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#121
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
"Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "J. Clarke" wrote in message in.local... In article , says... "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: [snip] Now, about EPA overreach and the dishwasher detergent regulations: They aren't from EPA at all. It's 16 individual states that enacted the near-ban in 2009 and 2010. The question is what prompted them. And if the EPA had declared dishwasher detergent phosphate use as de minimus, the states would not have argued. Actually, they could not have argued, by federal preemption. So, we are back in Washington. Uh, I'm not sure where preemption enters this. EPA did not dictate to the states what they had to do. They supplied research and analysis. There was a recent Supreme Court case on just this. If the Feds have entered an area, the states have to back off. For instance http://www.faegre.com/13445. There may be others, but I wasn't paying attention at the time. Joe Gwinn Yeah, I'm aware of the law regarding federal preemption, but I have seen no evidence that it applies in this case. If the EPA wrote a regulation on it and if a state tried to oppose it, there would be a preemption case. Again, I have not come across any such issue in the little reading I've done about it. I believe that he's saying that IF the EPA had declared phosphates in dishwasher detergent to be ACCEPTABLE then the states could not have banned it. If that's what he's saying, that's not the case. On the other hand, if the EPA banned it, and a state tried to legalize it, preemption would have kicked in. That's the case with lots of laws. Unless there's a 14th Amendment issue involved (regarding a "fundamental right"), or some specific federal authorization, states can make more restrictive laws than the related federal ones. Those issues have been involved, with the resolution still to be determined, over immigration. Likewise, even after a constitutional Amendment legalizing alcohol, states can regulate it, and can authorize municipalities to outlaw its sale. I didn't follow this dishwasher-detergent/phosphate law to the end of the line, but it looks like the EPA wasn't involved in the bans. It appears that it's all state law. I could be mistaken, but I didn't see any federal administrative law involved in it. I don't recall that the EPA did anything explicit either, which is the point. The EPA could have prevented extension to dishwasher detergents with a word, but chose not to. (One assumes that there were lots of private discussions.) In other words, if the EPA had said that a dishwashing detergent phosphate ban was unnecessary, it would have undermined efforts in the states to legislate or by regulation impose such a ban, and no such bans would have happened. Joe Gwinn I have no way to know if that's the case, but, assuming it is, I'd still want to see some up-to-date reports that analyze these challenged rivers and estuaries before making a judgment. I'm not convinced that the cost of eliminating phosphates is greater than the cost of not doing so. Notice the slide here, from dishwashing detergents (which struggle to be a 0.5% problem) to all phosphates (95% of which are used in agriculture, and thus are largely out of reach). Joe, do you remember the numbers from that report I cited? Point-source outflows were measured as 80% of the phosphate source in this river. Since there is no tertiary recovery, the conclusion is that almost all of that comes from detergents. I don't doubt that in Delaware, the point sources were significant (it's an outlier, but never mind), but there is no way that such a study can tell dishwasher detergent from clothes washer detergent from human effluent. Phosphate is phosphate. And the point remains that dishwasher detergent struggles to be 0.5% of the problem, and probably far less. If you want, I'll post a link to the study. It's long and dull, but, hey, that's my life. d8-) Sure. Life has been too interesting. As in the ancient Chinese curse "may you live in interesting times". Which would be false advertising in this case, the part about interesting, but never mind. Ok, you asked for it. Here's a quick summary of what has happened in the Delaware Basin: http://www.wra.udel.edu/node/43 There also are some others that are specific to the municipal outflow problems, which used to be horrific, but this one will keep you busy. It's an interesting type of study: http://www.ceoe.udel.edu/CMS/tchurch...31-160/151.pdf I lost the discussion and timeline about phosphates from Rutgers Univ. again, but I found the original data from which it was written. Take a look at the graph in Figure 3-6, page 16 of the PDF: http://www.state.nj.us/drbc/regs/MONa.pdf The total phosophus levels drepped from roughly 32 mu-M in 1969 to about 12 in 1975, and then to 4 by 1982. The dramatic fall in the early '70s corresponds with the elmination of detergent phosphates here at that time, when New York State outlawed it, NJ and PA threatened it, and the detergent makers pulled it out on their own because the market wouldn't support two versions (and we were being bombarded with PSAs to use non-phosphate detergents). If you want to see the discussion, I'll try to find it again. If you really get into the whole Delaware situation, here is an extremely detailed report. But I can't recommend it . It's 200 pages long: g http://www.wr.udel.edu/publications/...t_07042008.pdf And as for dead rivers in Delaware and NJ, the claim is being made that these rivers were restored by the phosphate ban. Forgotten is all the cleanups of the chemical industry that happened at the same time. (I lived in NJ in the late 1950s, and do remember the smell of the chemical plants.) So which cleanup caused which good effect? Or, was it the aggregate of all the cleanups? What chemical industry are you talking about? The only chemical industry on the Delaware is around Philadelphia, just before it dumps into the bay. Huh? The big smell was close to NYC. I lived in the Philadelphia suburbs, and the smell wasn't so large. Or I was inured to it. Whatever. You're talking about the refineries and petrochemical plants around Elizabeth. They dump into the Newark Bay and Hudson estuary. That's the opposite side of the state from the Delaware, and there is no connection. The whole middle Delaware and much of the upper Delaware were dead when I was a kid. Completely dead. It was not the chemical industry. There wasn't any up there. Umm. I think deeper research is indicated here. Polluters need not be chemical industry, and NJ is and was heavily industrial. Mostly on the eastern side of the state, Joe. Again, that has nothing to do with the Delaware. And the issue with the Delaware has always been oxygen deplation from excessive nutrient loads, not from chemical toxicity. The chemical problems are on my side of the state, in the Passaic River, the Raritan River, Newark Bay and the Hudson estuary. National Lead damned near paved the bottom of the Raritan before it was shut down. You may be thinking of the Raritan or the Passaic Rivers. They both have serious chemical problems. In the case of the Raritan, a lot of it comes from the closed John's Manville and National Lead plants, plus two others that dumped heavy metals and paint chemicals. The Hudson's problem is PCBs. I don't know specifically what the Passaic's problem is. Doesn't this prove my point? Huh? You aren't following the issue, or you need to look more closely at the geography. The chemcial pollution problems we have on the Atlantic side of NJ are unrelated to the oxygen-depletion and eutrification issues in the Deleware. Again, that report gave a pretty good analysis of before-and-after phosphate loads on the Delaware before and after the original ban, at numerous points along the river, so the evidence is not trivial. I'm not going to try to judge its veracity; I don't do chemistry. But the evidence does seem pretty clear. Well, I'd like to read the report. Have fun with the above. g I'd recommend a quick look at Figure 3-6 in this report first, which I also listed above. It dramatically shows what the phosphate history is. Because it's based on actual water samples, rather than sediment samples, the dates reflect the actual status of the water at those times: http://www.state.nj.us/drbc/regs/MONa.pdf Joe Gwinn |
#122
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ,
"Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: [snip] If you want, I'll post a link to the study. It's long and dull, but, hey, that's my life. d8-) Sure. Life has been too interesting. As in the ancient Chinese curse "may you live in interesting times". Which would be false advertising in this case, the part about interesting, but never mind. Ok, you asked for it. Here's a quick summary of what has happened in the Delaware Basin: http://www.wra.udel.edu/node/43 There also are some others that are specific to the municipal outflow problems, which used to be horrific, but this one will keep you busy. It's an interesting type of study: http://www.ceoe.udel.edu/CMS/tchurch/TMCWebPage/pdfweb131-160/151.pdf I lost the discussion and timeline about phosphates from Rutgers Univ. again, but I found the original data from which it was written. Take a look at the graph in Figure 3-6, page 16 of the PDF: http://www.state.nj.us/drbc/regs/MONa.pdf The total phosophus levels drepped from roughly 32 mu-M in 1969 to about 12 in 1975, and then to 4 by 1982. The dramatic fall in the early '70s corresponds with the elmination of detergent phosphates here at that time, when New York State outlawed it, NJ and PA threatened it, and the detergent makers pulled it out on their own because the market wouldn't support two versions (and we were being bombarded with PSAs to use non-phosphate detergents). If you want to see the discussion, I'll try to find it again. If you really get into the whole Delaware situation, here is an extremely detailed report. But I can't recommend it . It's 200 pages long: g http://www.wr.udel.edu/publications/DRBC/DRBCStateoftheBasinReport_07042008.pdf And as for dead rivers in Delaware and NJ, the claim is being made that these rivers were restored by the phosphate ban. Forgotten is all the cleanups of the chemical industry that happened at the same time. (I lived in NJ in the late 1950s, and do remember the smell of the chemical plants.) So which cleanup caused which good effect? Or, was it the aggregate of all the cleanups? What chemical industry are you talking about? The only chemical industry on the Delaware is around Philadelphia, just before it dumps into the bay. Huh? The big smell was close to NYC. I lived in the Philadelphia suburbs, and the smell wasn't so large. Or I was inured to it. Whatever. You're talking about the refineries and petrochemical plants around Elizabeth. They dump into the Newark Bay and Hudson estuary. That's the opposite side of the state from the Delaware, and there is no connection. The whole middle Delaware and much of the upper Delaware were dead when I was a kid. Completely dead. It was not the chemical industry. There wasn't any up there. Umm. I think deeper research is indicated here. Polluters need not be chemical industry, and NJ is and was heavily industrial. Mostly on the eastern side of the state, Joe. Again, that has nothing to do with the Delaware. And the issue with the Delaware has always been oxygen deplation from excessive nutrient loads, not from chemical toxicity. The chemical problems are on my side of the state, in the Passaic River, the Raritan River, Newark Bay and the Hudson estuary. National Lead damned near paved the bottom of the Raritan before it was shut down. Look at the bright side - you now can mine the riverbottom. You may be thinking of the Raritan or the Passaic Rivers. They both have serious chemical problems. In the case of the Raritan, a lot of it comes from the closed John's Manville and National Lead plants, plus two others that dumped heavy metals and paint chemicals. The Hudson's problem is PCBs. I don't know specifically what the Passaic's problem is. Doesn't this prove my point? Huh? You aren't following the issue, or you need to look more closely at the geography. The chemcial pollution problems we have on the Atlantic side of NJ are unrelated to the oxygen-depletion and eutrification issues in the Deleware. NJ is a small state, and Delaware is even smaller. Again, that report gave a pretty good analysis of before-and-after phosphate loads on the Delaware before and after the original ban, at numerous points along the river, so the evidence is not trivial. I'm not going to try to judge its veracity; I don't do chemistry. But the evidence does seem pretty clear. Well, I'd like to read the report. Have fun with the above. g I'd recommend a quick look at Figure 3-6 in this report first, which I also listed above. It dramatically shows what the phosphate history is. Because it's based on actual water samples, rather than sediment samples, the dates reflect the actual status of the water at those times: http://www.state.nj.us/drbc/regs/MONa.pdf Thanks for all the pointers. I'll rummage around a while. And the pinch of TSP in the dishwasher is working wonders. Joe Gwinn |
