware installed. http://www.home.earthlink.net/~cave-.../Raygun-02.jpg Laser goes in right about here... http://www.home.earthlink.net/~cave-.../Raygun-04.jpg The metal-working part... It took a few iterations to get the trigger shape right, but I'm happy with the results. I haven't measured the pull, but it's not heavy. The trigger was bandsawed from 1/4" aluminum plate and smoothed nicely. http://www.home.earthlink.net/~cave-.../Raygun-06.jpg The other part - call it the "loop"(?) - was blacksmithed from .063 steel strap by bending it around the correctly sized deep well socket and pounding it into submission with a hammer. The business end. http://www.home.earthlink.net/~cave-.../Raygun-07.jpg The pencil laser pointer is held in place with a sort piece of brass tube bonded in the front end, and a larger diameter piece in the aft end. The pencil fits over (ie outside) the front one and inside the aft one. Then a small plastic cap (from a sting-ez insect-sting stick - hey, it fit perfectly!!) holds the laser firmly in place. Up and running: http://www.home.earthlink.net/~cave-.../Raygun-08.jpg The second one (in the works now) will open up in the middle to allow for a 450 mw laser to be installed. Same shape and style, but a seriously more dangerous weapon. Fiberglass is fun stuff. All it takes is some imagination. http://www.instructables.com/id/Maki...erglass-parts/ Nicely done!! Gunner "At the core of liberalism is the spoiled child, miserable, as all spoiled children are, unsatisfied, demanding, ill-disciplined, despotic and useless. Liberalism is a philosophy of sniveling brats." PJ O'Rourke |
#53
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
On Fri, 31 Oct 2014 21:15:44 -0500, Richard
wrote: On 10/31/2014 8:08 PM, John B. Slocomb wrote: This message has been snipped some - just to show that the technology still works! Some people think a chalky boat is the epitome of success - because it takes no effort to maintain. And they are perfectly right - for them. Way back in the days of wooden boats I read an article in one of the U.S. magazines extolling topside paints that chalked easily. The writer said that they really hade the boot look good, longer, as when you scrubbed the topsides mid season the chalkiness scrubbed off taking the dirt and crud with it. The Maine lobster fishermen usually hauled once during the season and one chap came up with an ingenious scheme. They, of course, beached the boats, propped up with sticks and this guy, as soon as the tide started going out and the sticks started taking some weight started spraying the hull with Clorox from one of those back mounted spray tanks. Just walked round and round spraying. When the tide was pretty well all the way out he'd scrub the hull with a "straw Broom" and all the weeds and shell fish would fall off. He clamed that as he didn't have to scrape, the bottom paint wasn't damaged so he didn't have top re-paint half way through the season :-) Now that's a sailor! Fisherman actually :-) When I met the guy he was pulling 100 pots a day, so he had 200 lobster pots in the water. I suspect that other then not liking to scrape barnacles he was also in a hurry to get back in the water as those lobster pots needed hauling :-) Want to know the easiest way to do something? Put a smart lazy man on the job. The forty footer I owned, for some reason, had additional jib tracks added inboard of the original tracks on the gunnels. Apparently done by the previous owner who simply drilled holes through the deck and bolted them down. Needless to say, the holes leaked and the plywood core rutted in two six foot strips down the side decks, toward the forward end of the cockpit. I finally used a 4" hand grinder and sliced the fiberglass deck surface and removed two six foot long by about 18 inch wide sections. The plywood had turned into a black mush. I cleaned it out back to solid ply thinking that I could simply get some more plywood of the same thickness to "inlay". It turned out that the original plywood was some strange dimension that couldn't be duplicated and I ended up with a horrible job of gluing down a layer of ply, then building it up with epoxy filler and gluing the original deck sections back on top. A horrible mess trying to get the whole job smooth and fair with the old deck. Oh man. I feel your pain. A friend is involved with the Sea Scouts and sometimes get boats donated. One Catalina ancient 27 came in and the entire foredeck was spongy. He asked what it would cost to have it fixed. Well, traditional methods - more than the boat was worth - for sure. We tried something different. You know how that polyurethane Gorilla Glue foams up from moisture? We drilled some holes in the under side of the deck, poked plastic tubing down the length of the deck and squirted in 6 bottles of glue - one at a time. Squirt a bunch of glue and pull the hose out. Let it expand for a day or two(!). Then run another tube in as far as it will go and squirt in more glue. Didn't plug the holes or anything, just to let it relieve pressure. Put buckets under the drains and let it cook. I had a friend that tried to the same thing with that two part foam - mix the two parts and it foams up to ten or 20 times the volume of the liquid. He'd decided that his rudder wasn't big enough so he made a new one. Made a mold and laminated the two sides and glued them together, made a new shaft and all. Came over to get me to help. The scheme was that we would assemble the thing, stand it up straight and pour the mix in the top and it would expand and fill the hollow rudder and he could trim off the top and Viola! A new rudder. Unfortunately the stuff doesn't expand smoothly and progressively. It goes Whoosh and all expands at once and it awful sticky so it sticks to everything it comes in contact with. We ended up with a rudder that was half full of foam and twice the size it started. The next day he told me that after some thought he had decided that a larger rudder might be detrimental when the wind got up :-) A couple of weeks later the deck was solid as a rock again. The under side looked like hell. He didn't want to do anything but trim the foam off flush with a knife. He didn't want to mislead a buyer as to the condition of the boat. It sold soon after. Not much, but income for the Scouts. It's still sailing. A lot of work? Maybe. But a job that doesn't have to be reworked all the time is worth the extra expense and effort. At least that's how I feel. It all depends on your personal standards... -- Cheers, John B. |
#54
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1977 22' Catalina Capri Sailboat - $700 (Marina Del Rey)
