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Metalworking (rec.crafts.metalworking) Discuss various aspects of working with metal, such as machining, welding, metal joining, screwing, casting, hardening/tempering, blacksmithing/forging, spinning and hammer work, sheet metal work. |
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#1
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castting
I am research student I need any one interest in casting of copper base alloy or high copper alloy with chrome in different ratios (0.46 - 5)% chrome and copper base alloy with aluminum in different ratios (3 -9)% Al ,I need know how can cast of chrome in molten copper that has 1907 C temp whereas the copper 1085 C, can I add chrome to molten copper as powder? Did the chrome dissolved in molten copper.
then I will try to make solution treatment to these alloy for strengthening (quenching and aging) to ...then I will to compare between these alloy with mechanical properties, corrosion and wear resistance. Please if you any one can help me to achieved these requirements. Did the copper chrome alloy has more than properties from copper aluminum alloy with the ratios above Thank with my regards |
#2
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#3
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castting
On Wed, 19 Apr 2017 22:29:07 -0700, asaadka77 wrote:
I am research student I need any one interest in casting of copper base alloy or high copper alloy with chrome in different ratios (0.46 - 5)% chrome and copper base alloy with aluminum in different ratios (3 -9)% Al ,I need know how can cast of chrome in molten copper that has 1907 C temp whereas the copper 1085 C, can I add chrome to molten copper as powder? Did the chrome dissolved in molten copper. then I will try to make solution treatment to these alloy for strengthening (quenching and aging) to ...then I will to compare between these alloy with mechanical properties, corrosion and wear resistance. Please if you any one can help me to achieved these requirements. Did the copper chrome alloy has more than properties from copper aluminum alloy with the ratios above Thank with my regards Most of your questions I can't help you with, but the fact that you don't know if chromium is soluble in copper tells me that you haven't done your homework. A Really Short Web Search tells me that chromium-copper systems are pretty complex: apparently chromium isn't miscible in copper, so you have to work hard to get a nicely distributed suspension. This is NOT a question that you're likely to get answered on an amateur metalworking group (although there may be some enthusiast or retired metallurgist who knows, in which case I'll be interested in seeing the answer myself). I think you have some research papers to seek out and read. -- Tim Wescott Control systems, embedded software and circuit design I'm looking for work! See my website if you're interested http://www.wescottdesign.com |
#5
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castting
On 20/04/17 21:01, Tim Wescott wrote:
On Thu, 20 Apr 2017 17:33:33 +0100, David Billington wrote: On 20/04/17 06:29, wrote: I am research student I need any one interest in casting of copper base alloy or high copper alloy with chrome in different ratios (0.46 - 5)% chrome and copper base alloy with aluminum in different ratios (3 -9)% Al ,I need know how can cast of chrome in molten copper that has 1907 C temp whereas the copper 1085 C, can I add chrome to molten copper as powder? Did the chrome dissolved in molten copper. then I will try to make solution treatment to these alloy for strengthening (quenching and aging) to ...then I will to compare between these alloy with mechanical properties, corrosion and wear resistance. Please if you any one can help me to achieved these requirements. Did the copper chrome alloy has more than properties from copper aluminum alloy with the ratios above Thank with my regards You would need to know the solubility of chrome in copper to know how much you can add but modern pewter (Britannia metal) is made by melting tin and then adding the copper and stirring to dissolve the copper. Copper has a much higher melting temperature than tin but will readily dissolve up to a point. I did a bit of searching and based on the little bits I found it seems they're imiscible. I was hoping to find a master chart of the solubilities of all metals in all metals -- I was disappointed. I was reading recently about modern pewter (Britannia metal) and it's typically 92-6-2 for rolled sheet with slight variations depending on application. That's 92% tin, 6% antimony, and 2% copper. Apparently the antimony also helps keep the copper in suspension and evenly distributed as IIRC the copper would separate out and IIRC not much more copper will dissolve in tin anyway. I've not looked for information as you have about the copper chrome combination but maybe in a similar way another element addition might boost take-up, I think I'll leave that to the OP as I can't see I have any need for playing with a copper chrome alloy. |