#123
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
On Jul 21, 9:15*pm, Joseph Gwinn wrote:
In article , *"Ed Huntress" wrote: Huh? You aren't following the issue, or you need to look more closely at the geography. The chemcial pollution problems we have on the Atlantic side of NJ are unrelated to the oxygen-depletion and eutrification issues in the Deleware. NJ is a small state, and Delaware is even smaller. * You're confusing the Delaware river with the state of Delaware. Most of the eastern side of NJ is bordered by the Atlantic ocean. Most of the western side of NJ is bordered by the Delaware river. The state of Delaware is actually south of NJ. http://en.wikipedia.org/wiki/Delaware_River HTH |
#124
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
"Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: [snip] If you want, I'll post a link to the study. It's long and dull, but, hey, that's my life. d8-) Sure. Life has been too interesting. As in the ancient Chinese curse "may you live in interesting times". Which would be false advertising in this case, the part about interesting, but never mind. Ok, you asked for it. Here's a quick summary of what has happened in the Delaware Basin: http://www.wra.udel.edu/node/43 There also are some others that are specific to the municipal outflow problems, which used to be horrific, but this one will keep you busy. It's an interesting type of study: http://www.ceoe.udel.edu/CMS/tchurch/TMCWebPage/pdfweb131-160/151.pdf I lost the discussion and timeline about phosphates from Rutgers Univ. again, but I found the original data from which it was written. Take a look at the graph in Figure 3-6, page 16 of the PDF: http://www.state.nj.us/drbc/regs/MONa.pdf The total phosophus levels drepped from roughly 32 mu-M in 1969 to about 12 in 1975, and then to 4 by 1982. The dramatic fall in the early '70s corresponds with the elmination of detergent phosphates here at that time, when New York State outlawed it, NJ and PA threatened it, and the detergent makers pulled it out on their own because the market wouldn't support two versions (and we were being bombarded with PSAs to use non-phosphate detergents). If you want to see the discussion, I'll try to find it again. If you really get into the whole Delaware situation, here is an extremely detailed report. But I can't recommend it . It's 200 pages long: g http://www.wr.udel.edu/publications/DRBC/DRBCStateoftheBasinReport_07042008.pdf And as for dead rivers in Delaware and NJ, the claim is being made that these rivers were restored by the phosphate ban. Forgotten is all the cleanups of the chemical industry that happened at the same time. (I lived in NJ in the late 1950s, and do remember the smell of the chemical plants.) So which cleanup caused which good effect? Or, was it the aggregate of all the cleanups? What chemical industry are you talking about? The only chemical industry on the Delaware is around Philadelphia, just before it dumps into the bay. Huh? The big smell was close to NYC. I lived in the Philadelphia suburbs, and the smell wasn't so large. Or I was inured to it. Whatever. You're talking about the refineries and petrochemical plants around Elizabeth. They dump into the Newark Bay and Hudson estuary. That's the opposite side of the state from the Delaware, and there is no connection. The whole middle Delaware and much of the upper Delaware were dead when I was a kid. Completely dead. It was not the chemical industry. There wasn't any up there. Umm. I think deeper research is indicated here. Polluters need not be chemical industry, and NJ is and was heavily industrial. Mostly on the eastern side of the state, Joe. Again, that has nothing to do with the Delaware. And the issue with the Delaware has always been oxygen deplation from excessive nutrient loads, not from chemical toxicity. The chemical problems are on my side of the state, in the Passaic River, the Raritan River, Newark Bay and the Hudson estuary. National Lead damned near paved the bottom of the Raritan before it was shut down. Look at the bright side - you now can mine the riverbottom. You may be thinking of the Raritan or the Passaic Rivers. They both have serious chemical problems. In the case of the Raritan, a lot of it comes from the closed John's Manville and National Lead plants, plus two others that dumped heavy metals and paint chemicals. The Hudson's problem is PCBs. I don't know specifically what the Passaic's problem is. Doesn't this prove my point? Huh? You aren't following the issue, or you need to look more closely at the geography. The chemcial pollution problems we have on the Atlantic side of NJ are unrelated to the oxygen-depletion and eutrification issues in the Deleware. NJ is a small state, and Delaware is even smaller. Again, that report gave a pretty good analysis of before-and-after phosphate loads on the Delaware before and after the original ban, at numerous points along the river, so the evidence is not trivial. I'm not going to try to judge its veracity; I don't do chemistry. But the evidence does seem pretty clear. Well, I'd like to read the report. Have fun with the above. g I'd recommend a quick look at Figure 3-6 in this report first, which I also listed above. It dramatically shows what the phosphate history is. Because it's based on actual water samples, rather than sediment samples, the dates reflect the actual status of the water at those times: http://www.state.nj.us/drbc/regs/MONa.pdf Thanks for all the pointers. I'll rummage around a while. And the pinch of TSP in the dishwasher is working wonders. I've tried it twice now since you recommended it. Since then, no smell. I'm going to hold up on the TSP unless and until I detect the odor again, and, if so, I'll try the TSP again. That should nail it down. You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the copmany that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. -- Ed Huntress Joe Gwinn |
#125
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ,
"Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: [snip] If you want, I'll post a link to the study. It's long and dull, but, hey, that's my life. d8-) Sure. Life has been too interesting. As in the ancient Chinese curse "may you live in interesting times". Which would be false advertising in this case, the part about interesting, but never mind. Ok, you asked for it. Here's a quick summary of what has happened in the Delaware Basin: http://www.wra.udel.edu/node/43 There also are some others that are specific to the municipal outflow problems, which used to be horrific, but this one will keep you busy. It's an interesting type of study: http://www.ceoe.udel.edu/CMS/tchurch/TMCWebPage/pdfweb131-160/151.pdf I lost the discussion and timeline about phosphates from Rutgers Univ. again, but I found the original data from which it was written. Take a look at the graph in Figure 3-6, page 16 of the PDF: http://www.state.nj.us/drbc/regs/MONa.pdf The total phosophus levels drepped from roughly 32 mu-M in 1969 to about 12 in 1975, and then to 4 by 1982. The dramatic fall in the early '70s corresponds with the elmination of detergent phosphates here at that time, when New York State outlawed it, NJ and PA threatened it, and the detergent makers pulled it out on their own because the market wouldn't support two versions (and we were being bombarded with PSAs to use non-phosphate detergents). If you want to see the discussion, I'll try to find it again. If you really get into the whole Delaware situation, here is an extremely detailed report. But I can't recommend it . It's 200 pages long: g http://www.wr.udel.edu/publications/...Report_0704200 8.pdf And as for dead rivers in Delaware and NJ, the claim is being made that these rivers were restored by the phosphate ban. Forgotten is all the cleanups of the chemical industry that happened at the same time. (I lived in NJ in the late 1950s, and do remember the smell of the chemical plants.) So which cleanup caused which good effect? Or, was it the aggregate of all the cleanups? What chemical industry are you talking about? The only chemical industry on the Delaware is around Philadelphia, just before it dumps into the bay. Huh? The big smell was close to NYC. I lived in the Philadelphia suburbs, and the smell wasn't so large. Or I was inured to it. Whatever. You're talking about the refineries and petrochemical plants around Elizabeth. They dump into the Newark Bay and Hudson estuary. That's the opposite side of the state from the Delaware, and there is no connection. The whole middle Delaware and much of the upper Delaware were dead when I was a kid. Completely dead. It was not the chemical industry. There wasn't any up there. Umm. I think deeper research is indicated here. Polluters need not be chemical industry, and NJ is and was heavily industrial. Mostly on the eastern side of the state, Joe. Again, that has nothing to do with the Delaware. And the issue with the Delaware has always been oxygen deplation from excessive nutrient loads, not from chemical toxicity. The chemical problems are on my side of the state, in the Passaic River, the Raritan River, Newark Bay and the Hudson estuary. National Lead damned near paved the bottom of the Raritan before it was shut down. Look at the bright side - you now can mine the riverbottom. You may be thinking of the Raritan or the Passaic Rivers. They both have serious chemical problems. In the case of the Raritan, a lot of it comes from the closed John's Manville and National Lead plants, plus two others that dumped heavy metals and paint chemicals. The Hudson's problem is PCBs. I don't know specifically what the Passaic's problem is. Doesn't this prove my point? Huh? You aren't following the issue, or you need to look more closely at the geography. The chemcial pollution problems we have on the Atlantic side of NJ are unrelated to the oxygen-depletion and eutrification issues in the Deleware. NJ is a small state, and Delaware is even smaller. Again, that report gave a pretty good analysis of before-and-after phosphate loads on the Delaware before and after the original ban, at numerous points along the river, so the evidence is not trivial. I'm not going to try to judge its veracity; I don't do chemistry. But the evidence does seem pretty clear. Well, I'd like to read the report. Have fun with the above. g I'd recommend a quick look at Figure 3-6 in this report first, which I also listed above. It dramatically shows what the phosphate history is. Because it's based on actual water samples, rather than sediment samples, the dates reflect the actual status of the water at those times: http://www.state.nj.us/drbc/regs/MONa.pdf Thanks for all the pointers. I'll rummage around a while. And the pinch of TSP in the dishwasher is working wonders. I've tried it twice now since you recommended it. Since then, no smell. I'm going to hold up on the TSP unless and until I detect the odor again, and, if so, I'll try the TSP again. That should nail it down. You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn |
#126
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
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#128
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
Where did you get TSP?