Hunter 23 sailboat 1987 - $3200 (Lewisville)
http://dallas.craigslist.org/ndf/boa/4736043522.html Nice, solid Hunter 23 wing keel with trailer and outboard that fits the budget. Sails are in good shape. Below: V berth Large overhead opening hatch Shelves on both sides Shelf in forepeak Removable foot boards 12 volt circulation fan Salon Ray Jefferson 5000M VHF radio 3 X 12 volt access ports AM/FM cassette stereo Interior speakers Fold up salon table Bulkheads are solid 12 volt circulation fan Storage under settees Settes slide out to form berth Sliding galley module Sink Origo 1500 single burner alcohol stove Above: Stainless Steel bow pulpit Life lines Anchor locker(very deep) Mast winch Reefing mainsail w/ cover Sliding companionway hatch Mainsheet traveler 4:1 mainsheet Maxwell #14 sheet winches Gas locker to starboard Storage in port lazarette(very deep) Kick-up rudder Game Fisher 9.9hp outboard(haven't tried to start) Galvanized steel trailer Swivel tongue jack 15" wheels Bearing Buddys Extension tongue Call, Email or stop by to check her out. Two halyards, two cushion covers and a want to sail is all you need. "At the core of liberalism is the spoiled child, miserable, as all spoiled children are, unsatisfied, demanding, ill-disciplined, despotic and useless. Liberalism is a philosophy of sniveling brats." PJ O'Rourke |
#55
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Polyester gelcoat resins
John, this has been bugging the heck out of me -- I really hate it
when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g -- Ed Huntress |
#56
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Polyester gelcoat resins
On 11/6/2014 7:28 AM, Ed Huntress wrote:
John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. |
#57
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Polyester gelcoat resins
On Thu, 06 Nov 2014 08:41:26 -0600, Richard
wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. -- Ed Huntress |
#58
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Polyester gelcoat resins
On 11/6/2014 9:01 AM, Ed Huntress wrote:
On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. mek-P Don't forget the Peroxide! |
#59
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Polyester gelcoat resins
On Thu, 06 Nov 2014 11:14:16 -0600, Richard
wrote: On 11/6/2014 9:01 AM, Ed Huntress wrote: On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. mek-P Don't forget the Peroxide! Yeah, I see that they're putting that on the abbreviation now. For decades, the full name was used, but the abbreviation was just "MEK." I sometimes wish I knew something about chemistry. It was my weakest science subject. -- Ed Huntress |
#60
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Polyester gelcoat resins
"Ed Huntress" wrote in message
... On Thu, 06 Nov 2014 11:14:16 -0600, Richard wrote: On 11/6/2014 9:01 AM, Ed Huntress wrote: On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. mek-P Don't forget the Peroxide! Yeah, I see that they're putting that on the abbreviation now. For decades, the full name was used, but the abbreviation was just "MEK." I sometimes wish I knew something about chemistry. It was my weakest science subject. -- Ed Huntress "MEK" without the P refers to a common solvent resembling acetone. |
#61
Posted to rec.crafts.metalworking
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Polyester gelcoat resins
On Thu, 6 Nov 2014 13:08:24 -0500, "Jim Wilkins"
wrote: "Ed Huntress" wrote in message .. . On Thu, 06 Nov 2014 11:14:16 -0600, Richard wrote: On 11/6/2014 9:01 AM, Ed Huntress wrote: On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. mek-P Don't forget the Peroxide! Yeah, I see that they're putting that on the abbreviation now. For decades, the full name was used, but the abbreviation was just "MEK." I sometimes wish I knew something about chemistry. It was my weakest science subject. -- Ed Huntress "MEK" without the P refers to a common solvent resembling acetone. Good grief. I see that it's a natural component of chicken, apple juice, and cheese. I'm going to get off here, before this gets crazy. Thanks for the info, Jim...I think. g -- Ed Huntress |
#62
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Polyester gelcoat resins
On Thu, 06 Nov 2014 08:28:51 -0500, Ed Huntress
wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Ed, I think I wrote something like "I saw local guys..." or "The way that they do it here...". I can assure you that people here (however unlettered) are mixing a color pigment with polyester resin and slather it in the molds. Just about every "fiberglass shop" carries the pigments, it is that common. I think that the reason is that "proper" gel coat is very likely more expensive and probably not as easily available in local shops so the local guys don't use it as even with the recent doubling of the minimum wage here materials are still the most expensive part of job costs :-0 -- Cheers, John B. |
#63
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Polyester gelcoat resins
On Fri, 07 Nov 2014 08:35:49 +0700, John B. Slocomb
wrote: On Thu, 06 Nov 2014 08:28:51 -0500, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Ed, I think I wrote something like "I saw local guys..." or "The way that they do it here...". I can assure you that people here (however unlettered) are mixing a color pigment with polyester resin and slather it in the molds. Just about every "fiberglass shop" carries the pigments, it is that common. Oh, you did, and I don't doubt that they do it. I think that the reason is that "proper" gel coat is very likely more expensive and probably not as easily available in local shops so the local guys don't use it as even with the recent doubling of the minimum wage here materials are still the most expensive part of job costs :-0 I don't doubt that, either. But if I recall, somewhere in that discussion was the statement, or the implication, that gelcoat is nothing but laminating resin with pigment in it. I just wanted to clear up that point, in case anyone took that away from what we were saying. Mostly, I wanted to check my memory and clear it up for myself. I have some vivid memories of that work, but it was a *long* time ago. -- Ed Huntress |
#64
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Polyester gelcoat resins
On Thu, 06 Nov 2014 10:01:09 -0500, Ed Huntress
wrote: On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. Way back when I was in the Air Force the sheetmetal guys used what was likely polyester to make certain repairs on the B-52's (and probably other airplanes but I was in a B-52 wing :-) and in those days it was a three part mix, resin, hardener and an accelerator that they referred to as "cobalt". As I remember it the resin/hardener ratio was a constant and the cobalt was used for a longer or shorter hardening time. This wasn't my area of expertise but I've seen the Tin-benders mix stuff that set the paper mixing cup on fire. Rather impressive I thought :-) -- Cheers, John B. |
