Chip failure and air corrossion products
Mpfffff..... Some clarification required.
FINE silver plating (most of it) *will not* tarnish from exposure to air, nor will it form sulphur compounds - without other contributing factors. Sterling silver (.925 silver) is an entirely different matter.
What is going on here electro-galvanic (galvanic action) *corrosion* of the copper plating under the silver - and most things electro-silver-plated other than brass are first copper-plated to guarantee proper adhesion.
The black material noted is CuO, not tarnished silver.
Peter Wieck
Melrose Park, PA
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