-- Christopher A. Young Learn more about Jesus www.lds.org .. "Joseph Gwinn" wrote in message ... Thanks for all the pointers. I'll rummage around a while. And the pinch of TSP in the dishwasher is working wonders. Joe Gwinn |
#129
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ,
"Stormin Mormon" wrote: Where did you get TSP? Best place is a paint store. I bought Savogran brand. Be sure you are getting Trisodium Phosphate. Be aware that "TSP" is not definite, and sodium silicate is sometimes sold as TSP. Sodium silicate will not work, and may etch glass. http://www.amazon.com/Savogran-10622...SP/dp/B000AXE7 CY Read the first review. Joe Gwinn |
#130
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
"J. Clarke" wrote in message in.local... In article , says... "Joseph Gwinn" wrote in message ... In article , "Stormin Mormon" wrote: Where did you get TSP? Best place is a paint store. I bought Savogran brand. Be sure you are getting Trisodium Phosphate. Be aware that "TSP" is not definite, and sodium silicate is sometimes sold as TSP. Sodium silicate will not work, and may etch glass. http://www.amazon.com/Savogran-10622...SP/dp/B000AXE7 CY Read the first review. Joe Gwinn Also, you often can't find out what you have from the package label. That's when it's time to check online for the MSDS. For example, the Savogran brand that Joe mentions, which I also bought last time, is 75% - 80% real TSP, which you can only learn from the MSDS. But I don't know if all Savogran products labeled "TSP" are the same. There are several. You need the product number, too, which you can get off of the box. Mine is 10621. I bought it at Home Depot, which is not as reliable as getting it from a paint store. The stuff I got at Home Despot says that it contains trisodium phosphate and sodium carbonate, and that it is 6 percent phosphorus. Pure TSP would be about 18 percent so it's mostly something else other than TSP. Note that you can get photographic grade TSP from B&H photo for $4.50/pound and shipping. That's good to know. The critical use I have for it is in a brush-type electrolytic rust/corrosion cleaning formula: http://metalworking.com/Dropbox/_199...es/E-CLEAN.TXT It's a multi-part formula and I don't know *how* critical it is, but it works great with the 75% - 80% Savogran. -- Ed Huntress |
#131
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ocal,
"J. Clarke" wrote: In article , says... "Joseph Gwinn" wrote in message ... In article , "Stormin Mormon" wrote: Where did you get TSP? Best place is a paint store. I bought Savogran brand. Be sure you are getting Trisodium Phosphate. Be aware that "TSP" is not definite, and sodium silicate is sometimes sold as TSP. Sodium silicate will not work, and may etch glass. http://www.amazon.com/Savogran-10622...SP/dp/B000AXE7 CY Read the first review. Joe Gwinn Also, you often can't find out what you have from the package label. That's when it's time to check online for the MSDS. For example, the Savogran brand that Joe mentions, which I also bought last time, is 75% - 80% real TSP, which you can only learn from the MSDS. But I don't know if all Savogran products labeled "TSP" are the same. There are several. You need the product number, too, which you can get off of the box. Mine is 10621. I bought it at Home Depot, which is not as reliable as getting it from a paint store. The stuff I got at Home Despot says that it contains trisodium phosphate and sodium carbonate, and that it is 6 percent phosphorus. Pure TSP would be about 18 percent so it's mostly something else other than TSP. Note that you can get photographic grade TSP from B&H photo for $4.50/pound and shipping. The Savogran TSP seems to work just fine, and is easy to get. I did look the MSDS up, and the other component is an anti-caking ingredient. I would not have thought of B&H Photo. What was used in detergents was Sodium Triphosphate, a related chemical: http://en.wikipedia.org/wiki/Sodium_triphosphate Joe Gwinn |
#132
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
You can also order it from www.mcmaster.com - put tsp in the search box,
about $4-5/lb depending on qty. ----- Regards, Carl Ijames "Ed Huntress" wrote in message ... "J. Clarke" wrote in message in.local... In article , says... "Joseph Gwinn" wrote in message ... In article , "Stormin Mormon" wrote: Where did you get TSP? Best place is a paint store. I bought Savogran brand. Be sure you are getting Trisodium Phosphate. Be aware that "TSP" is not definite, and sodium silicate is sometimes sold as TSP. Sodium silicate will not work, and may etch glass. http://www.amazon.com/Savogran-10622...SP/dp/B000AXE7 CY Read the first review. Joe Gwinn Also, you often can't find out what you have from the package label. That's when it's time to check online for the MSDS. For example, the Savogran brand that Joe mentions, which I also bought last time, is 75% - 80% real TSP, which you can only learn from the MSDS. But I don't know if all Savogran products labeled "TSP" are the same. There are several. You need the product number, too, which you can get off of the box. Mine is 10621. I bought it at Home Depot, which is not as reliable as getting it from a paint store. The stuff I got at Home Despot says that it contains trisodium phosphate and sodium carbonate, and that it is 6 percent phosphorus. Pure TSP would be about 18 percent so it's mostly something else other than TSP. Note that you can get photographic grade TSP from B&H photo for $4.50/pound and shipping. That's good to know. The critical use I have for it is in a brush-type electrolytic rust/corrosion cleaning formula: http://metalworking.com/Dropbox/_199...es/E-CLEAN.TXT It's a multi-part formula and I don't know *how* critical it is, but it works great with the 75% - 80% Savogran. -- Ed Huntress |
#133
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ,
says... In article ocal, "J. Clarke" wrote: In article , says... "Joseph Gwinn" wrote in message ... In article , "Stormin Mormon" wrote: Where did you get TSP? Best place is a paint store. I bought Savogran brand. Be sure you are getting Trisodium Phosphate. Be aware that "TSP" is not definite, and sodium silicate is sometimes sold as TSP. Sodium silicate will not work, and may etch glass. http://www.amazon.com/Savogran-10622...SP/dp/B000AXE7 CY Read the first review. Joe Gwinn Also, you often can't find out what you have from the package label. That's when it's time to check online for the MSDS. For example, the Savogran brand that Joe mentions, which I also bought last time, is 75% - 80% real TSP, which you can only learn from the MSDS. But I don't know if all Savogran products labeled "TSP" are the same. There are several. You need the product number, too, which you can get off of the box. Mine is 10621. I bought it at Home Depot, which is not as reliable as getting it from a paint store. The stuff I got at Home Despot says that it contains trisodium phosphate and sodium carbonate, and that it is 6 percent phosphorus. Pure TSP would be about 18 percent so it's mostly something else other than TSP. Note that you can get photographic grade TSP from B&H photo for $4.50/pound and shipping. The Savogran TSP seems to work just fine, and is easy to get. I did look the MSDS up, and the other component is an anti-caking ingredient. I would not have thought of B&H Photo. What was used in detergents was Sodium Triphosphate, a related chemical: http://en.wikipedia.org/wiki/Sodium_triphosphate FWIW, I've got some of that on order and plan to give it a try when it arrives and see how it works. |
#134
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Dishwashing machines need phosphates
"Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: snip You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn Ok, I got the story from a guy who sat on legislative committee meetings while the state laws were being hashed out. It was an hour-long conversation, so I won't try to tell the whole thing, but the discussion did involve a lot about Pflueger cane fly rods and fishing for cutthroat trout in Montana, lake trout in Canada's N.W.T., oysters in the Raritan Bay, and so on. g Blame Washington State. And the EPA. It started with tightening of national point-source effluent standards from EPA. That's industrial and municipal waste discharges. Many states were able to meet them with old-style (alum flocculent) tertiary treatment, and new-style tertiary treatment (microbes), but Washington allowed the overbuilding of residences around the Spokane River, and the phosphates were filtering down through a porous geological cap, getting into drinking water, and overloading the sewage treatment. The stage beyond tertiary is a microfiltering screen process and it costs like hell. So it was a cost issue for the State of Washington -- and many others. The Washington legislators sat down with the industry association, the American Cleaning Institute (ACI) and told them how much cheaper it would be to just pull the phosphates out of dishwasher detergent (remember, this is a point-source regulation). That was in 2006. They wanted it done in two years. The industry said they couldn't do it that fast. They asked for 4-1/2 years. The legislators said Ok. The industry in Europe had tried non-phosphate dishwasher detergents back in the '90s, but they didn't work well and customers stayed away in droves. In 2006, they still didn't have a solution. By 2010, the whole industry did, and it worked very well. There are now 17 states that have blocked the manufacture and sale -- but not the use -- of phosphate dishwasher detergents. The ACI and its members, once they had a solution that works, supported the legislation in the other 16 states. I didn't ask him about the stink - time was short and I was more interested in his choices of fly rods for cutthroats g -- but that's where the change came from. -- Ed Huntress |
#135
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Dishwashing machines need phosphates