#65
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Polyester gelcoat resins
On Fri, 07 Nov 2014 08:48:37 +0700, John B. Slocomb
wrote: On Thu, 06 Nov 2014 10:01:09 -0500, Ed Huntress wrote: On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. Way back when I was in the Air Force the sheetmetal guys used what was likely polyester to make certain repairs on the B-52's (and probably other airplanes but I was in a B-52 wing :-) and in those days it was a three part mix, resin, hardener and an accelerator that they referred to as "cobalt". As I remember it the resin/hardener ratio was a constant and the cobalt was used for a longer or shorter hardening time. This wasn't my area of expertise but I've seen the Tin-benders mix stuff that set the paper mixing cup on fire. Rather impressive I thought :-) Yeah, a hot mix can be pretty exciting. Someone who's used to mixing a half-pint or less at a time, who mixes a gollon or two at the same ratio they used for quick cures in small batches, is in for a real surprise. g You can't make hot mixes of polyesterin big quantities without risking a fire and a complete loss of the batch. And a really hot mix can start a fire even in much smaller quantities. If you have a paper cup full and it catches on fire, that's 'way too hot to produce good mechanical properties in the cured resin. About the cobalt: Yes, and that's already pre-mixed in resins made for laminating boats. I've seen contradictory words used in the terminology, so I don't know which is really the catalyst, and which is the accelerator. But the cobalt compound percentage is fixed in ordinary resins. Military applications probably are much different. I'm surprised they used polyester, though. Its adhesive properties are pretty lousy, and a very small fraction of the adhesion of epoxy. And if it's military, it sure isn't because they're trying to save money. It may be the speed of cure that was required. Epoxies that cure at room temperature, in the time range of typical polyesters, are not strong epoxy resins, even if they set to an initial gel just as quickly. -- Ed Huntress |
#66
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Polyester gelcoat resins
On Thu, 06 Nov 2014 21:14:39 -0500, Ed Huntress
wrote: On Fri, 07 Nov 2014 08:48:37 +0700, John B. Slocomb wrote: On Thu, 06 Nov 2014 10:01:09 -0500, Ed Huntress wrote: On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. Way back when I was in the Air Force the sheetmetal guys used what was likely polyester to make certain repairs on the B-52's (and probably other airplanes but I was in a B-52 wing :-) and in those days it was a three part mix, resin, hardener and an accelerator that they referred to as "cobalt". As I remember it the resin/hardener ratio was a constant and the cobalt was used for a longer or shorter hardening time. This wasn't my area of expertise but I've seen the Tin-benders mix stuff that set the paper mixing cup on fire. Rather impressive I thought :-) Yeah, a hot mix can be pretty exciting. Someone who's used to mixing a half-pint or less at a time, who mixes a gollon or two at the same ratio they used for quick cures in small batches, is in for a real surprise. g You can't make hot mixes of polyesterin big quantities without risking a fire and a complete loss of the batch. And a really hot mix can start a fire even in much smaller quantities. If you have a paper cup full and it catches on fire, that's 'way too hot to produce good mechanical properties in the cured resin. About the cobalt: Yes, and that's already pre-mixed in resins made for laminating boats. I've seen contradictory words used in the terminology, so I don't know which is really the catalyst, and which is the accelerator. But the cobalt compound percentage is fixed in ordinary resins. Military applications probably are much different. I'm surprised they used polyester, though. Its adhesive properties are pretty lousy, and a very small fraction of the adhesion of epoxy. And if it's military, it sure isn't because they're trying to save money. It may be the speed of cure that was required. Epoxies that cure at room temperature, in the time range of typical polyesters, are not strong epoxy resins, even if they set to an initial gel just as quickly. This was years ago, probably in the late 1960's so I don't think that the guys in the sheet metal shop were that familiar with the stuff and to the best of my recollection they didn't use it very often. I vaguely remember them talking about temporary fixes on the B-52's but that is about all. I don't think that speed of curing was a critical part of it as the burning coffee cup was a demonstration my buddy did to sort of awe the natives - the natives being me and a guy from the welding shop :-0 -- Cheers, John B. |
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Polyester gelcoat resins
"John B. Slocomb" wrote in message
... On Thu, 06 Nov 2014 10:01:09 -0500, Ed Huntress wrote: On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. It's certainly a lot more complex than we've discussed so far. At Ranger, laminating resin was mixed, IIRC, 5 gallons at a time. There was a schedule for desired gel times, and a time/temperature chart that told you how much MEK would be required to meet those specs. They used a little graduated cup to measure out the MEK and it was mixed with a mechanical mixer. As I mentioned, I started there as a furniture bonder. We mixed much smaller quantities. We had a rule of thumb, but it was up to us to make small adjustments. My partner, who spoke no English, liked to get it over with fast. Some of his mixes actually bubbled and turned brown. He was overjoyed. The people who bought our boats may not have been. g In terms of end properties, polyester resins actually are quite flexible. You can get away with a pretty wide range of MEK percentages. The biggest danger, when you're working with large quantities and going slowly, is to use too little. The resin may never harden if you do that. If there's money involved and if that happens, sometimes they'll try to rescue the job by brushing on some kind of accelerator. Maybe it's MEK, but I don't think so. Sometimes it works, but it's really problematic. Way back when I was in the Air Force the sheetmetal guys used what was likely polyester to make certain repairs on the B-52's (and probably other airplanes but I was in a B-52 wing :-) and in those days it was a three part mix, resin, hardener and an accelerator that they referred to as "cobalt". As I remember it the resin/hardener ratio was a constant and the cobalt was used for a longer or shorter hardening time. This wasn't my area of expertise but I've seen the Tin-benders mix stuff that set the paper mixing cup on fire. Rather impressive I thought :-) -- Cheers, John B. http://en.wikipedia.org/wiki/Cobalt(II)_naphthenate http://en.wikipedia.org/wiki/Oil_drying_agent -jsw |