#6
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castting
"Tim Wescott" wrote in message
... On Wed, 19 Apr 2017 22:29:07 -0700, asaadka77 wrote: I am research student I need any one interest in casting of copper base alloy or high copper alloy with chrome in different ratios (0.46 - 5)% chrome and copper base alloy with aluminum in different ratios (3 -9)% Al ,I need know how can cast of chrome in molten copper that has 1907 C temp whereas the copper 1085 C, can I add chrome to molten copper as powder? Did the chrome dissolved in molten copper. then I will try to make solution treatment to these alloy for strengthening (quenching and aging) to ...then I will to compare between these alloy with mechanical properties, corrosion and wear resistance. Please if you any one can help me to achieved these requirements. Did the copper chrome alloy has more than properties from copper aluminum alloy with the ratios above Thank with my regards Most of your questions I can't help you with, but the fact that you don't know if chromium is soluble in copper tells me that you haven't done your homework. A Really Short Web Search tells me that chromium-copper systems are pretty complex: apparently chromium isn't miscible in copper, so you have to work hard to get a nicely distributed suspension. This is NOT a question that you're likely to get answered on an amateur metalworking group (although there may be some enthusiast or retired metallurgist who knows, in which case I'll be interested in seeing the answer myself). I think you have some research papers to seek out and read. -- Tim Wescott Control systems, embedded software and circuit design I'm looking for work! See my website if you're interested http://www.wescottdesign.com Phase Diagram: https://www.andrew.cmu.edu/user/dl0p...in/pdf/039.pdf It shows how the solubility of chromium in molten copper increases with temperature. Eutectic: http://csmres.jmu.edu/geollab/Fichte...x/BinryEu.html -jsw |
#7
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castting
On Thursday, April 20, 2017 at 4:01:48 PM UTC-4, Tim Wescott wrote:
On Thu, 20 Apr 2017 17:33:33 +0100, David Billington wrote: On 20/04/17 06:29, wrote: I am research student I need any one interest in casting of copper base alloy or high copper alloy with chrome in different ratios (0.46 - 5)% chrome and copper base alloy with aluminum in different ratios (3 -9)% Al ,I need know how can cast of chrome in molten copper that has 1907 C temp whereas the copper 1085 C, can I add chrome to molten copper as powder? Did the chrome dissolved in molten copper. then I will try to make solution treatment to these alloy for strengthening (quenching and aging) to ...then I will to compare between these alloy with mechanical properties, corrosion and wear resistance. Please if you any one can help me to achieved these requirements. Did the copper chrome alloy has more than properties from copper aluminum alloy with the ratios above Thank with my regards You would need to know the solubility of chrome in copper to know how much you can add but modern pewter (Britannia metal) is made by melting tin and then adding the copper and stirring to dissolve the copper. Copper has a much higher melting temperature than tin but will readily dissolve up to a point. I did a bit of searching and based on the little bits I found it seems they're imiscible. I was hoping to find a master chart of the solubilities of all metals in all metals -- I was disappointed. -- Tim Wescott Control systems, embedded software and circuit design I'm looking for work! See my website if you're interested http://www.wescottdesign.com Copper and chromium are not miscable, but they are somewhat soluble, and there is a whole class of copper/chromium alloys: https://www.copper.org/resources/pro.../chrom_cu.html When the alloy is cooled, the chromium either goes into solid solution (fast quench) or it precipitates out (slow quench). The usefulness of the alloy depends upon further heat treatment, which allows a fine matrix of chromium to precipitate out of the alpha copper, resulting in a very strong, precipitation-hardened alloy. You probably can find more by looking up the individual Copper Assn. alloy numbers, which are listed in the article linked to above. Corrosion resistance of precipitation-hardened alloys typically is not very good, but I have no idea about this pair. As for the aluminum, I'd start with the big handbooks from the American Society for Metals. I can look it up but it's worthwhile for the OP to make himself familiar with the resources. This is pretty obscure stuff and you have to find your way around the basic references if you're going to get anywhere with complex and obscure questions such as these. -- Ed Huntress |
#8
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castting
wrote in message