"Ed Huntress" wrote in message ... "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: snip You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn Ok, I got the story from a guy who sat on legislative committee meetings while the state laws were being hashed out. It was an hour-long conversation, so I won't try to tell the whole thing, but the discussion did involve a lot about Pflueger cane fly rods and fishing for cutthroat trout in Montana, lake trout in Canada's N.W.T., oysters in the Raritan Bay, and so on. g Blame Washington State. And the EPA. It started with tightening of national point-source effluent standards from EPA. That's industrial and municipal waste discharges. Many states were able to meet them with old-style (alum flocculent) tertiary treatment, and new-style tertiary treatment (microbes), but Washington allowed the overbuilding of residences around the Spokane River, and the phosphates were filtering down through a porous geological cap, getting into drinking water, and overloading the sewage treatment. The stage beyond tertiary is a microfiltering screen process and it costs like hell. So it was a cost issue for the State of Washington -- and many others. The Washington legislators sat down with the industry association, the American Cleaning Institute (ACI) and told them how much cheaper it would be to just pull the phosphates out of dishwasher detergent (remember, this is a point-source regulation). That was in 2006. They wanted it done in two years. The industry said they couldn't do it that fast. They asked for 4-1/2 years. The legislators said Ok. The industry in Europe had tried non-phosphate dishwasher detergents back in the '90s, but they didn't work well and customers stayed away in droves. In 2006, they still didn't have a solution. By 2010, the whole industry did, and it worked very well. There are now 17 states that have blocked the manufacture and sale -- but not the use -- of phosphate dishwasher detergents. The ACI and its members, once they had a solution that works, supported the legislation in the other 16 states. I didn't ask him about the stink - time was short and I was more interested in his choices of fly rods for cutthroats g -- but that's where the change came from. -- Ed Huntress Oh, one thing I didn't explain: Many, or most, of those newer houses near Spokane have septic systems, which is how the phosphate is getting into the aquifer. But the drinking water supplies municipal areas where they have municipal sewers. Some big engineering firm figured out the route. The ACI says that detergent phosphates, which now is mostly dishwasher detergent, can be up to 25% of the phosphate load from municipal point-source discharges. -- Ed Huntress |
#136
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Dishwashing machines need phosphates
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#137
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Dishwashing machines need phosphates
On Tue, 26 Jul 2011 16:39:05 -0400, wrote:
On Tue, 26 Jul 2011 19:11:03 +0000 (UTC), wrote: On Tue, 26 Jul 2011 14:38:36 -0400, "Ed Huntress" wrote: "Ed Huntress" wrote in message ... "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: snip You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn Ok, I got the story from a guy who sat on legislative committee meetings while the state laws were being hashed out. It was an hour-long conversation, so I won't try to tell the whole thing, but the discussion did involve a lot about Pflueger cane fly rods and fishing for cutthroat trout in Montana, lake trout in Canada's N.W.T., oysters in the Raritan Bay, and so on. g Blame Washington State. And the EPA. It started with tightening of national point-source effluent standards from EPA. That's industrial and municipal waste discharges. Many states were able to meet them with old-style (alum flocculent) tertiary treatment, and new-style tertiary treatment (microbes), but Washington allowed the overbuilding of residences around the Spokane River, and the phosphates were filtering down through a porous geological cap, getting into drinking water, and overloading the sewage treatment. The stage beyond tertiary is a microfiltering screen process and it costs like hell. So it was a cost issue for the State of Washington -- and many others. The Washington legislators sat down with the industry association, the American Cleaning Institute (ACI) and told them how much cheaper it would be to just pull the phosphates out of dishwasher detergent (remember, this is a point-source regulation). That was in 2006. They wanted it done in two years. The industry said they couldn't do it that fast. They asked for 4-1/2 years. The legislators said Ok. The industry in Europe had tried non-phosphate dishwasher detergents back in the '90s, but they didn't work well and customers stayed away in droves. In 2006, they still didn't have a solution. By 2010, the whole industry did, and it worked very well. There are now 17 states that have blocked the manufacture and sale -- but not the use -- of phosphate dishwasher detergents. The ACI and its members, once they had a solution that works, supported the legislation in the other 16 states. I didn't ask him about the stink - time was short and I was more interested in his choices of fly rods for cutthroats g -- but that's where the change came from. -- Ed Huntress Oh, one thing I didn't explain: Many, or most, of those newer houses near Spokane have septic systems, which is how the phosphate is getting into the aquifer. But the drinking water supplies municipal areas where they have municipal sewers. Some big engineering firm figured out the route. The ACI says that detergent phosphates, which now is mostly dishwasher detergent, can be up to 25% of the phosphate load from municipal point-source discharges. Greetings Ed, I live on an island in the Salish Sea (formerly Puget Sound) and used to live on one of the beaches. There were several houses on the beach that were originally only accessible by boat. These old houses had small septic systems. Many of them had drain fields that were back from the beach and the sea wall and were below mean high tide. Others had drain fields that were between the houses and the beach. Now most of these houses can be driven to and are occupied full time instead of just summers. And they have been remodeled into large homes. The septic systems are all grandfathered in. When walking down the beach at low tide you can smell some of the failing systems. And the beach in front of many homes has lots of extra sea weed. Especially the ones with failing drain fields. This sea weed crowds out some types of sea grasses that protect baby salmon when they come down the streams. So Island County really wants these septic systems to stop leaching nutrients into the water. Eric That's an easy fix. No weeping tiles. Holding tanks only - pumped on a regular basis and deliverd to municipal water treatment plants - and taxed accordingly. The problem is basically political. If allowed, the county would change the laws. There are many places where the liquid is pumped into a sewer system and the solids collected in septic tanks. This solution requires much smaller pipes and is way cheaper to install. Having just one holding tank that is pumped regularly would mean a huge tank or very frequent pumping. A better solution would be a sand filter mound system. Cheaper too over the long run. The county would like all new systems to be pressurised sand filter mound systems. But once again there is not the support of the citizens for this. And I'm one of 'em. I live far away from the water and have a standard gravity fed system. From the research I did before I installed the system a standard gravity fed system with the new infiltrator type drain field does not pose a pollution hazard at farther than a 100 foot radius. However, I don't know about the phosphate problem because I didn't look into it as I don't use detergents with phosphates. Phosphates may well leach out of infiltrator type systems and travel in ground water for miles. I just don't know, which is one of the reasons I avoid them. Eric |
#138
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Dishwashing machines need phosphates
In article ,
"Ed Huntress" wrote: "Ed Huntress" wrote in message ... "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: snip You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn Ok, I got the story from a guy who sat on legislative committee meetings while the state laws were being hashed out. It was an hour-long conversation, so I won't try to tell the whole thing, but the discussion did involve a lot about Pflueger cane fly rods and fishing for cutthroat trout in Montana, lake trout in Canada's N.W.T., oysters in the Raritan Bay, and so on. g It's the news reporter genes coming to the fore. Very interesting. Blame Washington State. And the EPA. It started with tightening of national point-source effluent standards from EPA. That's industrial and municipal waste discharges. We knew it! There had to be an EPA conspiracy! Many states were able to meet them with old-style (alum flocculent) tertiary treatment, and new-style tertiary treatment (microbes), but Washington allowed the overbuilding of residences around the Spokane River, and the phosphates were filtering down through a porous geological cap, getting into drinking water, and overloading the sewage treatment. The stage beyond tertiary is a microfiltering screen process and it costs like hell. So it was a cost issue for the State of Washington -- and many others. The Washington legislators sat down with the industry association, the American Cleaning Institute (ACI) and told them how much cheaper it would be to just pull the phosphates out of dishwasher detergent (remember, this is a point-source regulation). That was in 2006. They wanted it done in two years. The industry said they couldn't do it that fast. They asked for 4-1/2 years. The legislators said Ok. The industry in Europe had tried non-phosphate dishwasher detergents back in the '90s, but they didn't work well and customers stayed away in droves. In 2006, they still didn't have a solution. By 2010, the whole industry did, and it worked very well. There are now 17 states that have blocked the manufacture and sale -- but not the use -- of phosphate dishwasher detergents. The ACI and its members, once they had a solution that works, supported the legislation in the other 16 states. If there is a workable solution, where is it? The whole point of this thread is precisely that people are having one problem after another, starting with the stink and the cloudy dirty just-washed glassware. More to the point, what do they mean by a "solution that works"? There may be some dispute about the definition of "works". This deserves a follow-up question. There have always been very good dishwasher detergents for scientific glassware, but these detergents are expensive, about six times the cost per ounce of grocery-store detergents, although the cost per wash may be almost the same if the lab stuff is more concentrated. The traditional and biggest name is Alconox: http://www.alconox.com/static/section_top/gen_catalog.asp. Hmm, better check the MSDS. Aha! Its secret sauce is two phosphorus compounds that together comprise about half the total. I didn't ask him about the stink - time was short and I was more interested in his choices of fly rods for cutthroats g -- but that's where the change came from. -- Ed Huntress Oh, one thing I didn't explain: Many, or most, of those newer houses near Spokane have septic systems, which is how the phosphate is getting into the aquifer. But the drinking water supplies municipal areas where they have municipal sewers. Some big engineering firm figured out the route. The ACI says that detergent phosphates, which now is mostly dishwasher detergent, can be up to 25% of the phosphate load from municipal point-source discharges. Given that clothes washing detergent is now non-phosphate, I can believe that dishwasher detergent now competes only with the resident humans, who thus must account for 75% of the point-source load. Hmm. Maybe the 75% includes commercial establishments, chiefly restaurants and the like. They are still permitted to buy phosphate containing detergent. Anyway, this brings me to two questions. First, is the 25% reduction worthwhile? Second, how does the 100% compare with ongoing agricultural use? Joe Gwinn |