#68
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Polyester gelcoat resins
On 11/6/2014 7:48 PM, John B. Slocomb wrote:
This wasn't my area of expertise but I've seen the Tin-benders mix stuff that set the paper mixing cup on fire. Rather impressive I thought :-) Golly. I've done that with plain old polyester mix. Somebody "opened up" the hole in the MEKP bottle and the drops were actually squirts. Rather impressive, like you said. |
#69
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Polyester gelcoat resins
On 11/6/2014 7:46 PM, Ed Huntress wrote:
On Fri, 07 Nov 2014 08:35:49 +0700, John B. Slocomb wrote: On Thu, 06 Nov 2014 08:28:51 -0500, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap.g Ed, I think I wrote something like "I saw local guys..." or "The way that they do it here...". I can assure you that people here (however unlettered) are mixing a color pigment with polyester resin and slather it in the molds. Just about every "fiberglass shop" carries the pigments, it is that common. Oh, you did, and I don't doubt that they do it. I think that the reason is that "proper" gel coat is very likely more expensive and probably not as easily available in local shops so the local guys don't use it as even with the recent doubling of the minimum wage here materials are still the most expensive part of job costs :-0 I don't doubt that, either. But if I recall, somewhere in that discussion was the statement, or the implication, that gelcoat is nothing but laminating resin with pigment in it. Not at all. But you COULD say that gelcoat is nothing but laminating resin with WAX added... I just wanted to clear up that point, in case anyone took that away from what we were saying. Mostly, I wanted to check my memory and clear it up for myself. I have some vivid memories of that work, but it was a *long* time ago. |
#70
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Polyester gelcoat resins
On Fri, 07 Nov 2014 10:59:49 -0600, Richard
wrote: On 11/6/2014 7:46 PM, Ed Huntress wrote: On Fri, 07 Nov 2014 08:35:49 +0700, John B. Slocomb wrote: On Thu, 06 Nov 2014 08:28:51 -0500, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap.g Ed, I think I wrote something like "I saw local guys..." or "The way that they do it here...". I can assure you that people here (however unlettered) are mixing a color pigment with polyester resin and slather it in the molds. Just about every "fiberglass shop" carries the pigments, it is that common. Oh, you did, and I don't doubt that they do it. I think that the reason is that "proper" gel coat is very likely more expensive and probably not as easily available in local shops so the local guys don't use it as even with the recent doubling of the minimum wage here materials are still the most expensive part of job costs :-0 I don't doubt that, either. But if I recall, somewhere in that discussion was the statement, or the implication, that gelcoat is nothing but laminating resin with pigment in it. Not at all. But you COULD say that gelcoat is nothing but laminating resin with WAX added.. Don't get me started. g. Only the gelcoat that you spray on the outside of a hull. The original gelcoat, which they spray on the inside of a mold, has no wax. Unless you make it out of laminating resin, then it *probably* has wax. d8-) It's preferred not to use wax when another layer of polyester is going on top, and there's usually no wax in commercial gel coat made for spraying in a mold. That's sometimes true with the laminating resin, too, except for the last coat. Or it was, decades ago. The wax doesn't make much difference if wet resin it layed on top. The wax dissolves, and starts floating to the top again. But you only need it on the final layer, because polyester is air-inhibited. Now I'm done. I have to get ready to go to FABTECH in Atlanta. -- Ed Huntress I just wanted to clear up that point, in case anyone took that away from what we were saying. Mostly, I wanted to check my memory and clear it up for myself. I have some vivid memories of that work, but it was a *long* time ago. |
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#72
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On 11/7/2014 12:08 PM, Ian Malcolm wrote:
wrote in news:Ydqdncz1e6oLZ8HJnZ2dnUU7- : Not at all. But you COULD say that gelcoat is nothing but laminating resin with WAX added... No. Commercial gelcoat does *NOT* contain wax as it would impair the bond to the laminating resin in the layup being applied to the gelcoat in the mold. Flocoat contains wax for a non-tacky surface cure. Some entry level gelcoat repair kits contain wax, but if you are serious, you either seal polythene sheet over the repair to exclude air or use wax in styrene additive. Ok, I guess I'll retract that. The stuff I use does have wax so that it is self sealing, but I take the point... |
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Polyester gelcoat resins
On Thu, 06 Nov 2014 08:41:26 -0600, Richard
wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. Indeed! Well stated. With Luck and the sacrifice of ones first born child..one might get a color match. As for its strength..it has none and it is rather brittle as witnessed by the "spiderwebbing" on boat hulls in impact zones and flex points "At the core of liberalism is the spoiled child, miserable, as all spoiled children are, unsatisfied, demanding, ill-disciplined, despotic and useless. Liberalism is a philosophy of sniveling brats." PJ O'Rourke |
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Polyester gelcoat resins
On Fri, 7 Nov 2014 18:08:12 +0000 (UTC), Ian Malcolm
wrote: Richard wrote in news:Ydqdncz1e6oLZ8HJnZ2dnUU7- : Not at all. But you COULD say that gelcoat is nothing but laminating resin with WAX added... No. Commercial gelcoat does *NOT* contain wax as it would impair the bond to the laminating resin in the layup being applied to the gelcoat in the mold. Flocoat contains wax for a non-tacky surface cure. Some entry level gelcoat repair kits contain wax, but if you are serious, you either seal polythene sheet over the repair to exclude air or use wax in styrene additive. Ayup. "At the core of liberalism is the spoiled child, miserable, as all spoiled children are, unsatisfied, demanding, ill-disciplined, despotic and useless. Liberalism is a philosophy of sniveling brats." PJ O'Rourke |
