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Paul Barker Paul Barker is offline
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You're thinking on the right lines.

Sometimes you can clear the seat of the prv by geting th ehating roasting hot switching off the boiler and manually blowing a good jet out of the prv. If this fails you do have to change it.

As a secondary issue check the expansion vessel. If it is working correctly the pressure in the system should rise about 1/2 a bar from cold to hot, this depends on the size of your system. If it only rises to around 1/2 a bar greater, then no need to investigate further.

If it is faulty, let all the air out (if there is any) of the Shrieder valve (bike pump valve). If water comes out you need a new vessel. If air or no air but no water either, drain your system until there is 1/2 a bar showing on your built in guage. Get your bike pump and manually pump up the vessel a further 1/2 to 1 bar i.e. watch the guage go up by that amount. (whatever pressure your manufacturers instructions advise, 0.75 bar if no advice.).