#139
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Dishwashing machines need phosphates
"Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Ed Huntress" wrote in message ... "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: snip You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn Ok, I got the story from a guy who sat on legislative committee meetings while the state laws were being hashed out. It was an hour-long conversation, so I won't try to tell the whole thing, but the discussion did involve a lot about Pflueger cane fly rods and fishing for cutthroat trout in Montana, lake trout in Canada's N.W.T., oysters in the Raritan Bay, and so on. g It's the news reporter genes coming to the fore. Very interesting. Blame Washington State. And the EPA. It started with tightening of national point-source effluent standards from EPA. That's industrial and municipal waste discharges. We knew it! There had to be an EPA conspiracy! I should add that the particular problem in the Spokane River was that baby salmon weren't surviving because of the eutrification and low oxygen levels. Many states were able to meet them with old-style (alum flocculent) tertiary treatment, and new-style tertiary treatment (microbes), but Washington allowed the overbuilding of residences around the Spokane River, and the phosphates were filtering down through a porous geological cap, getting into drinking water, and overloading the sewage treatment. The stage beyond tertiary is a microfiltering screen process and it costs like hell. So it was a cost issue for the State of Washington -- and many others. The Washington legislators sat down with the industry association, the American Cleaning Institute (ACI) and told them how much cheaper it would be to just pull the phosphates out of dishwasher detergent (remember, this is a point-source regulation). That was in 2006. They wanted it done in two years. The industry said they couldn't do it that fast. They asked for 4-1/2 years. The legislators said Ok. The industry in Europe had tried non-phosphate dishwasher detergents back in the '90s, but they didn't work well and customers stayed away in droves. In 2006, they still didn't have a solution. By 2010, the whole industry did, and it worked very well. There are now 17 states that have blocked the manufacture and sale -- but not the use -- of phosphate dishwasher detergents. The ACI and its members, once they had a solution that works, supported the legislation in the other 16 states. If there is a workable solution, where is it? The whole point of this thread is precisely that people are having one problem after another, starting with the stink and the cloudy dirty just-washed glassware. More to the point, what do they mean by a "solution that works"? There may be some dispute about the definition of "works". This deserves a follow-up question. ACI notes that there are some performance issues, which can be solved by observing these points: 1) Make sure your water temp is at least 120 F (mine is 140 at the dishwasher). 2) Don't use too much detergent. If you have an old dishwasher, about half as much as the cups will hold is about right. 3) If you have water spots, chances are your water is hard. The guy I talked to told me he'd just returned from Ireland, where the water is very hard and they have water softeners *built in* to the dishwashers. If you have accumulated cloudiness, you may need to do a periodic vinegar treatment. Here's how they describe it: http://www.cleaninginstitute.org/cle...detergent.aspx You may also be interested in this: http://www.cleaninginstitute.org/cle...e rgents.aspx There have always been very good dishwasher detergents for scientific glassware, but these detergents are expensive, about six times the cost per ounce of grocery-store detergents, although the cost per wash may be almost the same if the lab stuff is more concentrated. The traditional and biggest name is Alconox: http://www.alconox.com/static/section_top/gen_catalog.asp. Hmm, better check the MSDS. Aha! Its secret sauce is two phosphorus compounds that together comprise about half the total. Fortunately, there probably isn't enough used to cause any problems. Note that the ACI FAQ, I think, mentions that there are not laws against *using* the stuff. The laws mostly regulate retail sale. My contact guy said that all big detergent manufacturers took phosphates out, but there may be some local ones in the states that don't regulate it, selling to the local market. I didn't ask him about the stink - time was short and I was more interested in his choices of fly rods for cutthroats g -- but that's where the change came from. -- Ed Huntress Oh, one thing I didn't explain: Many, or most, of those newer houses near Spokane have septic systems, which is how the phosphate is getting into the aquifer. But the drinking water supplies municipal areas where they have municipal sewers. Some big engineering firm figured out the route. The ACI says that detergent phosphates, which now is mostly dishwasher detergent, can be up to 25% of the phosphate load from municipal point-source discharges. Given that clothes washing detergent is now non-phosphate, I can believe that dishwasher detergent now competes only with the resident humans, who thus must account for 75% of the point-source load. Hmm. Maybe the 75% includes commercial establishments, chiefly restaurants and the like. They are still permitted to buy phosphate containing detergent. Anyway, this brings me to two questions. First, is the 25% reduction worthwhile? Second, how does the 100% compare with ongoing agricultural use? Nationwide, the ag use is by far the dominant source of phosphorus in rivers and streams. In heavily built-up areas, like around my beloved Delaware, residential cleaning use is the dominant source, with the Delaware apparently being an extreme, but not actually an outlying, example. My contact guy is an exec. with ACI in charge of this subject there, with over 20 years of industry experience. I think that further questions would have to be directed to the EPA. I know that there is some detailed research available that they used in their analysis. I just don't know what it is. And, without a paying article to write about it, my work is done here. d8-) It is quite interesting. Having followed water pollution issues in my area, I always find it interesting, because the real research so often refutes the conventional wisdom. And it's a consequential subject. Which reminds me that it's time to get out my son's microscope and do a species count of plankton in a local pond again. When he was in middle school, he did a science project that was based on some scientific data that ranks water quality on the basis of relative species counts. Local water-quality officials were very interested. Too few paramecia and too many cyclops, and you have trouble. g -- Ed Huntress Joe Gwinn |
#140
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Dishwashing machines need phosphates
On Jul 27, 11:28*am, "Ed Huntress" wrote:
ACI notes that there are some performance issues, which can be solved by observing these points: 1) Make sure your water temp is at least 120 F (mine is 140 at the dishwasher). 2) Don't use too much detergent. If you have an old dishwasher, about half as much as the cups will hold is about right. 3) If you have water spots, chances are your water is hard. The guy I talked to told me he'd just returned from Ireland, where the water is very hard and they have water softeners *built in* to the dishwashers. Coming into this a little late, but... I use "Cascade Complete" liquid, which is phosphate free (and ridiculously expensive). I use the "extra heat" setting on my dishwasher, which preheats the water. My dishes (and glasses) are very clean. |
#141
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Dishwashing machines need phosphates
In article ,
"Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Ed Huntress" wrote in message ... "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: snip You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn Ok, I got the story from a guy who sat on legislative committee meetings while the state laws were being hashed out. It was an hour-long conversation, so I won't try to tell the whole thing, but the discussion did involve a lot about Pflueger cane fly rods and fishing for cutthroat trout in Montana, lake trout in Canada's N.W.T., oysters in the Raritan Bay, and so on. g It's the news reporter genes coming to the fore. Very interesting. Blame Washington State. And the EPA. It started with tightening of national point-source effluent standards from EPA. That's industrial and municipal waste discharges. We knew it! There had to be an EPA conspiracy! I should add that the particular problem in the Spokane River was that baby salmon weren't surviving because of the eutrification and low oxygen levels. Was this due to dishwashers, or farmers? Many states were able to meet them with old-style (alum flocculent) tertiary treatment, and new-style tertiary treatment (microbes), but Washington allowed the overbuilding of residences around the Spokane River, and the phosphates were filtering down through a porous geological cap, getting into drinking water, and overloading the sewage treatment. The stage beyond tertiary is a microfiltering screen process and it costs like hell. So it was a cost issue for the State of Washington -- and many others. The Washington legislators sat down with the industry association, the American Cleaning Institute (ACI) and told them how much cheaper it would be to just pull the phosphates out of dishwasher detergent (remember, this is a point-source regulation). That was in 2006. They wanted it done in two years. The industry said they couldn't do it that fast. They asked for 4-1/2 years. The legislators said Ok. The industry in Europe had tried non-phosphate dishwasher detergents back in the '90s, but they didn't work well and customers stayed away in droves. In 2006, they still didn't have a solution. By 2010, the whole industry did, and it worked very well. There are now 17 states that have blocked the manufacture and sale -- but not the use -- of phosphate dishwasher detergents. The ACI and its members, once they had a solution that works, supported the legislation in the other 16 states. If there is a workable solution, where is it? The whole point of this thread is precisely that people are having one problem after another, starting with the stink and the cloudy dirty just-washed glassware. More to the point, what do they mean by a "solution that works"? There may be some dispute about the definition of "works". This deserves a follow-up question. ACI notes that there are some performance issues, which can be solved by observing these points: 1) Make sure your water temp is at least 120 F (mine is 140 at the dishwasher). 2) Don't use too much detergent. If you have an old dishwasher, about half as much as the cups will hold is about right. 