#75
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Polyester gelcoat resins
On Sat, 08 Nov 2014 11:34:48 -0600, Richard
wrote: On 11/7/2014 12:08 PM, Ian Malcolm wrote: wrote in news:Ydqdncz1e6oLZ8HJnZ2dnUU7- : Not at all. But you COULD say that gelcoat is nothing but laminating resin with WAX added... No. Commercial gelcoat does *NOT* contain wax as it would impair the bond to the laminating resin in the layup being applied to the gelcoat in the mold. Flocoat contains wax for a non-tacky surface cure. Some entry level gelcoat repair kits contain wax, but if you are serious, you either seal polythene sheet over the repair to exclude air or use wax in styrene additive. Ok, I guess I'll retract that. The stuff I use does have wax so that it is self sealing, but I take the point... The stuff you have likely is made for applying *after* a part is pulled from a mold, on the outside of the laminate.. You need the wax for that, or the surface could stay tacky forever. As Ian says, there are better ways to block the air from the gelcoat, but most external application is repair work, and, at Ranger, we added wax (or our repair specialist did) for making patches. Gelcoat sprayed in a mold, where it's covered with layers of glass and resin, doesn't need it -- and is much better off without it. The gelcoat-to-laminate bond is the most critical one, and needs the strongest bond. Since I have a few minutes g let me try to add to this discussion. Polyester resin is a very poor adhesive. If you lay one layer of cloth or woven roving (which is very coarse cloth) on top of another, the peel strength and shear strength are very poor. The same is true if you lay any fiberglass, including random-oriented mat, on top of already-sured resin or even gelled, but not cured resin. That's what happens when you lay the first layer of mat (or veil -- see below) on top of the gelcoat in a mold. It has to be firmly gelled before you do that or you'll poke through the gelcoat. And the result of letting the gelcoat partially gel before continuing the laminating is that you need all the help you can get to stick it to the next layer of laminate -- no wax, please. Now, about the interlayer strength of the laminate. Again, adhesive strength of polyester resin is very poor. Cloth-to-cloth layers often can be peeled apart by hand. The highest quality laminates, as in expensive racing dinghies, use a minimum of mat because mat layers are weak. But those boats, like all other expertly done polyester laminates, must use mat between layers of cloth. Or they use veil, also called "scrim," which is a very thin, semi-transparent layer of mat. You get the best strength-to-weight, and stiffness-to-weight, using veil and fairly light layers of cloth. (you can look up E-glass versus S-glass to get more detail on making the best polyester laminates.) When the resin, or the styrene monomer in the resin, dissolves the binder that holds dry mat together, the fibers get loose and tend to "cog" their way into the layers of cloth above and below as the layers are brushed out, and poked with the brush, or rolled out with a disk roller. This assumes that all layers are still wet. That's where the interlayer strength comes from. Polyester is a lousy adhesive but it has decent bulk strength, in a laminate, at least, and it holds those cogged pieces of mat into an interlocked mass with the cloth. (The cloth is inherently stronger because of the long-fiber orientation, not really because the fibers are just longer.) That overcomes the lack of peel strength and sheer strength in the resin. Unfortunately, you can't achieve the high glass-to-resin ratios with mat that you can with cloth, so the mat parts of a laminate are inherently weaker and a lot less flexible. Any boat that uses more than a minimum necessary amount of mat is less strong -- but cheaper to build. About wax: The best deal is to use resin without wax until you get to the last layer, the one that will be cured while exposed to air. But the wax dissolves in the resin, and, if you lay one layer of waxed resin on rop of another, most of the wax will dissolve again and rise to the top. How much, I don't know, but I know that many boats have been made with waxed resin in each layer of laminate, and I've never heard of it causing a delaminating problem by itself. Maybe it does; perhaps Ian knows. One final thing: None of this applies to epoxy laminates. Epoxy has such strong adhesive properties that you can laminate one layer of cloth on top of another. Epoxy laminates are a lot stronger to begin with. Avoiding the use of mat makes them even stronger. Watch out, though, that your glass cloth, or mat if you use any with epoxy, are made for use with epoxy. The finish on glass cloth made for polyester is actually weaker than a straight glass-to-epoxy bond. Don't use it. As for mat, the binder won't dissolve in epoxy. Try it, and you're likely to get a real mess. (this is the voice of sad experience -- before I learned about this). But you shouldn't be using mat with epoxy in the first place. Epoxy make a much stronger laminate without it. Phwew. g -- Ed Huntress |
#76
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Polyester gelcoat resins
On Sat, 08 Nov 2014 09:48:00 -0800, Gunner Asch
wrote: On Thu, 06 Nov 2014 08:41:26 -0600, Richard wrote: On 11/6/2014 7:28 AM, Ed Huntress wrote: John, this has been bugging the heck out of me -- I really hate it when I don't have a precise answer, so I did some checking to see that the story is on polyester gelcooat resin. Quality commercial gelcoats are made from an entirely different resin than laminating resin. Gelcoats are based on ISO/NPG (Isophthalic/Neopentyl Glychol) resins, which are much stronger, clearer, and more scratch-resistant than ordinary laminating resin, which is orthophthalic resin. In the course of checking this out I read that high-quality boatbuilders are switching to ISO/NPG resin for laminating, too, but that wasn't true when I was involved with it, so I don't know anything about that. You no doubt know that common plastic laminating resins, particularly epoxy, have no natural thixotropic properties. Spray or brush them on a vertical surface, and they drool. Commerical polyester gelcoat resins are loaded with thixotropic agents so you can lay on a fairly thick, even coat that doesn't drool. If you cut all the way through the gelcoat on a cheap boat, you may find that