... On Thursday, April 20, 2017 at 4:01:48 PM UTC-4, Tim Wescott wrote: On Thu, 20 Apr 2017 17:33:33 +0100, David Billington wrote: On 20/04/17 06:29, wrote: I am research student I need any one interest in casting of copper base alloy or high copper alloy with chrome in different ratios (0.46 - 5)% chrome and copper base alloy with aluminum in different ratios (3 -9)% Al ,I need know how can cast of chrome in molten copper that has 1907 C temp whereas the copper 1085 C, can I add chrome to molten copper as powder? Did the chrome dissolved in molten copper. then I will try to make solution treatment to these alloy for strengthening (quenching and aging) to ...then I will to compare between these alloy with mechanical properties, corrosion and wear resistance. Please if you any one can help me to achieved these requirements. Did the copper chrome alloy has more than properties from copper aluminum alloy with the ratios above Thank with my regards You would need to know the solubility of chrome in copper to know how much you can add but modern pewter (Britannia metal) is made by melting tin and then adding the copper and stirring to dissolve the copper. Copper has a much higher melting temperature than tin but will readily dissolve up to a point. I did a bit of searching and based on the little bits I found it seems they're imiscible. I was hoping to find a master chart of the solubilities of all metals in all metals -- I was disappointed. -- Tim Wescott Control systems, embedded software and circuit design I'm looking for work! See my website if you're interested http://www.wescottdesign.com Copper and chromium are not miscable, but they are somewhat soluble, and there is a whole class of copper/chromium alloys: https://www.copper.org/resources/pro.../chrom_cu.html When the alloy is cooled, the chromium either goes into solid solution (fast quench) or it precipitates out (slow quench). The usefulness of the alloy depends upon further heat treatment, which allows a fine matrix of chromium to precipitate out of the alpha copper, resulting in a very strong, precipitation-hardened alloy. You probably can find more by looking up the individual Copper Assn. alloy numbers, which are listed in the article linked to above. Corrosion resistance of precipitation-hardened alloys typically is not very good, but I have no idea about this pair. As for the aluminum, I'd start with the big handbooks from the American Society for Metals. I can look it up but it's worthwhile for the OP to make himself familiar with the resources. This is pretty obscure stuff and you have to find your way around the basic references if you're going to get anywhere with complex and obscure questions such as these. -- Ed Huntress ================ The copper-aluminum alloy is called a Bronze: https://en.wikipedia.org/wiki/Aluminium_bronze -jsw |
#9
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castting
On Thursday, April 20, 2017 at 4:35:22 PM UTC-4, Jim Wilkins wrote:
wrote in message ... On Thursday, April 20, 2017 at 4:01:48 PM UTC-4, Tim Wescott wrote: On Thu, 20 Apr 2017 17:33:33 +0100, David Billington wrote: On 20/04/17 06:29, wrote: I am research student I need any one interest in casting of copper base alloy or high copper alloy with chrome in different ratios (0.46 - 5)% chrome and copper base alloy with aluminum in different ratios (3 -9)% Al ,I need know how can cast of chrome in molten copper that has 1907 C temp whereas the copper 1085 C, can I add chrome to molten copper as powder? Did the chrome dissolved in molten copper. then I will try to make solution treatment to these alloy for strengthening (quenching and aging) to ...then I will to compare between these alloy with mechanical properties, corrosion and wear resistance. Please if you any one can help me to achieved these requirements. Did the copper chrome alloy has more than properties from copper aluminum alloy with the ratios above Thank with my regards You would need to know the solubility of chrome in copper to know how much you can add but modern pewter (Britannia metal) is made by melting tin and then adding the copper and stirring to dissolve the copper. Copper has a much higher melting temperature than tin but will readily dissolve up to a point. I did a bit of searching and based on the little bits I found it seems they're imiscible. I was hoping to find a master chart of the solubilities of all metals in all metals -- I was disappointed. -- Tim Wescott Control systems, embedded software and circuit design I'm looking for work! See my website if you're interested http://www.wescottdesign.com Copper and chromium are not miscable, but they are somewhat soluble, and there is a whole class of copper/chromium alloys: https://www.copper.org/resources/pro.../chrom_cu.html When the alloy is cooled, the chromium either goes into solid solution (fast quench) or it precipitates out (slow quench). The usefulness of the alloy depends upon further heat treatment, which allows a fine matrix of chromium to precipitate out of the alpha copper, resulting in a very strong, precipitation-hardened alloy. You probably can find more by looking up the individual Copper Assn. alloy numbers, which are listed in the article linked to above. Corrosion resistance of precipitation-hardened alloys typically is not very good, but I have no idea about