3) If you have water spots, chances are your water is hard. The guy I talked to told me he'd just returned from Ireland, where the water is very hard and they have water softeners *built in* to the dishwashers. If you have accumulated cloudiness, you may need to do a periodic vinegar treatment. Here's how they describe it: http://www.cleaninginstitute.org/clean_living/faqs_phosphate_and_dishwasher_detergent.aspx You may also be interested in this: http://www.cleaninginstitute.org/clean_living/cm_novdec2010_changes_in_automatic_dishwasher_dete rgents.aspx More weekend reading. All of the above ACI advice was mentioned on the various blogs I read when researching the stink problem, although I don't recall that people knew where the advice came from. I did all of those things, including the vinegar, to little avail. The built-in water softener makes sense. The big variable in reports of trouble in the US is how hard the local water is, and a major purpose of the phosphate was precisely to handle hard water. But I wonder what chemicals are used in the built-in softeners. There have always been very good dishwasher detergents for scientific glassware, but these detergents are expensive, about six times the cost per ounce of grocery-store detergents, although the cost per wash may be almost the same if the lab stuff is more concentrated. The traditional and biggest name is Alconox: http://www.alconox.com/static/section_top/gen_catalog.asp. Hmm, better check the MSDS. Aha! Its secret sauce is two phosphorus compounds that together comprise about half the total. Fortunately, there probably isn't enough used to cause any problems. Note that the ACI FAQ, I think, mentions that there are not laws against *using* the stuff. The laws mostly regulate retail sale. My contact guy said that all big detergent manufacturers took phosphates out, but there may be some local ones in the states that don't regulate it, selling to the local market. Most likely because there are far more users than sellers, so policing sellers is easier. I didn't ask him about the stink - time was short and I was more interested in his choices of fly rods for cutthroats g -- but that's where the change came from. -- Ed Huntress Oh, one thing I didn't explain: Many, or most, of those newer houses near Spokane have septic systems, which is how the phosphate is getting into the aquifer. But the drinking water supplies municipal areas where they have municipal sewers. Some big engineering firm figured out the route. The ACI says that detergent phosphates, which now is mostly dishwasher detergent, can be up to 25% of the phosphate load from municipal point-source discharges. Given that clothes washing detergent is now non-phosphate, I can believe that dishwasher detergent now competes only with the resident humans, who thus must account for 75% of the point-source load. Hmm. Maybe the 75% includes commercial establishments, chiefly restaurants and the like. They are still permitted to buy phosphate containing detergent. Anyway, this brings me to two questions. First, is the 25% reduction worthwhile? Second, how does the 100% compare with ongoing agricultural use? Nationwide, the ag use is by far the dominant source of phosphorus in rivers and streams. In heavily built-up areas, like around my beloved Delaware, residential cleaning use is the dominant source, with the Delaware apparently being an extreme, but not actually an outlying, example. My contact guy is an exec. with ACI in charge of this subject there, with over 20 years of industry experience. I think that further questions would have to be directed to the EPA. I know that there is some detailed research available that they used in their analysis. I just don't know what it is. And, without a paying article to write about it, my work is done here. d8-) It is quite interesting. Having followed water pollution issues in my area, I always find it interesting, because the real research so often refutes the conventional wisdom. And it's a consequential subject. And we were trying to give meaning to your life, a focus, something to aspire to. Which reminds me that it's time to get out my son's microscope and do a species count of plankton in a local pond again. When he was in middle school, he did a science project that was based on some scientific data that ranks water quality on the basis of relative species counts. Local water-quality officials were very interested. Too few paramecia and too many cyclops, and you have trouble. g Think globally, act locally? But the trend would be interesting. Joe Gwinn |
#142
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
"Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Ed Huntress" wrote in message ... "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: snip You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn Ok, I got the story from a guy who sat on legislative committee meetings while the state laws were being hashed out. It was an hour-long conversation, so I won't try to tell the whole thing, but the discussion did involve a lot about Pflueger cane fly rods and fishing for cutthroat trout in Montana, lake trout in Canada's N.W.T., oysters in the Raritan Bay, and so on. g It's the news reporter genes coming to the fore. Very interesting. Blame Washington State. And the EPA. It started with tightening of national point-source effluent standards from EPA. That's industrial and municipal waste discharges. We knew it! There had to be an EPA conspiracy! I should add that the particular problem in the Spokane River was that baby salmon weren't surviving because of the eutrification and low oxygen levels. Was this due to dishwashers, or farmers? I'll leave that for your research to uncover. Remember, nationwide figures don't tell you much about individual rivers, as I've learned through this exercise. Many states were able to meet them with old-style (alum flocculent) tertiary treatment, and new-style tertiary treatment (microbes), but Washington allowed the overbuilding of residences around the Spokane River, and the phosphates were filtering down through a porous geological cap, getting into drinking water, and overloading the sewage treatment. The stage beyond tertiary is a microfiltering screen process and it costs like hell. So it was a cost issue for the State of Washington -- and many others. The Washington legislators sat down with the industry association, the American Cleaning Institute (ACI) and told them how much cheaper it would be to just pull the phosphates out of dishwasher detergent (remember, this is a point-source regulation). That was in 2006. They wanted it done in two years. The industry said they couldn't do it that fast. They asked for 4-1/2 years. The legislators said Ok. The industry in Europe had tried non-phosphate dishwasher detergents back in the '90s, but they didn't work well and customers stayed away in droves. In 2006, they still didn't have a solution. By 2010, the whole industry did, and it worked very well. There are now 17 states that have blocked the manufacture and sale -- but not the use -- of phosphate dishwasher detergents. The ACI and its members, once they had a solution that works, supported the legislation in the other 16 states. If there is a workable solution, where is it? The whole point of this thread is precisely that people are having one problem after another, starting with the stink and the cloudy dirty just-washed glassware. More to the point, what do they mean by a "solution that works"? There may be some dispute about the definition of "works". This deserves a follow-up question. ACI notes that there are some performance issues, which can be solved by observing these points: 1) Make sure your water temp is at least 120 F (mine is 140 at the dishwasher). 2) Don't use too much detergent. If you have an old dishwasher, about half as much as the cups will hold is about right. 3) If you have water spots, chances are your water is hard. The guy I talked to told me he'd just returned from Ireland, where the water is very hard and they have water softeners *built in* to the dishwashers. If you have accumulated cloudiness, you may need to do a periodic vinegar treatment. Here's how they describe it: http://www.cleaninginstitute.org/clean_living/faqs_phosphate_and_dishwasher_detergent.aspx You may also be interested in this: http://www.cleaninginstitute.org/clean_living/cm_novdec2010_changes_in_automatic_dishwasher_dete rgents.aspx More weekend reading. Those are short. All of the above ACI advice was mentioned on the various blogs I read when researching the stink problem, although I don't recall that people knew where the advice came from. I did all of those things, including the vinegar, to little avail. The built-in water softener makes sense. The big variable in reports of trouble in the US is how hard the local water is, and a major purpose of the phosphate was precisely to handle hard water. But I wonder what chemicals are used in the built-in softeners. My contact said "salt," so I assume it's similar to the water softeners we have here. There have always been very good dishwasher detergents for scientific glassware, but these detergents are expensive, about six times the cost per ounce of grocery-store detergents, although the cost per wash may be almost the same if the lab stuff is more concentrated. The traditional and biggest name is Alconox: http://www.alconox.com/static/section_top/gen_catalog.asp. Hmm, better check the MSDS. Aha! Its secret sauce is two phosphorus compounds that together comprise about half the total. Fortunately, there probably isn't enough used to cause any problems. Note that the ACI FAQ, I think, mentions that there are not laws against *using* the stuff. The laws mostly regulate retail sale. My contact guy said that all big detergent manufacturers took phosphates out, but there may be some local ones in the states that don't regulate it, selling to the local market. Most likely because there are far more users than sellers, so policing sellers is easier. Well, that, and that is the way that many such regulations are handled. You go for the source and you don't want to stick consumers with the problem of what to do with what they already have. Retailers had plenty of time to clear their inventory. Keep in mind, too, that many environmental regulations are based on percentages, and there are loopholes all over the place for people who need to use something that is banned, with the recognition that a few motivated and determined users of most troublesome chemicals are not the problem. It's the mass markets that are the problem. I didn't ask him about the stink - time was short and I was more interested in his choices of fly rods for cutthroats g -- but that's where the change came from. -- Ed Huntress Oh, one thing I didn't explain: Many, or most, of those newer houses near Spokane have septic systems, which is how the phosphate is getting into the aquifer. But the drinking water supplies municipal areas where they have municipal sewers. Some big engineering firm figured out the route. The ACI says that detergent phosphates, which