the gelcoat is very uneven in thickness. Sometimes you can see this as ripples on the outside surface, because shrinkage upon curing makes the thick-and-thin stand out. But most builders conquered that problem decades ago. In the US, they use commercial gelcoat resin from the start. FWIW, even ISO/NPG resin, compared to most other resin systems, is weak and brittle. Without the glass fiber in it for reinforcement, a good gelcoat resin is mechanically much weaker than the laminate beneath it. But it does the job acceptably well. And, as you pointed out, it's cheap. g Excellent research, Ed. After all this comes the actual mix. The resin to catalyst ratio is a few drops of MEKP (methylethelkeytoneperoxide) per pound of resin. So how big is a drop? Rule of thumb? Roughly 50 CCs per gallon? So you can see that a little bit goes a LONG way. What might be the results from variations in the mix? Or how well mixed the mix is in the first place? At what temperature is this all done? Humidity? Alignment of the stars and planets? Lots of possible very small variations that have rather profound effects in the end product. Indeed! Well stated. With Luck and the sacrifice of ones first born child..one might get a color match. As for its strength..it has none and it is rather brittle as witnessed by the "spiderwebbing" on boat hulls in impact zones and flex points Good points. Spider cracks are more of a problem in thin hulls, but evern good polyester gelcoat on a thicker hull is not immune. Two-part polyurethane generally is. Thus, some of the very best racing boats are built with no gelcoat at all, and are sprayed with polyurethane after they're pulled from the mold. Color matching patches is a job for a very experienced pro, and even then, God help you if your boat is a medium color, like red or medium blue. -- Ed Hutnress |
#77
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Polyester gelcoat resins
On 11/8/2014 12:16 PM, Ed Huntress wrote:
On Sat, 08 Nov 2014 11:34:48 -0600, wrote: On 11/7/2014 12:08 PM, Ian Malcolm wrote: wrote in news:Ydqdncz1e6oLZ8HJnZ2dnUU7- : Not at all. But you COULD say that gelcoat is nothing but laminating resin with WAX added... No. Commercial gelcoat does *NOT* contain wax as it would impair the bond to the laminating resin in the layup being applied to the gelcoat in the mold. Flocoat contains wax for a non-tacky surface cure. Some entry level gelcoat repair kits contain wax, but if you are serious, you either seal polythene sheet over the repair to exclude air or use wax in styrene additive. Ok, I guess I'll retract that. The stuff I use does have wax so that it is self sealing, but I take the point... The stuff you have likely is made for applying *after* a part is pulled from a mold, on the outside of the laminate.. You need the wax for that, or the surface could stay tacky forever. As Ian says, there are better ways to block the air from the gelcoat, but most external application is repair work, and, at Ranger, we added wax (or our repair specialist did) for making patches. Gelcoat sprayed in a mold, where it's covered with layers of glass and resin, doesn't need it -- and is much better off without it. The gelcoat-to-laminate bond is the most critical one, and needs the strongest bond. Since I have a few minutesg let me try to add to this discussion. Polyester resin is a very poor adhesive. If you lay one layer of cloth or woven roving (which is very coarse cloth) on top of another, the peel strength and shear strength are very poor. The same is true if you lay any fiberglass, including random-oriented mat, on top of already-sured resin or even gelled, but not cured resin. That's what happens when you lay the first layer of mat (or veil -- see below) on top of the gelcoat in a mold. It has to be firmly gelled before you do that or you'll poke through the gelcoat. And the result of letting the gelcoat partially gel before continuing the laminating is that you need all the help you can get to stick it to the next layer of laminate -- no wax, please. Now, about the interlayer strength of the laminate. Again, adhesive strength of polyester resin is very poor. Cloth-to-cloth layers often can be peeled apart by hand. The highest quality laminates, as in expensive racing dinghies, use a minimum of mat because mat layers are weak. But those boats, like all other expertly done polyester laminates, must use mat between layers of cloth. Or they use veil, also called "scrim," which is a very thin, semi-transparent layer of mat. You get the best strength-to-weight, and stiffness-to-weight, using veil and fairly light layers of cloth. (you can look up E-glass versus S-glass to get more detail on making the best polyester laminates.) When the resin, or the styrene monomer in the resin, dissolves the binder that holds dry mat together, the fibers get loose and tend to "cog" their way into the layers of cloth above and below as the layers are brushed out, and poked with the brush, or rolled out with a disk roller. This assumes that all layers are still wet. That's where the interlayer strength comes from. Polyester is a lousy adhesive but it has decent bulk strength, in a laminate, at least, and it holds those cogged pieces of mat into an interlocked mass with the cloth. (The cloth is inherently stronger because of the long-fiber orientation, not really because the fibers are just longer.) That overcomes the lack of peel strength and sheer strength in the resin. Unfortunately, you can't achieve the high glass-to-resin ratios with mat that you can with cloth, so the mat parts of a laminate are inherently weaker and a lot less flexible. Any boat that uses more than a minimum necessary amount of mat is less strong -- but cheaper to build. About wax: The best deal is to use resin without wax until you get to the last layer, the one that will be cured while exposed to air. But the wax dissolves in the resin, and, if you lay one layer of waxed resin on rop of another, most of the wax will dissolve again and rise to the top. How much, I don't know, but I know that many boats have been made with waxed resin in each layer of laminate, and I've never heard of it causing a delaminating problem by itself. Maybe it does; perhaps Ian knows. One final thing: None of this applies to epoxy laminates. Epoxy has such strong adhesive properties that you can laminate one layer of cloth on top of another. Epoxy laminates are a lot stronger to begin with. Avoiding the use of mat makes them even stronger. Watch out, though, that your glass cloth, or mat if you use any with epoxy, are made for use with epoxy. The finish on glass cloth made for polyester is actually weaker than a straight glass-to-epoxy bond. Don't use it. As for mat, the binder won't dissolve in epoxy. Try it, and you're likely to get a real mess. (this is the voice of sad experience -- before I learned about this). But you shouldn't be using mat with epoxy in the first place. Epoxy make a much stronger laminate without it. Phwew.g Preaching to the choir, Ed. I'm an epoxy guy. I've used polyester in the (far) past, but gave it up as soon as I found the light. My first love was Dow 330, but it's not made any more. It was fairly benign stuff as toxic chemicals go, but would crystallize at cool temps. One only had to warm it up to be usable again, but that was too much hassle for too many users. These days it's mostly West 105, unless there is a physical requirement that is beyond what that stuff can provide. Strictly volan coated woven glass for me. |