this pair. As for the aluminum, I'd start with the big handbooks from the American Society for Metals. I can look it up but it's worthwhile for the OP to make himself familiar with the resources. This is pretty obscure stuff and you have to find your way around the basic references if you're going to get anywhere with complex and obscure questions such as these. -- Ed Huntress ================ The copper-aluminum alloy is called a Bronze: https://en.wikipedia.org/wiki/Aluminium_bronze -jsw I think he said chromium/copper/aluminum, but yeah, plain aluminum bronze is quite common -- and very strong. With the chromiun/copper, the question is whether he wants a solid solution or the precipitation-hardened version. The precipitation process is commonly called "aging," but I don't know if this alloy will age naturally, like 6061 aluminum. -- Ed Huntress |
#10
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castting
Thank Mr. David ...the solubility of chrome in copper about 1.5 %...I understand from your massage can I add chrome powder to copper....thank
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#11
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castting
Thank Mr. Tim Wescotti ....research and read more papers ...but some of problem in practice or some things can not be includedcan in papers
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#12
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castting
Thank Mr.Ed Huntress ...I read that and your words very true but I need some one who is expert in casting in the workshops because in practice the melt and cast very difficult
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#13
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castting
On Thursday, April 20, 2017 at 5:50:33 PM UTC-4, Asaad Kadhem wrote:
Thank Mr.Ed Huntress ...I read that and your words very true but I need some one who is expert in casting in the workshops because in practice the melt and cast very difficult This is more complicated than you're reading here. For over 100 years, they've made copper/chromium alloys by melting, but they achieved only about 0.5% chrome that way. Higher alloys, up to 10%, have been achieved by aluminothermic reaction (like thermite). You need the papers. Don't assume you can just dissolve chromium into molten copper and come up with a 1.5% alloy. -- Ed Huntress |
#14
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castting
On Thu, 20 Apr 2017 14:50:28 -0700 (PDT), Asaad Kadhem
wrote: Thank Mr.Ed Huntress ...I read that and your words very true but I need some one who is expert in casting in the workshops because in practice the melt and cast very difficult Greetings Asaad, An expert in casting will not be able to give you the advice you need on this newsgroup because there is too much information to type. So you really need to get a book aboput casting. Since you are totally new to this I think a book written so for folks like you would be best. One that has the casting basics but also enough information so that as you get more experience there will also be information you can use. So try this book. "The Complete Metalsmith" by Tim McCreight. The book covers many aspects of metalsmithing which you may find interesting but the section on casting is really good for beginners. It tells you about various fluxes, why they are needed, how they work, and how to use them. You will need to know this to do the casting you want to do. The book also covers heat sources and crucibles. I hope you learn something that you can tell us all about. Cheers, Eric |
#15
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castting
On Thursday, April 20, 2017 at 8:07:31 PM UTC-4, wrote:
On Thu, 20 Apr 2017 14:50:28 -0700 (PDT), Asaad Kadhem wrote: Thank Mr.Ed Huntress ...I read that and your words very true but I need some one who is expert in casting in the workshops because in practice the melt and cast very difficult Greetings Asaad, An expert in casting will not be able to give you the advice you need on this newsgroup because there is too much information to type. So you really need to get a book aboput casting. Since you are totally new to this I think a book written so for folks like you would be best. One that has the casting basics but also enough information so that as you get more experience there will also be information you can use. So try this book. "The Complete Metalsmith" by Tim McCreight. The book covers many aspects of metalsmithing which you may find interesting but the section on casting is really good for beginners. It tells you about various fluxes, why they are needed, how they work, and how to use them. You will need to know this to do the casting you want to do. The book also covers heat sources and crucibles. I hope you learn something that you can tell us all about. Cheers, Eric That's good advice -- he really needs to know which questions to ask -- but, as one who covered materials, including casting, in the metalworking press for 40 years, I would be very surprised if he finds answers to his specific questions in any ordinary casting