now is mostly dishwasher detergent, can be up to 25% of the phosphate load from municipal point-source discharges. Given that clothes washing detergent is now non-phosphate, I can believe that dishwasher detergent now competes only with the resident humans, who thus must account for 75% of the point-source load. Hmm. Maybe the 75% includes commercial establishments, chiefly restaurants and the like. They are still permitted to buy phosphate containing detergent. Anyway, this brings me to two questions. First, is the 25% reduction worthwhile? Second, how does the 100% compare with ongoing agricultural use? Nationwide, the ag use is by far the dominant source of phosphorus in rivers and streams. In heavily built-up areas, like around my beloved Delaware, residential cleaning use is the dominant source, with the Delaware apparently being an extreme, but not actually an outlying, example. My contact guy is an exec. with ACI in charge of this subject there, with over 20 years of industry experience. I think that further questions would have to be directed to the EPA. I know that there is some detailed research available that they used in their analysis. I just don't know what it is. And, without a paying article to write about it, my work is done here. d8-) It is quite interesting. Having followed water pollution issues in my area, I always find it interesting, because the real research so often refutes the conventional wisdom. And it's a consequential subject. And we were trying to give meaning to your life, a focus, something to aspire to. Uh, it's more a habit of mind developed from several decades of research. I don't like not knowing things that are important to know. Which reminds me that it's time to get out my son's microscope and do a species count of plankton in a local pond again. When he was in middle school, he did a science project that was based on some scientific data that ranks water quality on the basis of relative species counts. Local water-quality officials were very interested. Too few paramecia and too many cyclops, and you have trouble. g Think globally, act locally? But the trend would be interesting. The relative plankton measures are an indirect way to measure overall water quality. It's quick and it corresponds well to some broad indexes -- particularly dissolved oxygen, but also some common toxins. You don't have to count organisms per unit volume of water, only their relative incidence. So sampling and preparation of samples is simple and cheap. It makes a great science project for a kid who's reached the stage where they can follow the connections. -- Ed Huntress Joe Gwinn |
#143
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ,
"Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: "Ed Huntress" wrote in message ... "Joseph Gwinn" wrote in message ... In article , "Ed Huntress" wrote: snip You got me going on this again. Darn you. g It was too hot to take my usual walk after lunch so I made some calls. First I called the company that makes Finish dishwasher detergent. They said they pulled the phosphate out on July 1, 2010, along with all of the other major producers. And the reason was, indeed, the 16 states who suddenly outlawed it, combined with the fact that they didn't want to make and market two different products. That's similar to what happened years ago with laundry detergent. The other call was to the NJ office of USGS, who monitors navigable waters here. The key researcher in this area is supposed to call me back; the one I talked to didn't know the issues with dishwasher detergent, or what the basis was for those states (which does not include NJ) to ban TSP. We'll see if I can get an answer. This could prove interesting. Joe Gwinn Ok, I got the story from a guy who sat on legislative committee meetings while the state laws were being hashed out. It was an hour-long conversation, so I won't try to tell the whole thing, but the discussion did involve a lot about Pflueger cane fly rods and fishing for cutthroat trout in Montana, lake trout in Canada's N.W.T., oysters in the Raritan Bay, and so on. g It's the news reporter genes coming to the fore. Very interesting. Blame Washington State. And the EPA. It started with tightening of national point-source effluent standards from EPA. That's industrial and municipal waste discharges. We knew it! There had to be an EPA conspiracy! I should add that the particular problem in the Spokane River was that baby salmon weren't surviving because of the eutrification and low oxygen levels. Was this due to dishwashers, or farmers? I'll leave that for your research to uncover. Remember, nationwide figures don't tell you much about individual rivers, as I've learned through this exercise. Well, based on what I have already found,that 95% goes into agriculture, I'm going with farmers. Many states were able to meet them with old-style (alum flocculent) tertiary treatment, and new-style tertiary treatment (microbes), but Washington allowed the overbuilding of residences around the Spokane River, and the phosphates were filtering down through a porous geological cap, getting into drinking water, and overloading the sewage treatment. The stage beyond tertiary is a microfiltering screen process and it costs like hell. So it was a cost issue for the State of Washington -- and many others. The Washington legislators sat down with the industry association, the American Cleaning Institute (ACI) and told them how much cheaper it would be to just pull the phosphates out of dishwasher detergent (remember, this is a point-source regulation). That was in 2006. They wanted it done in two years. The industry said they couldn't do it that fast. They asked for 4-1/2 years. The legislators said Ok. The industry in Europe had tried non-phosphate dishwasher detergents back in the '90s, but they didn't work well and customers stayed away in droves. In 2006, they still didn't have a solution. By 2010, the whole industry did, and it worked very well. There are now 17 states that have blocked the manufacture and sale -- but not the use -- of phosphate dishwasher detergents. The ACI and its members, once they had a solution that works, supported the legislation in the other 16 states. If there is a workable solution, where is it? The whole point of this thread is precisely that people are having one problem after another, starting with the stink and the cloudy dirty just-washed glassware. More to the point, what do they mean by a "solution that works"? There may be some dispute about the definition of "works". This deserves a follow-up question. ACI notes that there are some performance issues, which can be solved by observing these points: 1) Make sure your water temp is at least 120 F (mine is 140 at the dishwasher). 2) Don't use too much detergent. If you have an old dishwasher, about half as much as the cups will hold is about right. 3) If you have water spots, chances are your water is hard. The guy I talked to told me he'd just returned from Ireland, where the water is very hard and they have water softeners *built in* to the dishwashers. If you have accumulated cloudiness, you may need to do a periodic vinegar treatment. Here's how they describe it: http://www.cleaninginstitute.org/cle..._and_dishwashe r_detergent.aspx You may also be interested in this: http://www.cleaninginstitute.org/cle...changes_in_aut omatic_dishwasher_detergents.aspx More weekend reading. Those are short. But not sweet. All of the above ACI advice was mentioned on the various blogs I read when researching the stink problem, although I don't recall that people knew where the advice came from. I did all of those things, including the vinegar, to little avail. The built-in water softener makes sense. The big variable in reports of trouble in the US is how hard the local water is, and a major purpose of the phosphate was precisely to handle hard water. But I wonder what chemicals are used in the built-in softeners. My contact said "salt," so I assume it's similar to the water softeners we have here. Salt is certainly plausible. But the ion exchange process cannot destroy calcium and magnesium, so these are going into the effluent. But it may not matter. There have always been very good dishwasher detergents for scientific glassware, but these detergents are expensive, about six times the cost per ounce of grocery-store detergents, although the cost per wash may be almost the same if the lab stuff is more concentrated. The traditional and biggest name is Alconox: http://www.alconox.com/static/section_top/gen_catalog.asp. Hmm, better check the MSDS. Aha! Its secret sauce is two phosphorus compounds that together comprise about half the total. Fortunately, there probably isn't enough used to cause any problems. Note that the ACI FAQ, I think, mentions that there are not laws against *using* the stuff. The laws mostly regulate retail sale. My contact guy said that all big detergent manufacturers took phosphates out, but there may be some local ones in the states that don't regulate it, selling to the local market. Most likely because there are far more users than sellers, so policing sellers is easier. Well, that, and that is the way that many such regulations are handled. You go for the source and you don't want to stick consumers with the problem of what to do with what they already have. Retailers had plenty of time to clear their inventory. Keep in mind, too, that many environmental regulations are based on percentages, and there are loopholes all over the place for people who need to use something that is banned, with the recognition that a few motivated and determined users of most troublesome chemicals are not the problem. It's the mass markets that are the problem. But isn't this the key question? In other words, why chase 0.5%? I didn't ask him about the stink - time was short and I was more interested in his choices of fly rods for cutthroats g -- but that's where the change came from. -- Ed Huntress Oh, one thing I didn't explain: Many, or most, of those newer houses near Spokane have septic systems, which is how the phosphate is getting into the aquifer. But the drinking water supplies municipal areas where they have municipal sewers. Some big engineering firm figured out the route. The ACI says that detergent phosphates, which now is mostly dishwasher detergent, can be up to 25% of the phosphate load from municipal point-source discharges. Given that clothes washing detergent is now non-phosphate, I can believe that dishwasher detergent now competes only with the resident humans, who thus must account for 75% of the point-source load. Hmm. Maybe the 75% includes commercial establishments, chiefly restaurants and the like. They are still permitted to buy phosphate containing detergent. Anyway, this brings me to two questions. First, is the 25% reduction worthwhile? Second, how does the 100% compare with ongoing agricultural use? Nationwide, the ag use is by far the dominant source of phosphorus in rivers and streams. In heavily built-up areas, like around my beloved Delaware, residential cleaning use is the dominant source, with the Delaware apparently being