#78
Posted to rec.crafts.metalworking
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Polyester gelcoat resins
On Sat, 08 Nov 2014 15:45:53 -0600, Richard
wrote: On 11/8/2014 12:16 PM, Ed Huntress wrote: On Sat, 08 Nov 2014 11:34:48 -0600, wrote: On 11/7/2014 12:08 PM, Ian Malcolm wrote: wrote in news:Ydqdncz1e6oLZ8HJnZ2dnUU7- : Not at all. But you COULD say that gelcoat is nothing but laminating resin with WAX added... No. Commercial gelcoat does *NOT* contain wax as it would impair the bond to the laminating resin in the layup being applied to the gelcoat in the mold. Flocoat contains wax for a non-tacky surface cure. Some entry level gelcoat repair kits contain wax, but if you are serious, you either seal polythene sheet over the repair to exclude air or use wax in styrene additive. Ok, I guess I'll retract that. The stuff I use does have wax so that it is self sealing, but I take the point... The stuff you have likely is made for applying *after* a part is pulled from a mold, on the outside of the laminate.. You need the wax for that, or the surface could stay tacky forever. As Ian says, there are better ways to block the air from the gelcoat, but most external application is repair work, and, at Ranger, we added wax (or our repair specialist did) for making patches. Gelcoat sprayed in a mold, where it's covered with layers of glass and resin, doesn't need it -- and is much better off without it. The gelcoat-to-laminate bond is the most critical one, and needs the strongest bond. Since I have a few minutesg let me try to add to this discussion. Polyester resin is a very poor adhesive. If you lay one layer of cloth or woven roving (which is very coarse cloth) on top of another, the peel strength and shear strength are very poor. The same is true if you lay any fiberglass, including random-oriented mat, on top of already-sured resin or even gelled, but not cured resin. That's what happens when you lay the first layer of mat (or veil -- see below) on top of the gelcoat in a mold. It has to be firmly gelled before you do that or you'll poke through the gelcoat. And the result of letting the gelcoat partially gel before continuing the laminating is that you need all the help you can get to stick it to the next layer of laminate -- no wax, please. Now, about the interlayer strength of the laminate. Again, adhesive strength of polyester resin is very poor. Cloth-to-cloth layers often can be peeled apart by hand. The highest quality laminates, as in expensive racing dinghies, use a minimum of mat because mat layers are weak. But those boats, like all other expertly done polyester laminates, must use mat between layers of cloth. Or they use veil, also called "scrim," which is a very thin, semi-transparent layer of mat. You get the best strength-to-weight, and stiffness-to-weight, using veil and fairly light layers of cloth. (you can look up E-glass versus S-glass to get more detail on making the best polyester laminates.) When the resin, or the styrene monomer in the resin, dissolves the binder that holds dry mat together, the fibers get loose and tend to "cog" their way into the layers of cloth above and below as the layers are brushed out, and poked with the brush, or rolled out with a disk roller. This assumes that all layers are still wet. That's where the interlayer strength comes from. Polyester is a lousy adhesive but it has decent bulk strength, in a laminate, at least, and it holds those cogged pieces of mat into an interlocked mass with the cloth. (The cloth is inherently stronger because of the long-fiber orientation, not really because the fibers are just longer.) That overcomes the lack of peel strength and sheer strength in the resin. Unfortunately, you can't achieve the high glass-to-resin ratios with mat that you can with cloth, so the mat parts of a laminate are inherently weaker and a lot less flexible. Any boat that uses more than a minimum necessary amount of mat is less strong -- but cheaper to build. About wax: The best deal is to use resin without wax until you get to the last layer, the one that will be cured while exposed to air. But the wax dissolves in the resin, and, if you lay one layer of waxed resin on rop of another, most of the wax will dissolve again and rise to the top. How much, I don't know, but I know that many boats have been made with waxed resin in each layer of laminate, and I've never heard of it causing a delaminating problem by itself. Maybe it does; perhaps Ian knows. One final thing: None of this applies to epoxy laminates. Epoxy has such strong adhesive properties that you can laminate one layer of cloth on top of another. Epoxy laminates are a lot stronger to begin with. Avoiding the use of mat makes them even stronger. Watch out, though, that your glass cloth, or mat if you use any with epoxy, are made for use with epoxy. The finish on glass cloth made for polyester is actually weaker than a straight glass-to-epoxy bond. Don't use it. As for mat, the binder won't dissolve in epoxy. Try it, and you're likely to get a real mess. (this is the voice of sad experience -- before I learned about this). But you shouldn't be using mat with epoxy in the first place. Epoxy make a much stronger laminate without it. Phwew.g Preaching to the choir, Ed. I'm an epoxy guy. I've used polyester in the (far) past, but gave it up as soon as I found the light. My first love was Dow 330, but it's not made any more. It was fairly benign stuff as toxic chemicals go, but would crystallize at cool temps. One only had to warm it up to be usable again, but that was too much hassle for too many users. These days it's mostly West 105, unless there is a physical requirement that is beyond what that stuff can provide. Strictly volan coated woven glass for me. I use both for small projects, depending on what is needed. I made some giant clams out of polyester and mat, with a thin cloth coating, for my wife's classroom presentation about the deep sea. I figured they'd last long enough. g I'm a fan of the WEST System, but I usually use System Three. It is, or was, a lot less expensive. I've had good results with both. BTW, speaking of the WEST System, I've sailed with the Gougeon brothers, on Adazio, when all three were young. http://www.westsystem.com/ss/old-lad...-70-mph-blast/ -- Ed Huntress |