book. I doubt if chromium/copper alloys are cooked up in any ordinary casting operation. It's a specialty and the only people who are likely to know about it are well-educated casting engineers. Finding one working in a foundry who can talk authoritatively about site-mixed chrome/copper (plus aluminum) is something I wouldn't even try. When I had to answer arcane questions like that, I'd go straight to the associations who know the highest-level engineers in the field I'm inquiring about. They're geared toward educating people about their industry; they're usually very helpful at connecting you with the people who are most likely to know. In this case, the two organizations I'd try would be ASM International (formerly the American Society for Metals), and the ICA (the International Copper Association). Here are their websites: http://copperalliance.org/ http://www.asminternational.org/web/guest/home Like most industry associations, they have staff that deals with the press, so I always had an easy way in. But they're also geared toward helping students and educational institutions. They're the most likely places to reach someone who really knows the answers. -- Ed Huntress |
#16
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castting
On Thu, 20 Apr 2017 17:45:09 -0700 (PDT), wrote:
On Thursday, April 20, 2017 at 8:07:31 PM UTC-4, wrote: On Thu, 20 Apr 2017 14:50:28 -0700 (PDT), Asaad Kadhem wrote: Thank Mr.Ed Huntress ...I read that and your words very true but I need some one who is expert in casting in the workshops because in practice the melt and cast very difficult Greetings Asaad, An expert in casting will not be able to give you the advice you need on this newsgroup because there is too much information to type. So you really need to get a book aboput casting. Since you are totally new to this I think a book written so for folks like you would be best. One that has the casting basics but also enough information so that as you get more experience there will also be information you can use. So try this book. "The Complete Metalsmith" by Tim McCreight. The book covers many aspects of metalsmithing which you may find interesting but the section on casting is really good for beginners. It tells you about various fluxes, why they are needed, how they work, and how to use them. You will need to know this to do the casting you want to do. The book also covers heat sources and crucibles. I hope you learn something that you can tell us all about. Cheers, Eric That's good advice -- he really needs to know which questions to ask -- but, as one who covered materials, including casting, in the metalworking press for 40 years, I would be very surprised if he finds answers to his specific questions in any ordinary casting book. I doubt if chromium/copper alloys are cooked up in any ordinary casting operation. It's a specialty and the only people who are likely to know about it are well-educated casting engineers. Finding one working in a foundry who can talk authoritatively about site-mixed chrome/copper (plus aluminum) is something I wouldn't even try. When I had to answer arcane questions like that, I'd go straight to the associations who know the highest-level engineers in the field I'm inquiring about. They're geared toward educating people about their industry; they're usually very helpful at connecting you with the people who are most likely to know. In this case, the two organizations I'd try would be ASM International (formerly the American Society for Metals), and the ICA (the International Copper Association). Here are their websites: http://copperalliance.org/ http://www.asminternational.org/web/guest/home Like most industry associations, they have staff that deals with the press, so I always had an easy way in. But they're also geared toward helping students and educational institutions. They're the most likely places to reach someone who really knows the answers. I figger before he can start experimenting with new alloys he needs to understand the fundamentals of melting and casting small ingots. Once he has that down pat he can start to experiment. Of prime importance is the heat source, type of crucible material, and how to avoid oxidation of the melt. No matter which course he decides to take he is gonna need to do lots of reading. The links you posted will be a good start in the reading dept. Eric |
#17
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castting
On Thursday, April 20, 2017 at 9:37:56 PM UTC-4, wrote:
I figger before he can start experimenting with new alloys he needs to understand the fundamentals of melting and casting small ingots. Once he has that down pat he can start to experiment. Of prime importance is the heat source, type of crucible material, and how to avoid oxidation of the melt. No matter which course he decides to take he is gonna need to do lots of reading. The links you posted will be a good start in the reading dept. Eric That would depend very much on whether his research is theoretical or practical. I hope it is both. |
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