an extreme, but not actually an outlying, example. My contact guy is an exec. with ACI in charge of this subject there, with over 20 years of industry experience. I think that further questions would have to be directed to the EPA. I know that there is some detailed research available that they used in their analysis. I just don't know what it is. And, without a paying article to write about it, my work is done here. d8-) It is quite interesting. Having followed water pollution issues in my area, I always find it interesting, because the real research so often refutes the conventional wisdom. And it's a consequential subject. And we were trying to give meaning to your life, a focus, something to aspire to. Uh, it's more a habit of mind developed from several decades of research. I don't like not knowing things that are important to know. We're here to help... Which reminds me that it's time to get out my son's microscope and do a species count of plankton in a local pond again. When he was in middle school, he did a science project that was based on some scientific data that ranks water quality on the basis of relative species counts. Local water-quality officials were very interested. Too few paramecia and too many cyclops, and you have trouble. g Think globally, act locally? But the trend would be interesting. The relative plankton measures are an indirect way to measure overall water quality. It's quick and it corresponds well to some broad indexes -- particularly dissolved oxygen, but also some common toxins. You don't have to count organisms per unit volume of water, only their relative incidence. So sampling and preparation of samples is simple and cheap. It makes a great science project for a kid who's reached the stage where they can follow the connections. I don't know how it works with paramecia and cyclops, but a big discovery in the last decade or two is that ocean bacteria are largely limited by bacteriophages, which are viruses that infect bacteria. If it were not for the phages, the bacteria would cover the Earth with goo. Joe Gwinn |
#144
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
On Thu, 28 Jul 2011 22:40:03 -0400, Joseph Gwinn
wrote: In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... ...... Was this due to dishwashers, or farmers? I'll leave that for your research to uncover. Remember, nationwide figures don't tell you much about individual rivers, as I've learned through this exercise. Well, based on what I have already found,that 95% goes into agriculture, I'm going with farmers. But this says little about how much P gets into water bodies. Virtually all the P in detergents leaves the point of use via wastewater. The farmers' interest lies in maximizing uptake of P by plants and minimizing loss by leaching or erosion. ......... Keep in mind, too, that many environmental regulations are based on percentages, and there are loopholes all over the place for people who need to use something that is banned, with the recognition that a few motivated and determined users of most troublesome chemicals are not the problem. It's the mass markets that are the problem. But isn't this the key question? In other words, why chase 0.5%? Where's this .5% come from? BTW, we found the new Cascade formulas lacking, but a generic brand (Home 360?) from the local Hannaford works fine. -- Ned Simmons |
#145
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ,
Ned Simmons wrote: On Thu, 28 Jul 2011 22:40:03 -0400, Joseph Gwinn wrote: In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... ..... Was this due to dishwashers, or farmers? I'll leave that for your research to uncover. Remember, nationwide figures don't tell you much about individual rivers, as I've learned through this exercise. Well, based on what I have already found,that 95% goes into agriculture, I'm going with farmers. But this says little about how much P gets into water bodies. Virtually all the P in detergents leaves the point of use via wastewater. The farmers' interest lies in maximizing uptake of P by plants and minimizing loss by leaching or erosion. All true, but farmers use tons of fertilizer, while homes use pounds of detergent. Keep in mind, too, that many environmental regulations are based on percentages, and there are loopholes all over the place for people who need to use something that is banned, with the recognition that a few motivated and determined users of most troublesome chemicals are not the problem. It's the mass markets that are the problem. But isn't this the key question? In other words, why chase 0.5%? Where's this 0.5% come from? You might wish to read the beginning of the thread. It's all there. BTW, we found the new Cascade formulas lacking, but a generic brand (Home 360?) from the local Hannaford works fine. Hmm. There is a Hannaford nearby. What I've been using is plain old Cascade plus a pinch of TSP, and this does work. Joe Gwinn |
#146
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
On Fri, 29 Jul 2011 10:22:42 -0400
Joseph Gwinn wrote: snip What I've been using is plain old Cascade plus a pinch of TSP, and this does work. Maybe you already found this (shrug), but... http://www.amazon.com/Cascade-Automa...1967952&sr=8-1 or http://www.restockit.com/cascade-aut...(34953pg).html We have a walk-in/open to the public restaurant supplier in town that claims to have it in stock. Thought it may give you some ideas to ponder... -- Leon Fisk Grand Rapids MI/Zone 5b Remove no.spam for email |
#147
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
On Fri, 29 Jul 2011 10:22:42 -0400, Joseph Gwinn
wrote: In article , Ned Simmons wrote: On Thu, 28 Jul 2011 22:40:03 -0400, Joseph Gwinn wrote: In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... ..... Was this due to dishwashers, or farmers? I'll leave that for your research to uncover. Remember, nationwide figures don't tell you much about individual rivers, as I've learned through this exercise. Well, based on what I have already found,that 95% goes into agriculture, I'm going with farmers. But this says little about how much P gets into water bodies. Virtually all the P in detergents leaves the point of use via wastewater. The farmers' interest lies in maximizing uptake of P by plants and minimizing loss by leaching or erosion. All true, but farmers use tons of fertilizer, while homes use pounds of detergent. Keep in mind, too, that many environmental regulations are based on percentages, and there are loopholes all over the place for people who need to use something that is banned, with the recognition that a few motivated and determined users of most troublesome chemicals are not the problem. It's the mass markets that are the problem. But isn't this the key question? In other words, why chase 0.5%? Where's this 0.5% come from? You might wish to read the beginning of the thread. It's all there. BTW, we found the new Cascade formulas lacking, but a generic brand (Home 360?) from the local Hannaford works fine. Hmm. There is a Hannaford nearby. What I've been using is plain old Cascade plus a pinch of TSP, and this does work. Joe Gwinn How big a "pinch"? I am adding about a teaspoon full - probably too much! Gerry :-)} London, Canada |
#148
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ,
Gerald Miller wrote: On Fri, 29 Jul 2011 10:22:42 -0400, Joseph Gwinn wrote: In article , Ned Simmons wrote: On Thu, 28 Jul 2011 22:40:03 -0400, Joseph Gwinn wrote: In article , "Ed Huntress" wrote: "Joseph Gwinn" wrote in message ... ..... Was this due to dishwashers, or farmers? I'll leave that for your research to uncover. Remember, nationwide figures don't tell you much about individual rivers, as I've learned through this exercise. Well, based on what I have already found,that 95% goes into agriculture, I'm going with farmers. But this says little about how much P gets into water bodies. Virtually all the P in detergents leaves the point of use via wastewater. The farmers' interest lies in maximizing uptake of P by plants and minimizing loss by leaching or erosion. All true, but farmers use tons of fertilizer, while homes use pounds of detergent. Keep in mind, too, that many environmental regulations are based on percentages, and there are loopholes all over the place for people who need to use something that is banned, with the recognition that a few motivated and determined users of most troublesome chemicals are not the problem. It's the mass markets that are the problem. But isn't this the key question? In other words, why chase 0.5%? Where's this 0.5% come from? You might wish to read the beginning of the thread. It's all there. BTW, we found the new Cascade formulas lacking, but a generic brand (Home 360?) from the local Hannaford works fine. Hmm. There is a Hannaford nearby. What I've been using is plain old Cascade plus a pinch of TSP, and this does work. Joe Gwinn How big a "pinch"? I am adding about a teaspoon full - probably too much! I think I'm using about 1/4 teaspoon, but how much is needed will depend on the local water, so experiment a bit. Joe Gwinn |
#149
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
In article ,
Leon Fisk wrote: On Fri, 29 Jul 2011 10:22:42 -0400 Joseph Gwinn wrote: snip What I've been using is plain old Cascade plus a pinch of TSP, and this does work. Maybe you already found this (shrug), but... http://www.amazon.com/Cascade-Automatic-Dishwasher-Detergent-Powdered/dp/B000BC19Y8/ref=sr_1_1?ie=UTF8&qid=1311967952&sr=8-1 or http://www.restockit.com/cascade-automatic-dishwasher-detergent-85-oz-(34953pg).html We have a walk-in/open to the public restaurant supplier in town that claims to have it in stock. Thought it may give you some ideas to ponder... Cascade with phosphate is available, but in large cartons. restockit.com seemed to be the main internet source. The Amazon stuff didn't actually say it contained phosphate. I recall a different carton, which has "with Phosphates" in bold letters, so I am unsure what these webpages are showing. I live in the Boston area, and I have to believe that there is a local restaurant supply house that has the real stuff over the counter. Joe Gwinn |
#150
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Dishwashing machines need phosphates
I am also curious to know.
-- Christopher A. Young Learn more about Jesus www.lds.org .. "Gerald Miller" wrote in message ... On Fri, 29 Jul 2011 10:22:42 -0400, Joseph Gwinn wrote: What I've been using is plain old Cascade plus a pinch of TSP, and this does work. Joe Gwinn How big a "pinch"? I am adding about a teaspoon full - probably too much! Gerry :-)} London, Canada |
#151
Posted to rec.crafts.metalworking
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Dishwashing machines need phosphates
Yes, that makes sense. Thanks, t hat's a good start point.
-- Christopher A. Young Learn more about Jesus www.lds.org .. "Joseph Gwinn" wrote in message ... How big a "pinch"? I am adding about a teaspoon full - probably too much! I think I'm using about 1/4 teaspoon, but how much is needed will depend on the local water, so experiment a bit. Joe Gwinn |
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