#80
Posted to rec.crafts.metalworking
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Polyester gelcoat resins
On Sat, 08 Nov 2014 13:16:28 -0500, Ed Huntress
wrote: On Sat, 08 Nov 2014 11:34:48 -0600, Richard wrote: On 11/7/2014 12:08 PM, Ian Malcolm wrote: wrote in news:Ydqdncz1e6oLZ8HJnZ2dnUU7- : Not at all. But you COULD say that gelcoat is nothing but laminating resin with WAX added... No. Commercial gelcoat does *NOT* contain wax as it would impair the bond to the laminating resin in the layup being applied to the gelcoat in the mold. Flocoat contains wax for a non-tacky surface cure. Some entry level gelcoat repair kits contain wax, but if you are serious, you either seal polythene sheet over the repair to exclude air or use wax in styrene additive. Ok, I guess I'll retract that. The stuff I use does have wax so that it is self sealing, but I take the point... The stuff you have likely is made for applying *after* a part is pulled from a mold, on the outside of the laminate.. You need the wax for that, or the surface could stay tacky forever. As Ian says, there are better ways to block the air from the gelcoat, but most external application is repair work, and, at Ranger, we added wax (or our repair specialist did) for making patches. Gelcoat sprayed in a mold, where it's covered with layers of glass and resin, doesn't need it -- and is much better off without it. The gelcoat-to-laminate bond is the most critical one, and needs the strongest bond. Since I have a few minutes g let me try to add to this discussion. Polyester resin is a very poor adhesive. If you lay one layer of cloth or woven roving (which is very coarse cloth) on top of another, the peel strength and shear strength are very poor. The same is true if you lay any fiberglass, including random-oriented mat, on top of already-sured resin or even gelled, but not cured resin. That's what happens when you lay the first layer of mat (or veil -- see below) on top of the gelcoat in a mold. It has to be firmly gelled before you do that or you'll poke through the gelcoat. And the result of letting the gelcoat partially gel before continuing the laminating is that you need all the help you can get to stick it to the next layer of laminate -- no wax, please. Now, about the interlayer strength of the laminate. Again, adhesive strength of polyester resin is very poor. Cloth-to-cloth layers often can be peeled apart by hand. The highest quality laminates, as in expensive racing dinghies, use a minimum of mat because mat layers are weak. But those boats, like all other expertly done polyester laminates, must use mat between layers of cloth. Or they use veil, also called "scrim," which is a very thin, semi-transparent layer of mat. You get the best strength-to-weight, and stiffness-to-weight, using veil and fairly light layers of cloth. (you can look up E-glass versus S-glass to get more detail on making the best polyester laminates.) When the resin, or the styrene monomer in the resin, dissolves the binder that holds dry mat together, the fibers get loose and tend to "cog" their way into the layers of cloth above and below as the layers are brushed out, and poked with the brush, or rolled out with a disk roller. This assumes that all layers are still wet. That's where the interlayer strength comes from. Polyester is a lousy adhesive but it has decent bulk strength, in a laminate, at least, and it holds those cogged pieces of mat into an interlocked mass with the cloth. (The cloth is inherently stronger because of the long-fiber orientation, not really because the fibers are just longer.) That overcomes the lack of peel strength and sheer strength in the resin. Unfortunately, you can't achieve the high glass-to-resin ratios with mat that you can with cloth, so the mat parts of a laminate are inherently weaker and a lot less flexible. Any boat that uses more than a minimum necessary amount of mat is less strong -- but cheaper to build. About wax: The best deal is to use resin without wax until you get to the last layer, the one that will be cured while exposed to air. But the wax dissolves in the resin, and, if you lay one layer of waxed resin on rop of another, most of the wax will dissolve again and rise to the top. How much, I don't know, but I know that many boats have been made with waxed resin in each layer of laminate, and I've never heard of it causing a delaminating problem by itself. Maybe it does; perhaps Ian knows. One final thing: None of this applies to epoxy laminates. Epoxy has such strong adhesive properties that you can laminate one layer of cloth on top of another. Epoxy laminates are a lot stronger to begin with. Avoiding the use of mat makes them even stronger. Watch out, though, that your glass cloth, or mat if you use any with epoxy, are made for use with epoxy. The finish on glass cloth made for polyester is actually weaker than a straight glass-to-epoxy bond. Don't use it. As for mat, the binder won't dissolve in epoxy. Try it, and you're likely to get a real mess. (this is the voice of sad experience -- before I learned about this). But you shouldn't be using mat with epoxy in the first place. Epoxy make a much stronger laminate without it. Phwew. g While you are accurate in saying that the binder used in common chopped mat is dissolved by styrene based resins and not by epoxy resins, common chopped mat can still be used with epoxy. If you are careful and completely wet out chopped mat with epoxy you can make a composite that is very satisfactory for most uses. The difference between water absorbency between epoxy and cloth and epoxy and chopped mat, for example, is about 0.4%. The WEST Systems people have done tests of epoxy and common chopped mate, see: http://www.westsystem.com/ss/chopped-strand-mat-epoxy/ and while they don't suggest it as a first choice they do say that it is usable. I might mention that I've used a fair amount of chopped mat with epoxy with no problems whatsoever. Not, I might add, because I thought it was better but because I had a considerable amount of it on hand and no woven cloth of the right weight :-) -- Cheers, John B. |
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